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排序方式: 共有347条查询结果,搜索用时 15 毫秒
31.
32.
Stolcic D Fischer M Ganteför G Kim YD Sun Q Jena P 《Journal of the American Chemical Society》2003,125(10):2848-2849
Using ultraviolet photoelectron spectroscopy, we provide direct experimental evidence that di-oxygen species are stable on anionic gold dimer and tetramer clusters at room temperature. The stabilization of molecular oxygen is crucial for the high activities of the low-temperature reactions on gold catalysts. 相似文献
33.
34.
Bimal P. Singh Jayadev Jena Laxmidhar Besra Sarama Bhattacharjee 《Journal of nanoparticle research》2007,9(5):797-806
The dispersion characteristics of nanosize silicon carbide (SiC) suspension were investigated in terms of surface charge,
particle size, rheological measurement and adsorption study. Ammonium polycarboxylate has been used as dispersant to stabilize
the suspension. It was found that the isoelectric point (iep) of SiC powder was pHiep (4.9). The surface charge of powder changed significantly in presence of the ammonium polycarboxylate dispersant and iep
shifted significantly towards lower acidic pH (3.6). The shift in iep has been quantified in terms of ΔG
0
SP, the specific free energy of adsorption between the surface sites and the adsorbing polyelectrolyte (APC). The values of
ΔG
0
SP (−10.85 RT unit) estimated by the electro kinetic data compare well with those obtained from adsorption isotherms (−9.521 RT unit). The experimentally determined optimum concentration of dispersant required for maximizing the dispersion was found
to be 2.4 mg/g of SiC (corresponding to an adsorbed amount of 1.10 mg/g), at pH 7.5. This is much below the full monolayer
coverage (corresponding to adsorbed amount of 1.75 mg/g) of the particles surface by the dispersant. The surface charge quantity,
rheological, pH, electro kinetic and adsorption isotherm results were used to explain and correlate the stability of the nanosize
silicon carbide in aqueous media. At pH 7.5, where both SiC surface and APC are negatively charged, the adsorption of APC
was low because of limited availability of favourable adsorption sites. In addition, the brush-like configuration of the adsorbed
polymer prevented close approach of any additional dispersant; hence stabilization of the slurry happens at a comparatively
lower concentration than the monolayer coverage. 相似文献
35.
The nucleon electromagnetic form factorsG
E
P
(q2),G
M
P
(q2) and the axial-vector form factor GA(q2) are studied in a relativistic model of independent quarks confined by an equally mixed scalar-vector square root potentialV
q(r)=1/2(1+γ
0)(ar
1/2+ν
0) taking into account the appropriate centre-of-mass corrections. The respective root-mean-square radii associated withG
E
P
(q2) and G
A
(q2) come out as [〈r
2〉
E
P
]1/2=0.86 fm and 〈r
A
2
〉1/2=0.88 fm. Restoration of chiral symmetry in this model is discussed to derive the pion-nucleon form factorG
πNN(q2) and consequently the pion-nucleon coupling constant is obtained asg
πNN(q2)=12.81 as compared tog
πNN(q2)exp⋍13. 相似文献
36.
The thermal instability of a horizontal layer of micropolar fluid which loses heat throughout its volume at a constant rate has been considered. The influence of the various micropolar fluid parameters on the onset of convection have been analysed. It is found that heat source and heat sink have the same destabilising effect in micropolar fluid. It is observed that the horizontal dimension of the cells remains insensitive to the changes in the micropolar fluid parameters and also to the heat source parameterQ except forQ values near zero, where the change is drastic. Further, it is observed that though the vertical component of velocity and the curl of microrotation do not vanish anywhere between the two boundaries forQ=0, they vanish at a point nearer to the lower boundary even for a small change in theQ value. 相似文献
37.
N. Bohidar B. Jena S. R. Mohanty 《Journal of Radioanalytical and Nuclear Chemistry》1985,95(5):291-299
The influence of -irradiation upto 200 Mrad on the thermal decomposition of barium bromate has been studied in the temperature range 553–583 K. The fraction decomposed //-time /t/ characteristics for irradiated barium bromate exhibit stages, viz. initial gas and decay stages. Irradiation shortens the induction period conforming to the relation I=C1–C2 lg dose. All experimental data for induction period are tested against the values obtained from the theoretical calculations by making use of this induction-period dose relation. The topochemical aspect of the validity of the above relation has been considered to be due to the linear growth of nuclei during irradiation and subsequent exponential growth during the induction period. 相似文献
38.
In an attempt to study the scope of a theorem due to Pati, the authors have established that φ(t) logK|t∈B
u
V in (0,π)⟹ΣA
n
(x) is |C, 0,β| forβ>1, at the pointt = x. 相似文献
39.
A simple independent-quark-model based on the Dirac equation with logarithmic potential is used to calculate several properties
of octet baryons such as magnetic moment, the axial vector coupling constantg
A (n) for neutronβ-decay and the charge radius of the proton. In view of the simplicity of the model, the results obtained are quite good. 相似文献
40.
Ko YJ Shakya A Wang H Grubisic A Zheng W Götz M Ganteför G Bowen KH Jena P Kiran B 《The Journal of chemical physics》2010,133(12):124308
The equilibrium structure, stability, and electronic properties of the Al(13)X (X=H,Au,Li,Na,K,Rb,Cs) clusters have been studied using a combination of photoelectron spectroscopy experiment and density functional theory. All these clusters constitute 40 electron systems with 39 electrons contributed by the 13 Al atoms and 1 electron contributed by each of the X (X=H,Au,Li,Na,K,Rb,Cs) atom. A systematic study allows us to investigate whether all electrons contributed by the X atoms are alike and whether the structure, stability, and properties of all the magic clusters are similar. Furthermore, quantitative agreement between the calculated and the measured electron affinities and vertical detachment energies enable us to identify the ground state geometries of these clusters both in neutral and anionic configurations. 相似文献