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71.
Sandhya C Binod P Nampoothiri KM Szakacs G Pandey A 《Applied biochemistry and biotechnology》2005,127(1):1-15
Antifungal activity of chitinase can be effectively utilized in biologic pest control strategies. Because solid-state cultivation
has been termed a cost-effective means for fungal growth and metabolite production, chitinase production by Trichoderma harzianum was studied using wheat bran-based solid medium containing 1% colloidal chitin. Chitinase synthesis was found to be growth
associated because maximum enzyme (5.4 U/g of dry substrate) and biomass production occurred at 72h. Substrate moisture had
a critical impact on chitinase production; five grams of medium having an initial moisture content of 68.4% when incubated
for 72 h increased the enzyme yield to 9.3 U/g of dry substrate. Optimization of colloidal chitin concentration showed that
improvements in chitinase yield and maximum activity were attained with a 2% (w/w) concentration. Supplementation of additional
nitrogen sources also influenced enzyme production, and the best yield was obtained with yeast extract. The effect of crude
chitinase on hyphal morphology of the phytopathogenic fungus Collelotrichum gloeosporioides was swelling as well as lysis of hyphal wall, depending on the age of the mycelium. Studies of pH and thermal stability showed
that crude culture filtrate was active over pH 4.0–6.0 and retained about 48.2% activity after 40 min of incubation at 40°C. 相似文献
72.
Virgil Percec Makoto Obata Jonathan G. Rudick Binod B. De Martin Glodde Tushar K. Bera Sergei N. Magonov V. S. K. Balagurusamy Paul A. Heiney 《Journal of polymer science. Part A, Polymer chemistry》2002,40(20):3509-3533
The synthesis of 2‐ethynyl‐9‐substituted carbazole and 3‐ethynyl‐9‐substituted carbazole monomers containing first‐generation chiral and achiral dendritic (i.e., minidendritic) substituents, 2‐ethynyl‐9‐[3,4,5‐tris(dodecan‐1‐yloxy)benzyl]carbazole (2ECz), 3‐ethynyl‐9‐[3,4,5‐tris(dodecan‐1‐yloxy)benzyl]carbazole (3ECz), 2‐ethynyl‐9‐{3,4,5‐tris[(S)‐2‐methylbutan‐1‐yloxy]benzyl}carbazole (2ECz*), and 3‐ethynyl‐9‐{3,4,5‐tris[(S)‐2‐methylbutan‐1‐yloxy]benzyl}carbazole (3ECz*), is presented. All monomers were polymerized and copolymerized by stereospecific polymerization to produce cis‐transoidal soluble stereoisomers. A structural analysis of poly(2ECz), poly(2ECz*), poly(3ECz), poly(3ECz*), poly(2ECz*‐co‐2ECz), and poly(3ECz*‐co‐3ECz) by a combination of techniques, including 1H NMR, ultraviolet–visible, and circular dichroism spectroscopy, thermal optical polarized microscopy, and X‐ray diffraction experiments, demonstrated that these polymers had a helical conformation that produced cylindrical macromolecules exhibiting chiral and achiral nematic phases. Individual chains of these cylindrical macromolecules were visualized by atomic force microscopy. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 3509–3533, 2002 相似文献
73.
In this article we study some properties of the Nörlund and Riesz mean of sequences of fuzzy real numbers. We establish necessary and sufficient conditions for the Nörlund and Riesz means to transform convergent sequences of fuzzy numbers into convergent sequences of fuzzy numbers with limit preserving. 相似文献
74.
In recent past, Hawking temperature has been modified for the validity of thermodynamical laws at the event horizon in general relativity context. This lead to the introduction of modified Hawking temperature and it has been found that the modified Hawking temperature is more realistic on the event horizon. With this motivation, here we investigate the thermodynamical consistency of scalar-tensor gravity based models by examining the validity of the generalized second law of thermodynamics (GSLT) and thermodynamical equilibrium (TE) at the event horizon. In order to attain our goal, we consider a spatially flat Friedman–Robertson–Walker Universe filled with ordinary matter and the boundary of the Universe bounded by the event horizon that is in thermal equilibrium with modified Hawking temperature. Next, we calculate the general expressions for the GSLT and TE using modified Hawking temperature in the context of the more general action of scalar-tensor gravity where there is a non-minimally coupling between the scalar field and matter Lagrangian (as the chameleon field). From the general expression of GSLT, we find that the null energy condition must hold for a viable scalar-tensor model of the Universe dominated by a perfect fluid. Furthermore, in order to better understand these complicated general expressions of GSLT and TE, we explore the validity of the GSLT and TE for two viable models of scalar-tensor gravity namely Brans–Dicke gravity with a self-interacting potential and Chameleon gravity at the event horizon using special cosmological solutions. Finally, some graphical representation of the GSLT and TE have been presented. From the graphical analysis, we found that the power-law forms of the scale factor and scalar field is much favourable for the study of universal thermodynamics as compared to other choices of the scalar field and the analytic function. 相似文献
75.
On a Class of Generalized Lacunary Difference Sequence Spaces Defined by Orlicz Functions 总被引:1,自引:0,他引:1
In this article we introduce the generalized lacunary difference sequence spaces [N_θ,M,Δ~m]_0,[N_θ,M,Δ~m]_1 and [N_θ,M,Δ~m]_∞using m~(th)- difference.We study their properties like completeness,solidness,symmetricity.Also we obtain some inclusion relations involving the spaces [N_θ,M,Δ~m]_0,[N_θ,M,Δ~m]_1 and[N_θ,M,Δ~m]_∞and the Cesàro summable and strongly Cesàro summable sequences. 相似文献
76.
In this article we introduce the vector valued paranormed sequence spaces
and
defined over a seminormed space (X,q). We study their different properties like completeness, solidness, symmetry, convergence freeness etc. We prove some inclusion
results.
相似文献
77.
Giri BR Kiefer JH Xu H Klippenstein SJ Tranter RS 《Physical chemistry chemical physics : PCCP》2008,10(41):6266-6273
The thermal dissociation of fluoroethane has been studied using shock tube (ST)/time-of-flight mass spectrometry (TOF-MS) at 500 and 1200 Torr over the temperature range 1200-1550 K. The ST/TOF-MS experiments confirm that elimination of HF is the only reaction channel and rate coefficients for this reaction were extracted from concentration/time profiles derived from the mass spectra. Results from a novel diaphragmless shock tube coupled to the TOF-MS are also presented and demonstrate the unique ability of this apparatus to generate sufficiently reproducible shock waves that signal averaging can be performed over multiple experiments; something that is not possible with a conventional shock tube. The dissociation is also studied with ab initio transition state theory based master equation simulations. A modest increase in the calculated barrier height (i.e., by 1 kcal mol(-1)) yields predicted high pressure rate coefficients that are in good agreement with the existing literature data. The present pressure dependent observations are accurately reproduced for a downwards energy transfer for neon at 1200 to 1500 K of approximately 270 cm(-1), which is somewhat smaller than that found in previous studies on fluorinated ethanes with the same bath gases. 相似文献
78.
Binod Raj Giri Krishna Prasad Shrestha Tam V.-T. Mai Fabian Mauss Lam K. Huynh 《国际化学动力学杂志》2023,55(1):3-14
Amino (NH2) radicals play a central role in the pyrolysis and oxidation of ammonia. Several reports in the literature highlight the importance of the reactions of NH2 radicals with fuel in NH3-dual-fuel combustion. Therefore, we investigated the reactions of NH2 radicals with methanol (CH3OH) and ethanol (C2H5OH) theoretically. We explored the various reaction pathways by exploiting CCSD(T)/cc-pV(T, Q)Z//M06-2X/aug-cc-pVTZ level of theory. The reaction proceeds via complex formation at the entrance and exit channels in an overall exothermic process. We used canonical transition state theory to obtain the high-pressure limiting rate coefficients for various channels over the temperature range of 300–2000 K. We discerned the role of various channels in the potential energy surface (PES) of NH2 + CH3OH/C2H5OH reactions. For both reactions, the hydrogen abstraction pathway at the OH-site of alcohols plays a minor role in the entire T-range investigated. By including the title reactions into an extensive kinetic model, we demonstrated that the reaction of NH2 radicals with alcohols plays a paramount role in accurately predicting the low-temperature oxidation kinetics of NH3-alcohols dual fuel systems (e.g., shortening the ignition delay time). On the contrary, these reactions have negligible importance for high-temperature oxidation kinetics of NH3-alcohol blends (e.g., not affecting the laminar flame speed). In addition, we calculated the rate coefficients for NH2 + CH4 = CH3 + NH3 reaction that are in excellent agreement with the experimental data. 相似文献