Ethyl 3‐(2′‐deoxyuridin‐5‐yl)‐3‐hydroxy‐2‐iodopropanoate,a ­nucleoside analogue

In the title compound, C₁₄H₁₉IN₂O₈, an almost planar heterocyclic base is oriented anti with respect to the puckered sugar moiety. The sugar pucker is C2′‐endo/C3′‐exo, the N‐glycosidic torsion angle is 166.4 (4)° and the conformation of O5′ is +sc. The mol­ecules are linked by hydrogen bonds of the types N—H?O and O—H?O.     

Search for <Emphasis Type="Italic">B</Emphasis><Subscript><Emphasis Type="Italic">s</Emphasis></Subscript> → <Emphasis Type="Italic">ϕ</Emphasis>µµ decay at the Large Hadron Collider

As B _s -mesons will be produced abundantly at the LHC, the observability of the flavour-changing-neutral-current decay mode B _s → ϕμ⁺μ⁻ has been studied in CMS at the LHC centre-of-mass energy of 10 TeV. With an integrated luminosity of 100 pb⁻¹, an upper limit of 6.7 × 10⁻⁶ on the branching ratio is expected to be obtained. The potential at 7 TeV with a luminosity of 1 fb⁻¹ is expected to be better.     

Measurement of <Emphasis Type="Italic">Z</Emphasis> → <Emphasis Type="Italic">ττ</Emphasis> → <Emphasis Type="Italic">e</Emphasis>µ inclusive process at Large Hadron Collider

In several scenarios of beyond Standard Model physics a new heavy resonance is invoked which may decay preferentially, to a pair of taus. Identification of the decay of Standard Model Z resonance to tau pairs at LHC via subsequent decays of the taus to leptons as well as hadrons is the first step towards the discovery. A method has been suggested to discriminate Z to tau pair to electron+muon final state against various backgrounds, for early phase of 14 TeV LHC.     

Novel metalloreagent Cp(CO)2FeP(Se)(OR)2 produced from P-Se bond cleavage in the thermal reaction of [CpFe(CO)2]2 with phosphor-1,1-diselenolates

The reaction of [CpFe(CO)2]2 with NH4Se2P(OR)2 yields a novel reagent Cp(CO)2FeP(Se)(OR)2, which has demonstrated coordination properties at the Se center to form heterometallic clusters as well as reactivity at the Se site toward C-based electrophiles.     

Heavy traffic approximation for the stationary distribution of stochastic fluid networks

It has recently been shown that in the heavy traffic limit, the stationary distribution of the scaled queue length process of a Generalized Jackson Network converges to the stationary distribution of its corresponding Reflected Brownian Motion limit. In this paper, we show that this “interchange of limits” is valid for Stochastic Fluid Networks with Lévy inputs. Furthermore, under additional assumptions, we extend the result to show that the interchange is valid for moments of the stationary distribution and for state-dependent routing. The results are obtained using monotonicity and sample-path arguments.     

Phase behavior, interfacial composition and thermodynamic properties of mixed surfactant (CTAB and Brij-58) derived w/o microemulsions with 1-butanol and 1-pentanol as cosurfactants and n-heptane and n-decane as oils

Phase diagrams of pseudo-quaternary systems of cetyltrimethylammonium bromide (CTAB)/polyoxyethylene(20)cetyl ether (Brij-58)/water/1-butanol (or 1-pentanol)/n-heptane (or n-decane) at fixed omega (=[water]/[surfactant]) of 55.6 were constructed at different temperatures (293, 303, 313, and 323 K) and different mole fraction compositions of Brij-58 (X(Brij-58)=0, 0.5, and 1.0 in CTAB + Brij-58 mixture). Pure CTAB stabilized systems produced larger single-phase domains than pure Brij-58 stabilized systems. Increasing temperature increased the single-phase domain in the Brij-58 stabilized systems, whereas the domain decreased in the CTAB stabilized systems. For mixed surfactant systems (with X(Brij)=0.5) negligible influence of temperature in the studied range of 293 to 323 K on the phase behavior was observed. Interfacial compositions of the mixed microemulsion systems at different temperature and different compositions were evaluated by the dilution method. The n(a)(i) (number of moles of alcohol at the interface) and n(a)(o) (number of moles of alcohol in the oil phase) determined from dilution experiments were found to decrease and increase respectively for CTAB stabilized systems, whereas an opposite trend was witnessed for Brij-58 stabilized systems. The energetics of transfer of cosurfactants from oil to the interface were found to be exothermic and endothermic for CTAB and Brij-58 stabilized systems, respectively. At equimolar composition of CTAB and Brij-58, the phase diagrams were temperature insensitive, so that the enthalpy of the aforesaid transfer process was zero.     

Interface of AOT/Brij mixed reverse micellar systems: conductometric and spectrophotometric investigations

Solubilization and conductivity studies are carried out with AOT/Brijs (Brij-30, Brij-35, Brij-52, Brij-56, Brij-58, Brij-72, Brij-76, Brij-78)/isooctane/water mixed reverse micellar systems. Replacement of AOT molecules with large head group Brij molecules (Brij-30, Brij-35, Brij-56, Brij-58, Brij-76, Brij-78) decreases the solubilization capacity, whereas those with smaller polar head groups (Brij-52 and Brij-72) increases it. The former blends assist the conductance percolation whereas the latter retard it. An attempt has been taken to obtain more insight on the interfacial composition of the mixed interface with the help of spectrophotometric studies using 7-hydroxycoumarin as the fluorophore. The results obtained from the solubilization and conductometric studies have been correlated with those obtained from the spectroscopic studies.     

Efimov states and their Fano resonances in a neutron-rich nucleus

Asymmetric resonances in elastic n+19C scattering are attributed to Efimov states of such neutron-rich nuclei, that is, three-body bound states of the n+n+18C system when none of the pairs is bound or some of them are only weakly bound. By fitting to the general resonance shape described by Fano, we extract the resonance position, width, and the "Fano profile index." While Efimov states have been discussed extensively in many areas of physics, there is only one very recent experimental observation in trimers of cesium atoms. The conjunction that we present of the Efimov and Fano phenomena may lead to experimental realization in nuclei.     

Synthesis of 2-(ethynyloxy)naphthaene-1-carbaldehyde using 2-hydroxy benzyl alcohol and propargyl bromide in aqueous micellar media

Research on Chemical Intermediates - A highly convenient method has been developed for the synthesis of 2-(ethynyloxy) napthaene-1-carbaldehyde and its derivatives. Substituted naphthalene...