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21.
近年来,应用聚合物载体氧化剂进行醇类氧化反应的研究已有报道,蔡坤等人采用盐酸三甲胺为配体的三氧化铬,制成对醇类具有高度氧化选择性的氧化剂。我们将三甲胺基和四甲胺基用反应选择性较好的低交联凝胶树脂固载化,合成了未见报道的重铬酸型叔胺树脂氧化剂(Ⅰ)和不同于Cainelli氧化剂的低交联凝胶重铬酸型季铵树脂氧化剂(Ⅱ)。合成路线如下: 相似文献
22.
The design, fabrication and use of mesh microcontactor structures is described. These allow contact between immiscible fluid phases (liquid/liquid or gas/liquid) enabling mass transfer and reaction between and within the phases. The phases are not mixed and are removed separately for subsequent use or analysis. The structures were designed for kinetic studies on biphasic reactions with the ability to handle sequential samples without excessive sample dispersion. Mass transport conditions are defined by fluid layer depths of 100 microm and the volume for each phase contacting in the reaction region was selected at 100 microl as sufficient for a range of analytical techniques. Micromeshes with pore diameter, depth, and spacing each of approximately 5 microm were formed by electrodeposition of nickel onto substrates with defined photoresist layers, and released by etching a copper sub-layer. Reactor enclosures defining chambers on each side of the mesh were formed from milled glass and metal components. The assembled structures have been used in flow-through and static fluid modes. System function has been demonstrated for both liquid/liquid and gas/liquid reactions. Test chemistries selected for ease of optical monitoring were hydrolysis of colourless fluorescein diacetate in toluene with transfer as fluorescein anion to aqueous alkali, and oxygen absorption into aqueous alkaline pyrogallol solution generating a coloured product, purpurogallin. 相似文献
23.
From the methanolic extract of Azadirachta indica leaves, we have isolated three new tetracyclic triterpenoids of biogenetic interest, namely, melianol 1, desfurano-desacetylnimbin-17-one 2 and meliatetraone 3. The structure elucidation is based on extensive spectral studies including 1H–1H-COSY, NOESY, HMQC, and HMBC experiments. 相似文献
24.
A simple, rapid, solvent-free, room temperature one pot synthesis of benzene ring acylated and demethylated analogues of harmine using acyl halides/acid anhydrides and AlCl(3) has been developed. Eight different acyl halides/acid anhydrides were used in the synthesis. The resulting mixture of products was separated by column chromatography to afford 10- and 12-monoacyl analogues, along with 10,12-diacyl-11-hydroxy products. In five cases the corresponding 10-acyl-11-hydroxy analogues were also obtained. Yields from the eight syntheses (29 products in total) were in the 6-34% range and all compounds were fully characterized. 相似文献
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26.
Preparation, structure and spasmolytic activities of some derivatives of harmine series of alkaloids
Begum S Imran Hassan S Siddiqui BS Ifzal R Perwaiz S Kiran T Shaheen F Ghayur MN Gilani AH 《Natural product research》2006,20(3):213-227
Keeping in view the interesting chemistry and pharmacological importance of harmine series of bases -- the beta-carboline alkaloids, a number of new derivatives of tetrahydroharmine and harmalol have been prepared and characterized through spectral studies. Some of these derivatives showed spasmolytic activity. It was observed that all the N-acyl tetrahydroharmine derivatives are stable, not labile and no ring opening occurs in these compounds, as reported recently. 相似文献
27.
We solve exactly the dynamics of N strongly driven two-level atoms equally coupled on resonance to a dissipative cavity mode. Analytical results are derived on decoherence, entanglement, purity, atomic correlations and cavity field mean photon number. Decoherence-free subspaces are predicted for the whole system and the N-qubit subsystem. Multi-partite entangled states and cavity cat-like states can be conditionally generated. The decay of quantum coherence and purity can be monitored by joint measurements on atomic populations. Atoms prepared in states invariant under permutation of any two components evolve within the subspace spanned by the completely symmetric Dicke states. Applications to N = 3, 4 are discussed. 相似文献
28.
Bina Bhattacharyya 《Transactions of the American Mathematical Society》2003,355(2):433-463
We describe the principal graphs of the subfactors studied by Krishnan and Sunder in terms of group actions on Cayley-type graphs. This leads to the construction of a tower of tree algebras, for every positive integer , which are symmetries of the Krishnan-Sunder subfactors of index . Using our theory, we prove that the principal graph of the irreducible infinite depth subfactor of index 9 constructed by Krishnan and Sunder is not a tree, contrary to their expectations. We also show that the principal graphs of the Krishnan-Sunder subfactors of index 4 are the affine A and D Coxeter graphs.
29.
Kay CW Mennenga B Görisch H Bittl R 《Journal of the American Chemical Society》2005,127(22):7974-7975
Pyrroloquinoline quinone (2,7,9-tricarboxypyrroloquinoline quinone, PQQ) is one of several quinone cofactors that is utilized in a class of dehydrogenases known as quinoproteins. In this contribution, we have used continuous-wave high-field/high-frequency electron paramagnetic resonance (EPR) at 94 GHz (W-band) to study substrate binding in ethanol dehydrogenase (QEDH) from Pseudomonas aeruginosa, taking advantage of the fact that the enzyme is isolated with a substantial proportion of the PQQ cofactor in the paramagnetic semiquinone form. In the substrate-free enzyme, the principal values of the g-tensor, obtained by spectral simulation are: gx = 2.00585(2), gy = 2.00518(2), and gz = 2.00212(2), giving giso = 2.00438(2). All three principal values of the g-tensor decrease when ethanol is bound to the protein: gx = 2.00574(2), gy = 2.00511(2), and gz = 2.00207(2), giving giso = 2.00431(2). The results represent the first direct evidence for the tight binding of an alcohol to a PQQ-dependent alcohol dehydrogenase and show that ethanol also binds to the enzyme even when the PQQ cofactor is in the semiquinone form. The decrease in g is consistent with an increase in polarity in the immediate vicinity of the PQQ cofactor and probably reflects a changed geometry of the PQQ-Ca2+ complex when ethanol binds. 相似文献
30.
Avraham Basch Bina Zvilichovsky Bella Hirshmann Menachem Lewin 《Journal of polymer science. Part A, Polymer chemistry》1979,17(1):27-37
Polymer formation from THPOH-urea, THPOH-dichloropropanol-urea, and THPC-urea was studied. Order and rate of urea addition were shown to influence insoluble polymer yields as well as polymer structure. The polymers were characterized by elemental analyses and infrared spectroscopy, and predominant structures proposed. The structures were correlated with thermogravimetric and differential scanning calorimetry data and probable thermal decomposition paths. 相似文献