Periodic surface nanostructures on polycrystalline ZnO induced by femtosecond laser pulses

Periodic surface nanostructures induced by femtosecond laser pulses on polycrystalline ZnO are presented. By translating the sample line-by-line under appropriate irradiation conditions, grating-like nanostructures with an average period of 160 nm are fabricated. The dependence of surface morphologies on the processing parameters, such as laser fluence, pulse number and laser polarization, are studied by scanning electronic microscope (SEM). In addition, photoluminescence (PL) analysis at room-temperature indicates that the PL intensity of the irradiated area increases significantly compared with the un-irradiated area. Using femtosecond laser pulses irradiation to fabricate periodic surface nanostructures on polycrystalline ZnO is efficient, simple and low cost, which shows great potential applications in ZnO-based optoelectronic devices.     

超声速和高超声速进气道的数值模拟

本文讨论超声速和高超声速进气道的数值模拟问题,其中包括国内外对进气道问题的一些主要进展、方向和今后预研的动态,目的在于弄清流场形成的机理,为高速飞行器进气道的气动设计提供理论依据。      

Interaction Between Plumbagin and Human Serum Albumin by Fluorescence Spectroscopy

The interaction of plumbagin (PLU) with human serum albumin (HSA) in physiological buffer (pH=7.4) was studied by fluorescence spectroscopy. Results obtained from analysis of the fluorescence spectra indicated that PLU has a strong ability to quench the intrinsic fluorescence of HSA through a static quenching procedure. Fluorescence quenching data revealed that the quenching constants (K) are 4.43×10⁴, 3.26×10⁴ and 1.69×10⁴ L?mol^?1 at 293, 303 and 313 K, respectively. The thermodynamic parameters ΔH° and ΔS° were calculated to be ?36.63 kJ?mol^?1, and ?35.702 J?mol^?1?K^?1 respectively, which suggested that van der Waals interactions and hydrogen bonds play a major role in the interaction of PLU with HSA. The distance between donor (HSA) and acceptor (PLU) was calculated to be 3.76 nm based on Förster’s non-radiative energy transfer theory. The results of synchronous fluorescence spectra showed that binding of PLU to HSA can induce conformational changes in HSA.     

2-(苯并噻唑-2-基)-5-(N,N-二乙基氨基)苯酚衍生物的合成及其对H2S的识别

以4-N,N-二乙基氨基水杨醛为原料,制备了2-(苯并噻唑-2-基)-5-(N,N-二乙基氨基)苯酚衍生物(探针L),并对其结构进行了表征。在DMSO/PBS(体积比3∶7,pH=7.4)溶液中,探针L具有高选择性并可荧光"关-开"识别H_2S,在365nm紫外灯照射下,由无荧光变成蓝色荧光。实验表明,探针L识别H_2S的检测限为2.05×10~(-6)mol/L,pH适用范围为6～9,可用于检测实际水样中的H_2S。     

Prediction of mixed-mode fracture based on an elasto–plastic energy balance criterion

The maximum energy release rate criterion, i.e., G _max criterion, is commonly used for crack propagation analysis. This fracture criterion is based on the elastic macroscopic strength of materials. In the present investigation, however, the G _max criterion has been modified in order to accommodate the consideration of plastic strain energy. This modified criterion is extended to study the fatigue crack growth characteristics of mixed-mode cracks. To predict crack propagation due to fatigue loads, a new elasto–plastic energy model is presented. This new model includes the effects of material properties such as strain hardening exponent n, yield strength σ _y , and fracture toughness and stress intensity factor ranges. The results obtained are compared with those obtained using the commonly employed crack growth law and the experimental data.     

Electrochemical Behavior of Herbal Antitumor Drug Aloe‐Emodin at Carbon‐Coated Nickel Magnetic Nanoparticles Modified Glassy Carbon Electrode

The electrochemical behavior of aloe‐emodin (AE), an important herbal antitumor drug, was investigated at a carbon‐coated nickel magnetic nanoparticles modified glassy carbon electrode (CNN/GCE). A couple of well‐defined redox peaks was obtained. Some electrochemical parameters of AE at a CNN/GCE, such as the charge number, exchange current density, standard heterogeneous rate constant, were measured. The square wave voltammetry (SWV) response of AE was linear with the concentration over two concentration intervals viz. 6.24×10^?9?1.13×10^?6 M and 1.13×10^?6?1.23×10^?5 M, with a detection limit of 2.08 nM. A fast, simple and sensitive detection and analysis of AE was developed.     

影响杂化钙钛矿太阳能电池稳定性的因素探讨

自从2009年首次报道采用有机-无机杂化钙钛矿作为吸光材料用于太阳能电池以来, 钙钛矿太阳能电池效率的快速提升引起了人们广泛的关注, 这类电池同时具有制备工艺简单、成本低廉等优点, 引发了钙钛矿电池的研究热潮. 目前研究工作大多数集中在如何提高电池的光电转化效率, 但钙钛矿电池要真正实现产业化应用, 急需要解决材料及器件的稳定性问题. 本文探讨影响钙钛矿材料及器件的稳定性因素, 从温度及湿度等方面分析了材料的稳定性, 从传输材料及其界面问题讨论了器件的稳定性.     

A cinnamoyl substituted Nile Red-based probe to detect hydrazine

Herein we discovered that a Nile Red-based probe with a cinnamoyl unit was highly selective and sensitive to N₂H₄. Hydrazinolysis by N₂H₄ would release a hydroxyl substituted Nile Red and result in remarkable fluorescence quench. Importantly, Cys/Hcy would not interrupt the N₂H₄ recognition. This is because, for this probe, the combination of the π-π conjugate system can stabilize the ethylene union, which results in the nucleophilic addition of the thiol group of Cys/Hcy becomes non-effective.     

Evaluation and Optimization of New Nanocomposite Fiber for Fracturing Technology Based on a New Equipment

The fiber has great advantages in hydraulic fracturing when considering fluid leak off and flow friction, proppant transportation and fracture damage, proppant or sand production, and fracture geometry. However, some drawbacks, such as poor chemical stability, mechanical properties, heat denaturation, and dispersivity, always emerge in oilfield cases. Accordingly, a new type of nanocomposite fiber is used to overcome these shortcomings in our research. Generally, fiber??s conventional performance, dispersivity and proppant suspension capability can be evaluated easily, but reliable evaluation and optimization of fiber applications could not be obtained by normal indoor experimental instruments. So we developed the ??fracture filling model??, a specially designed instrument to evaluate the performances of fracture conductivity, proppant backflow, and sand control. All the performances of the nanocomposite fiber were evaluated, and the length and concentration of the fiber were optimized. The results have great influences on both theoretical study and field treatments of the new nanocomposite fiber.     

Mathematical problems in the integral-transformation method of dynamic crack

In the investigation on fracture mechanics, the potential function was introduced,and the moving differential equation was constructed. By making Laplace and Fourier transformation as well as sine and cosine transformation to moving differential equations and various responses, the dual equation which is constructed from boundary conditions lastly was solved. This method of investigating dynamic crack has become a more systematic one that is used widely. Some problems are encountered when the dynamic crack is studied.After the large investigation on the problems, it is discovered that during the process of mathematic derivation, the method is short of precision, and the derived results in this method are accidental and have no credibility. A model for example is taken to explain the problems existing in initial deriving process of the integral-transformation method of dynamic crack.