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81.
Non-isothermal oxidation of linolenic acid (LNA) in bulk phase was monitored by differential scanning calorimetry. The kinetic
parameters E
a, Z and k (activation energies, pre-exponential factors, and rate constants, respectively) were calculated by Ozawa-Flynn-Wall method
for the first detectable exothermic effect of uninhibited LNA oxidation. The kinetic parameters were also calculated for LNA
oxidation inhibited by 2,6-di-tert-butyl-4-methylphenol (BHT), and two natural compounds, 1,3-dihydroxy-5-pentylbenzene (olivetol), and 4-(4’-hydroxy-3’-methoxyphenyl)-3-buten-2-one
(DHZ, dehydrozingerone) at various concentrations.
For oxidation processes at 25, 90 and 180°C the plots of logk values vs. concentration of phenolic compounds indicated that optimal concentration of inhibitor determined for one particular temperature
cannot be extrapolated to other temperatures. 相似文献
82.
83.
Glucose oxidase was immobilised on nylon net by the method of O-alkylation using dimethyl sulfate and lysine as a spacer.
The influence of alkylation conditions on the characteristics of the resulting glucose electrode was evaluated. The best electrode
was then tested under batch and flow conditions, respectively. The influence of pH and temperature on electrode response were
examined. The glucose oxidase immobilised on nylon net seemed to be inhibited by glucose in alkaline pH and at higher temperatures.
Moreover, the shape of the electrode signal after addition of glucose was unusual. Glucose oxidase immobilised on nylon net
was unstable and lost its activity rather quickly, especially when stored dry in the refrigerator. Also the operational stability
of the electrode in the flow system was rather poor.
Received: 26 February 1998 / Revised: 22 May 1998 / Accepted: 29 June 1998 相似文献
84.
Glucose oxidase was immobilised on nylon net by the method of O-alkylation using dimethyl sulfate and lysine as a spacer. The influence of alkylation conditions on the characteristics of the resulting glucose electrode was evaluated. The best electrode was then tested under batch and flow conditions, respectively. The influence of pH and temperature on electrode response were examined. The glucose oxidase immobilised on nylon net seemed to be inhibited by glucose in alkaline pH and at higher temperatures. Moreover, the shape of the electrode signal after addition of glucose was unusual. Glucose oxidase immobilised on nylon net was unstable and lost its activity rather quickly, especially when stored dry in the refrigerator. Also the operational stability of the electrode in the flow system was rather poor. 相似文献
85.
The concept of Heider balance, usually applied to interpersonal relations, is generalized here to opinions gathered in surveys. At first, we compare four algorithms, which drive a matrix dataset to a balanced state. The criterion is that the final state obtained with an algorithm should be as close as possible to the initial state. The result is that deterministic differential equations work better than their Monte Carlo counterparts. Next, we apply the winning algorithms to the matrix of correlations between opinions gathered in American states between 1974 and 1998. The results are interpreted in terms of the classic comfort hypothesis (E. Babbie, 2007). 相似文献
86.
A procedure for the extraction of Cr(VI) from solid soil-like samples was presented in which the complexing properties of
diethylenetriaminepentaacetic acid (DTPA) were exploited to extract insoluble compounds of Cr(VI). A concentration of DTPA
in an ammonium sulphate/ammonium hydroxide buffer equal to 0.02 mol l−1 was chosen. The conditions of extraction of insoluble Cr(VI) from solid samples were optimised using soil certified reference
material spiked with known concentration of insoluble Cr(VI) added as PbCrO4. The extracts were analysed by adsorptive stripping voltammetry. Validation of the proposed procedure of extraction was carried
out by analysis of certified reference material (CRM) 545 and comparison of the results obtained using the proposed and other
methods of extraction in the course of analysis of natural soil samples. 相似文献
87.
Daniel Długosz Malgorzata Pach Anna Zabrzeńska Monika Zegar Barbara J. Oleksyn Justyna Kalinowska-Tłuścik Katarzyna Ostrowska 《Monatshefte für Chemie / Chemical Monthly》2008,139(5):543-548
Bis(cycloamidine-2-yl)alkanes easily form bromide tribromide salts in the reduction-oxidation processes with bromine. Bis(tetrahydroimidazolium-2-yl)ethane
and bis(hexahydropyrimidinium-2-yl)-ethane bromide tribromides are such new convenient brominating agents for aromatic amides
in chemo- and regioselective electrophilic substitutions and α-bromination reactions.
Correspondence: Katarzyna Ostrowska, Department of Organic Chemistry, Jagiellonian University, R. Ingardena 3, PL-30060 Kraków,
Poland. 相似文献
88.
The reaction of hydrated electron with 9-anthrylmethylammonium cation to form the respective anthracene radical anion in aqueous solution has been studied by the method of pulse radiolysis. The rate constant of the reaction of with is reported. It is demonstrated that the anthracene radical anion is unstable and undergoes further reactions. The spectra of transient intermediates, leading to the final reduction products, are presented. 相似文献
89.
Malgorzata Rosol 《Journal of organometallic chemistry》2005,690(9):2291-2296
1′-Carbopalladated complexes derived from 4-ferrocenyl-1,3-oxazolines are reported in this paper as efficient catalysts for the Heck coupling of iodo- and bromoarenes with alkenes. Experimental evidence points out strongly towards the involvement of a Pd(0)/Pd(II) catalytic cycle in the mechanism of the reaction. For the first time, the disassembly of the carbopalladated complex via coupling with the olefin in a non-catalytic Heck reaction has been demonstrated to be the origin of the release of Pd(0) from the palladacycle carrier. 相似文献
90.
This paper demonstrates the special potential of vibrational NIR FT Raman microspectroscopy for the study of fennel fruits, chamomile inflorescence and curcuma roots to obtain detailed information about their microstructure and chemical composition. Microscopic Raman maps of fennel fruits demonstrate that anethole, which is the main essential oil component, is present in the whole mericarp with highest concentration at the top of the fruit. In situ measurements obtained of the essential oil cells are dominated by two bands observed at 1657 cm(-1) and 1609 cm(-1) which are characteristic for anethole. Raman images of chamomile inflorescence show that spiroethers, identified by significant bands between 2150 and 2250 cm(-1), are accumulated in the middle part of the flower head. Due to the intense curcumin bands in the Raman spectrum of curcuma root, the distribution of this dyeing substance can be clearly determined; highest concentration of curcumin was observed on the core of the root. 相似文献