全文获取类型
收费全文 | 75090篇 |
免费 | 2407篇 |
国内免费 | 190篇 |
专业分类
化学 | 43626篇 |
晶体学 | 639篇 |
力学 | 2766篇 |
综合类 | 5篇 |
数学 | 11553篇 |
物理学 | 19098篇 |
出版年
2023年 | 481篇 |
2022年 | 721篇 |
2021年 | 943篇 |
2020年 | 959篇 |
2019年 | 940篇 |
2018年 | 1725篇 |
2017年 | 1335篇 |
2016年 | 2107篇 |
2015年 | 1804篇 |
2014年 | 2014篇 |
2013年 | 4080篇 |
2012年 | 4738篇 |
2011年 | 5193篇 |
2010年 | 3277篇 |
2009年 | 2945篇 |
2008年 | 4453篇 |
2007年 | 4407篇 |
2006年 | 4061篇 |
2005年 | 3755篇 |
2004年 | 3217篇 |
2003年 | 2638篇 |
2002年 | 2313篇 |
2001年 | 1972篇 |
2000年 | 1585篇 |
1999年 | 1185篇 |
1998年 | 853篇 |
1997年 | 839篇 |
1996年 | 855篇 |
1995年 | 605篇 |
1994年 | 662篇 |
1993年 | 598篇 |
1992年 | 636篇 |
1991年 | 555篇 |
1990年 | 546篇 |
1989年 | 496篇 |
1988年 | 402篇 |
1987年 | 402篇 |
1986年 | 344篇 |
1985年 | 523篇 |
1984年 | 486篇 |
1983年 | 331篇 |
1982年 | 429篇 |
1981年 | 405篇 |
1980年 | 341篇 |
1979年 | 327篇 |
1978年 | 335篇 |
1976年 | 341篇 |
1975年 | 307篇 |
1974年 | 290篇 |
1973年 | 288篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
91.
Morphological and chemical properties of both the surface and interface of poly(vinylidene fluoride)/poly(methyl methacrylate)-co-poly(ethyl acrylate) (PVDF/PMMA-co-PEA) blend films have been investigated before and after the samples were exposed to ultraviolet (UV) irradiation using a xenon arc lamp at 50 °C and 9% relative humidity (RH) for 7 months. Surface and interfacial morphologies were studied by atomic force microscopy (AFM). Chemical composition information was obtained by confocal Raman microscopy, attenuated total reflection-FTIR spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. Results show an enrichment of the PVDF material at the air surface, while the acrylic copolymer enriches the interface. Blends having greater than 50% mass fraction of PVDF show little change in the surface morphology after UV exposure for 7 months. However, for a lower PVDF content, blends exhibit significant degradation of PMMA-co-PEA copolymer and a much rougher surface after UV exposure. Microstructural changes in the PVDF spherulites are also observed after UV degradation. It is found that the surface and interfacial morphologies are correlated with the chemical properties. 相似文献
92.
Electronic properties of model quantum-dot structures in zero and finite magnetic fields 总被引:1,自引:0,他引:1
H. Saarikoski E. Räsänen S. Siljamäki A. Harju M.J. Puska R.M. Nieminen 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(2):241-252
We have computed electronic structures and total energies of circularly confined two-dimensional quantum dots and their lateral
dimers in zero and finite uniform external magnetic fields using different theoretical schemes: the spin-density-functional
theory (SDFT), the current-and-spin-density-functional theory (CSDFT), and the variational quantum Monte Carlo (VMC) method.
The SDFT and CSDFT calculations employ a recently-developed, symmetry-unrestricted real-space algorithm allowing solutions
which break the spin symmetry. Results obtained for a six-electron dot in the weak confinement limit and in zero magnetic
field as well as in a moderate confinement and in finite magnetic fields enable us to draw conclusions about the reliability
of the more approximative SDFT and CSDFT schemes in comparison with the VMC method. The same is true for results obtained
for the two-electron quantum dot dimer as a function of inter-dot distance. The structure and role of the symmetry-breaking
solutions appearing in the SDFT and CSDFT calculations for the above systems are discussed.
Received 16 October 2001 and Received in final form 17 January 2002 相似文献
93.
Yu You George W. Kattawar Ping Yang Yong X. Hu Bryan A. Baum 《Journal of Quantitative Spectroscopy & Radiative Transfer》2006,100(1-3):470-482
Measurements from depolarized lidars provide a promising method to retrieve both cloud and aerosol properties and a versatile complement to passive satellite-based sensors. For lidar observations of clouds and aerosols, multiple scattering plays an important role in the scattering process. Monte Carlo simulations are carried out to investigate the sensitivity of lidar backscattering depolarization to cloud and aerosol properties. Lidar parameters are chosen to be similar to those of the upcoming space-based CALIPSO lidar. Cases are considered that consist of a single cloud or aerosol layer, as well as a case in which cirrus clouds overlay different types of aerosols. It is demonstrated that besides thermodynamic cloud phase, the depolarized lidar signal may provide additional information on ice or aerosol particle shapes. However, our results show little sensitivity to ice or aerosol particle sizes. Additionally, for the case of multiple but overlapping layers involving both clouds and aerosols, the depolarized lidar contains information that can help identify the particle properties of each layer. 相似文献
94.
In this paper, nonconvex multiobjective optimization problems are studied. New characterizations of a properly efficient solution in the sense of Geoffrion's are established in terms of the stability of one scalar optimization problem and the existence of an exact penalty function of a scalar constrained program, respectively. One of the characterizations is applied to derive necessary conditions for a properly efficient control-parameter pair of a nonconvex multiobjective discrete optimal control problem with linear constraints. 相似文献
95.
96.
Csilla Bujtás 《Discrete Applied Mathematics》2007,155(11):1395-1407
For a mixed hypergraph H=(X,C,D), where C and D are set systems over the vertex set X, a coloring is a partition of X into ‘color classes’ such that every C∈C meets some class in more than one vertex, and every D∈D has a nonempty intersection with at least two classes. A vertex-orderx1,x2,…,xn on X (n=|X|) is uniquely colorable if the subhypergraph induced by {xj:1?j?i} has precisely one coloring, for each i (1?i?n). We prove that it is NP-complete to decide whether a mixed hypergraph admits a uniquely colorable vertex-order, even if the input is restricted to have just one coloring. On the other hand, via a characterization theorem it can be decided in linear time whether a given color-sequence belongs to a mixed hypergraph in which the uniquely colorable vertex-order is unique. 相似文献
97.
A. Ferreira da Silva I. Pepe S.A. Tomás W.M. de Azevedo R. Ahuja 《Applied Surface Science》2006,252(15):5365-5367
In this paper we present spectroscopic properties of doped and undoped titanium dioxide (TiO2) as nanofilms prepared by the sol-gel process with rhodamine 6G doping and studied by photoacoustic absorption, excitation and emission spectroscopy. The absorption spectra of TiO2 thin films doped with rhodamine 6G at very low concentration during their preparation show two absorption bands, one at 2.3 eV attributed to molecular dimmer formation, which is responsible for the fluorescence quenching of the sample and the other at 3.0 eV attributed to TiO2 absorption, which subsequently yields a strong emission band at 600 nm. The electronic band structure and optical properties of the rutile phase of TiO2 are calculated employing a fully relativistic, full-potential, linearized, augmented plane-wave (FPLAPW) method within the local density approximation (LDA). Comparison of this calculation with experimental data for TiO2 films prepared for undoped sol-gels and by sputtering is performed. 相似文献
98.
陈永静 朱胜江 J.H.Hamilton A.V.Ramayya J.K.Hwang Y.X.Luo J.O.Rasmussen 车兴来 丁怀博 李明亮 《中国物理 C》2006,30(8):740-744
通过测量252Cf自发裂变所产生的瞬发γ射线, 对146Ce核的高自旋结构进行了重新研究, 结果更新了以前报道的能级纲图, 把八级形变集体带扩展到更高的自旋, 并且重新构建了可能的准γ带结构. 此外, 用反射不对称壳模型(RASM)对146Ce核的八级形变带进行了计算, 低自旋处的计算结果与实验数据符合得很好. 相似文献
99.
Summary High-purity indium was analysed by spark source mass spectrometry, using electrical and photoplate detection. For the calibration of the differences in elemental sensitivity, a standard sample was prepared in which 10 impurities were determined by graphite furnace atomic absorption spectrometry. In this way accuracies of less than 40% were obtained for relatively homogeneous elements at ppm and sub-ppm level. About 40 elements could be determined with detection limits of 10 to 30 ppb. Two pattern recognition methods, principal component analysis and clustering analysis, were applied to obtain information on trace element distribution, which indicated that a number of elements were strongly spatially correlated in the analysed sample.
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
Chemische Analyse und Verteilungsbestimmung von Spurenelementen in Indium-Matrix durch Funkenquellen-Massenspektrometrie
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
100.
This paper is devoted to the proof of almost global existence results for Klein‐Gordon equations on Zoll manifolds (e.g., spheres of arbitrary dimension) with Hamiltonian nonlinearities, when the Cauchy data are smooth and small. The proof relies on Birkhoff normal form methods and on the specific distribution of eigenvalues of the Laplacian perturbed by a potential on Zoll manifolds. © 2007 Wiley Periodicals, Inc. 相似文献