On the production mechanism of MF-HF radiopulses associated with large extensive air showers

Summary The existing theories on radio-emission from extensive air showers (EAS) are inadequate to explain the observed high fields associated with the emission of LF-MF-HF radiopulses. One of the attempts has been to explain the phenomenon in the light of the transition radiation (TR) mechanism from the excess negative charge of EAS on striking the ground. However, experimental data are very meagre. In order to concretise the theoretical basis of LF-MF-HF emission, experimental investigations on different aspects of radio-emission are essential. The present paper reports the experimental studies on radio-emission at some preselected frequencies (LF-HF) using a sophisticated data acquisition system. Results on i) variation of field strength with age parameter (S) for different primary energies (E _p) and different core distance (R), ii) lateral distribution of field strength for differentE _p andS and iii) frequency spectrum of radio-emission, are presented and analysed in the light of the TR mechanism.     

Non-static spherically symmetric clusters of particles in general relativity: I

In an ingenious way rotation (but no angular momentum) has been introduced in the case of spherical symmetry by Einstein, who has considered a stationary cluster of particles moving freely under the influence of the gravitational field produced by all of them together. The aim of the present work is to extend his idea to the non-static case, and it seems that under some circumstances instead of an indefinite gravitational collapse there is a minimum of the volume and a bouncing back.     

Congestion in large balanced multirate networks

In this paper, we obtain analytical approximations for various performance measures for a large fluid stochastic network that operates under a balanced fair bandwidth allocation policy. Balanced fairness results in the insensitivity of the stationary distribution of the number in the system to the precise distribution of file sizes. Balanced fairness has been shown to coincide with proportional fairness in large systems. The model we consider is that of servers operating under balanced fair rate allocations that are accessed by a large number of independent heterogeneous flows characterized by their arrival rate and general distributions of the file sizes; and a maximum service rate associated with each type of flow. The largeness of the system is parameterized by a scaling parameter that scales the arrival rates and capacity in such a way that the ratio is fixed. By exploiting a connection of the congestion probabilities with multirate Erlang loss systems, we use local limit large deviation methods to obtain accurate approximations as the scaling increases. The paper first discusses the single link case which is then extended to the case of a parking lot model that is a special case of tree networks.     

Selection of Suitable Combination of Nonfunctional Micellar Catalyst and Heteroaromatic Nitrogen Base as Promoter for Chromic Acid Oxidation of Ethanol to Acetaldehyde in Aqueous Medium at Room Temperature

The effect of the promoter and micellar catalyst on chromic acid on the oxidation of ethanol in aqueous acid media has been studied. Picolinic acid (PA), 1,10‐phenanthroline (phen), and 2,2′‐bipyridine (bipy) are used as promoters. Sodium dodecyl sulfate (SDS), cetyl pyridinium chloride (CPC), and Triton‐X‐100 (TX‐100) are tested as micellar catalysts. Hexavelent chromium is an active species in the absence of the promoter. In the presence of the heteroaromatic nitrogen bases used as the promoter, Cr(VI)–PA, Cr(VI)–bipy, and Cr(VI)–phen complexes have been proposed as the active oxidants. The time taken for completion of the reaction using different combinations of promoter and micellar catalysts are different. Although the rate is highest (12.5 times) in TX‐100 in the absence of the promoter, it is observed that the rate is almost 737 times faster for the combination of SDS and bipy compared to the unpromoted and uncatalyzed path. CPC inhibits the oxidation process. The observed acceleration and retardation of the rate of oxidation process has been explained on the basis of partitioning of the reactants in the micellar and aqueous phase. © 2013 Wiley Periodicals, Inc. Int J Chem Kinet 45: 175–186, 2013     

Novel metalloreagent Cp(CO)2FeP(Se)(OR)2 produced from P-Se bond cleavage in the thermal reaction of [CpFe(CO)2]2 with phosphor-1,1-diselenolates

The reaction of [CpFe(CO)2]2 with NH4Se2P(OR)2 yields a novel reagent Cp(CO)2FeP(Se)(OR)2, which has demonstrated coordination properties at the Se center to form heterometallic clusters as well as reactivity at the Se site toward C-based electrophiles.     

Phase behavior, interfacial composition and thermodynamic properties of mixed surfactant (CTAB and Brij-58) derived w/o microemulsions with 1-butanol and 1-pentanol as cosurfactants and n-heptane and n-decane as oils

Phase diagrams of pseudo-quaternary systems of cetyltrimethylammonium bromide (CTAB)/polyoxyethylene(20)cetyl ether (Brij-58)/water/1-butanol (or 1-pentanol)/n-heptane (or n-decane) at fixed omega (=[water]/[surfactant]) of 55.6 were constructed at different temperatures (293, 303, 313, and 323 K) and different mole fraction compositions of Brij-58 (X(Brij-58)=0, 0.5, and 1.0 in CTAB + Brij-58 mixture). Pure CTAB stabilized systems produced larger single-phase domains than pure Brij-58 stabilized systems. Increasing temperature increased the single-phase domain in the Brij-58 stabilized systems, whereas the domain decreased in the CTAB stabilized systems. For mixed surfactant systems (with X(Brij)=0.5) negligible influence of temperature in the studied range of 293 to 323 K on the phase behavior was observed. Interfacial compositions of the mixed microemulsion systems at different temperature and different compositions were evaluated by the dilution method. The n(a)(i) (number of moles of alcohol at the interface) and n(a)(o) (number of moles of alcohol in the oil phase) determined from dilution experiments were found to decrease and increase respectively for CTAB stabilized systems, whereas an opposite trend was witnessed for Brij-58 stabilized systems. The energetics of transfer of cosurfactants from oil to the interface were found to be exothermic and endothermic for CTAB and Brij-58 stabilized systems, respectively. At equimolar composition of CTAB and Brij-58, the phase diagrams were temperature insensitive, so that the enthalpy of the aforesaid transfer process was zero.     

Interface of AOT/Brij mixed reverse micellar systems: conductometric and spectrophotometric investigations

Solubilization and conductivity studies are carried out with AOT/Brijs (Brij-30, Brij-35, Brij-52, Brij-56, Brij-58, Brij-72, Brij-76, Brij-78)/isooctane/water mixed reverse micellar systems. Replacement of AOT molecules with large head group Brij molecules (Brij-30, Brij-35, Brij-56, Brij-58, Brij-76, Brij-78) decreases the solubilization capacity, whereas those with smaller polar head groups (Brij-52 and Brij-72) increases it. The former blends assist the conductance percolation whereas the latter retard it. An attempt has been taken to obtain more insight on the interfacial composition of the mixed interface with the help of spectrophotometric studies using 7-hydroxycoumarin as the fluorophore. The results obtained from the solubilization and conductometric studies have been correlated with those obtained from the spectroscopic studies.