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101.
Ching‐Yuan Cheng Kuan‐Jiuh Lin 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(8):m363-m365
In the title compound, catena‐poly[lithium‐μ3‐ethylenediphosphonato], [Li(C2H7O6P2)]n, the supramolecular monoclinic (C2/c) structure consists of one‐dimensional lithium chains [Li⋯Li = 2.7036 (8) Å] that are embedded within ethylenediphosphonate anions linked by strong symmetric hydrogen bonds [O⋯O = 2.473 (3) Å]. The Li atoms and the H atom in the symmetric hydrogen bond reside on twofold rotation axes and there is an inversion center at the mid‐point of the C—C bond of the ethylenediphosphonate ligand. 相似文献
102.
具P-Laplacian算子型周期边值问题解的存在性 总被引:8,自引:0,他引:8
本文利用拓扑度理论和一些分析技巧讨论了具p—Laplacian算子型周期边值问题(φp(χ’))’+d/dt gradF(χ)+gradG(χ)=e(t),χ(0)=χ(T),χ’(0)=χ’(T)解的存在性,在对阻尼项d/dtgradF(χ)没有任何限制的前提下,给出了解存在的充分条件. 相似文献
103.
Omer Ozturk Steven N. MacEachern 《Annals of the Institute of Statistical Mathematics》2004,56(4):701-720
We develop a method of randomizing units to treatments that relies on subjective judgement or on possible coarse modeling
to produce restrictions on the randomization. The procedure thus fits within the general framework of ranked set sampling.
However, instead of selecting a single unit from each set for full measurement, all units within a set are used. The units
within a set are assigned to different treatments. Such an assignment translates the positive dependence among units within
a set into a reduction in variation of contrasting features of the treatments.
A test for treatment versus control comparison, with controlled familywise error rate, is developed along with the associated
confidence intervals. The new procedure is shown to be superior to corresponding procedures based on completely randomized
or ranked set sample designs. The superiority appears both in asymptotic relative efficiency and in power for finite sample
sizes. Importantly, this test does not rely on perfect rankings; rather, the information in the data on the quality of rankings
is exploited to maintain the level of the test when rankings are imperfect. The asymptotic relative efficiency of the test
is not affected by estimation of the quality of rankings, and the finite sample performance is only mildly affected. 相似文献
104.
105.
Wang Qing-Lun Zhao Bin Liao Dai-Zheng Yan Shi-Ping Cheng Peng Jiang Zong-Hui 《Transition Metal Chemistry》2003,28(3):326-330
The copper(II) complex Na2[Cu(pba)] · 6H2O has been synthesized and its structure determined. It consists of a novel two-dimensional network of [Cu(pba)]2– anions connected to each other through the sodium ion as a bridge. Spectroscopic and magnetic properties have been measured and a spin distribution calculation has been carried out with the GAUSSIAN-94. Theoretical calculations indicate the rather larger spin density on nitrogen atoms should be responsible for the satellite lines appearing beside the main hyperfine coupling signs of copper(II). The antiferromagnetic interaction may be due to the intermolecular interaction and/or different copper(II) ions through the Na+ bridge in the same layer. 相似文献
106.
Chris Hope 《The Journal of the Operational Research Society》2003,54(11):1167-1176
What strategy should a football (soccer, in American parlance) club adopt when deciding whether to sack its manager? This paper introduces a simple model assuming that a club's objective is to maximize the number of league points that it scores per season. The club's strategy consists of three choices: the length of the honeymoon period during which it will not consider sacking a new manager, the level of the performance trapdoor below which the manager get the sack, and the weight that it will give to more recent games compared to earlier ones. Some data from the last six seasons of the English Premiership are used to calibrate the model. At this early stage of the research, the best strategy appears to have only a short honeymoon period of eight games (much less than the actual shortest period of 12 games), to set the trapdoor at 0.74 points per game, and to put 47% of the weight on the last five games. A club adopting this strategy would obtain on average 56.8 points per season, compared to a Premiership average of 51.8 points. 相似文献
107.
ZhongJunMA XianLI YangLU ChengWANG QiTaiZHENG 《中国化学快报》2003,14(6):594-596
A novel cycloartane,named sphaerophysone A,9,19-cycloart-7β,24β,25-triol-1-en-3-one,was isolated from the ethanol extract of Sphaerophysa salsula DC.The structure was elucidated on the basis of spectral evidences and confirmed by X-ray analysis,the stereochemistry of the compound was also defined by X-ray analysis. 相似文献
108.
109.
Dominique Fourdrinier William E. Strawderman 《Annals of the Institute of Statistical Mathematics》2003,55(4):803-816
We consider estimation of loss for generalized Bayes or pseudo-Bayes estimators of a multivariate normal mean vector, θ. In
3 and higher dimensions, the MLEX is UMVUE and minimax but is inadmissible. It is dominated by the James-Stein estimator and by many others. Johnstone (1988,
On inadmissibility of some unbiased estimates of loss,Statistical Decision Theory and Related Topics, IV (eds. S. S. Gupta and J. O. Berger), Vol. 1, 361–379, Springer, New York) considered the estimation of loss for the usual
estimatorX and the James-Stein estimator. He found improvements over the Stein unbiased estimator of risk. In this paper, for a generalized
Bayes point estimator of θ, we compare generalized Bayes estimators to unbiased estimators of loss. We find, somewhat surprisingly,
that the unbiased estimator often dominates the corresponding generalized Bayes estimator of loss for priors which give minimax
estimators in the original point estimation problem. In particular, we give a class of priors for which the generalized Bayes
estimator of θ is admissible and minimax but for which the unbiased estimator of loss dominates the generalized Bayes estimator
of loss. We also give a general inadmissibility result for a generalized Bayes estimator of loss.
Research supported by NSF Grant DMS-97-04524. 相似文献
110.