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101.
Daniele Passarella Sergio Riva Gabriele Grieco Francesco Cavallo Begoña Checa Federica Arioli Elena Riva Daniela Comi Bruno Danieli 《Tetrahedron: Asymmetry》2009,20(2):192-197
The convenient synthesis of both enantiomers of the piperidine alkaloids such as dumetorine and epidihydropinidine is described. Pure enantiomers of 2-(2-hydroxy-ethyl)-piperidine-1-carboxylic acid tert-butyl ester are used as a common starting material. The syntheses are based on a RCM reaction and on methylation of the piperidine ring according to Beak–Lee methodology, respectively. 相似文献
102.
103.
L. Bianchi 《Mathematische Annalen》1880,16(4):577-582
Ohne Zusammenfassung 相似文献
104.
Summary
In un precedente articolo [2]G. Mägerl ed il secondo autore hanno dimostrato la buona posizione del problema ricostruttivo di Hammer, imponendo che il corpo convesso da ricostruire fosse contenuto in un preassegnato insieme limitato. Si dimostra qui che tale limitazione può essere tolta.Ricerca finanziata con fondi MPI. 相似文献
105.
A coarse grained model for flexible polymers end-grafted to repulsive spherical nanoparticles is studied for various chain lengths and grafting densities under good solvent conditions by molecular dynamics methods and density functional theory. With increasing chain length, the monomer density profile exhibits a crossover to the star polymer limit. The distribution of polymer ends and the linear dimensions of individual polymer chains are obtained, while the inhomogeneous stretching of the chains is characterized by the local persistence lengths. The results on the structure factor of both single chain and full spherical brush as well as the range of applicability of the different theoretical tools are presented. Finally, a brief discussion of the experiment is given. 相似文献
106.
Andrea Speltini Michela Sturini Federica Maraschi Antonella Profumo 《Journal of separation science》2010,33(8):1115-1131
The aim of this review is to provide a general overview on the analytical methods proposed in the last decade for trace fluoroquinolone (FQ) determination in environmental waters. A large number of studies have been developed on this topic in reason of the importance of their monitoring in the studies of environmental mobility and potential degradation pathways. Every step of the analysis has been carefully considered, with a particular attention to sample preparation, in relationship with the problems involved in the analysis of real matrices. The different strategies to minimise interference from organic matter and to achieve optimal sensitivity, especially important in those samples with lower FQ concentrations, were also highlighted. Results and progress in this field have been described and critically commented. Moreover, a worldwide overview on the presence of FQs in the environmental waters has been reported. 相似文献
107.
Federica Pellati Giuseppe CannazzaStefania Benvenuti 《Journal of chromatography. A》2010,1217(21):3503-3510
In this study, the racemization kinetic parameters of R-(−)-synephrine, the active phenethylamine alkaloid of Citrus aurantium L., were determined by means of an off-column HPLC method. Enantioseparation was carried out in different buffer solutions and solvents on a chiral stationary phase (CSP) with cellobiohydrolase as the chiral selector (Chiral-CBH, 100 mm × 4.0 mm i.d., 5 μm). The mobile phase was 10 mM sodium phosphate buffer (pH 6.0)-2-propanol (95:5, w/w), with 50 μM disodium EDTA, at 0.8 mL/min. The column was thermostatted at 20 °C and detection was set at 225 nm. The influence of pH value, ionic strength, temperature and addition of organic modifier on the rate constant, the half-life of racemization and the free energy barrier of racemization of R-(−)-synephrine were determined. Among the different chemical and physical parameters evaluated as affecting the racemization of naturally occurring R-(−)-synephrine, pH, temperature and addition of an organic co-solvent appear to have the strongest effect, while ionic strength does not exert a significant influence on the racemization rate. The results of the present study indicated that synephrine racemization is possible at high temperature at both acidic and basic pH values; therefore, the extraction procedure of R-(−)-synephrine from the plant material should be carried out under specific conditions to preserve the stereochemical integrity and the biological activity of this secondary metabolite. 相似文献
108.
King PD Hatch RC Bianchi M Ovsyannikov R Lupulescu C Landolt G Slomski B Dil JH Guan D Mi JL Rienks ED Fink J Lindblad A Svensson S Bao S Balakrishnan G Iversen BB Osterwalder J Eberhardt W Baumberger F Hofmann P 《Physical review letters》2011,107(9):096802
We report a Rashba spin splitting of a two-dimensional electron gas in the topological insulator Bi(2)Se(3) from angle-resolved photoemission spectroscopy. We further demonstrate its electrostatic control, and show that spin splittings can be achieved which are at least an order-of-magnitude larger than in other semiconductors. Together these results show promise for the miniaturization of spintronic devices to the nanoscale and their operation at room temperature. 相似文献
109.
Exposing the (111) surface of the topological insulator Bi(2)Se(3) to carbon monoxide results in strong shifts of the features observed in angle-resolved photoemission. The behavior is very similar to an often reported "aging" effect of the surface, and it is concluded that this aging is most likely due to the adsorption of rest gas molecules. The spectral changes are also similar to those recently reported in connection with the adsorption of the magnetic adatom Fe. All spectral changes can be explained by a simultaneous confinement of the conduction band and valence band states. This is possible only because of the unusual bulk electronic structure of Bi(2)Se(3). The valence band quantization leads to spectral features which resemble those of a band gap opening at the Dirac point. 相似文献
110.
Joaquín Díaz Iñaki López Emilio Nogales Bianchi Méndez Javier Piqueras 《Journal of nanoparticle research》2011,13(5):1833-1839
Silicon-doped gallium oxide nanowires have been synthesized by thermal methods using either a mixture of gallium oxide and
silicon powders or metallic gallium with silicon powder as precursor materials. The growth mechanism has been found to be
a vapour–liquid–solid (VLS) or vapour–solid (VS) process, respectively, depending on the precursor used. In the former case,
silicon oxide droplets at the end of the nanowires have been observed. Their possible role during the growth of the nanostructures
is discussed. Structural and morphological characterization of the doped nanowires has been performed by transmission electron
microscopy (TEM) and scanning electron microscopy (SEM). The results show a high crystalline quality and a uniform distribution
of silicon along the nanowires. Room temperature cathodoluminescence (CL) in the SEM shows that slight variations in the composed
UV–blue emission band appear due to the influence of Si impurities in the oxygen vacancy defect structure. 相似文献