Selective and Simultaneous Voltammetric Determination of Glutathione,Uric Acid and Penicillamine by a Modified Carbon Nanotube Paste Electrode

In this paper, the use of a carbon paste electrode (CPE) modified by (E)‐3‐((2‐(2,4‐dinitrophenyl)hydrazono)methyl)benzene‐1,2‐diol (DHB) and carbon nanotubes (CNTs) for the determination of glutathione (GSH), uric acid (UA) and penicillamine (PA) is described. Initially, cyclic voltammetry was used to investigate the redox properties of the modified electrode in phosphate buffer. Next, the electrocatalytic oxidation of GSH via EC′ mechanism at the modified electrode was described. At the optimum pH of 7.0, the oxidation of GSH occurs at a potential that is 530 mV less positive than that of an unmodified carbon paste electrode. The values of the diffusion coefficient (D=2.5×10^?6 cm² s^?1) and the catalytic rate constant (k=1.7×10³ M^?1 s^?1) were calculated for GSH, using chronoamperometry. Based on differential pulse voltammetry, the oxidation of GSH exhibited a dynamic range between 0.4 and 700.0 µM and a detection limit (3σ) of 70.0 nM. Also, simultaneous determination of GSH, UA and PA was described at the modified electrode. Finally, this method was used for the determination of these substances in synthetic solutions and blood serum samples.     

Gamma radiation effects on physico-chemical parameters of apple fruit during commercial post-harvest preservation

The physico-chemical parameters (including moisture, total soluble solids, antioxidant activity, phenolic content and firmness) of cv. Red Delicious apple subjected to γ radiation were evaluated for their ability to avoid the post-harvest blue mold caused by Penicillium expansum during cold storage. Freshly harvested apples were inoculated with P. expansum. Treated fruits were irradiated at doses of 0, 300, 600, 900 and 1200 Gy and stored at 1 °C. Apples were evaluated at three month intervals. The results showed that there was a clear link between phenolic content and antioxidant activity, so that dose range of 900 Gy and higher significantly decreased phenolic content and antioxidant activity. The moisture percent of stored apples was more responsive to irradiation (at doses of 900–1200 Gy) than storage time and pathogen. Lesion diameter of pathogen-treated non-irradiated apples was significantly increased after three months. This means that storage at low temperature is not enough to avoid blue mold growth. As dose and storage time increased firmness decreased; also pathogen accelerated softening of stored apples. This study showed conclusively that low irradiation doses (300 and 600 Gy) combined with cold storage is a way to minimize apple quality losses during nine month storage period.     

Effect of crystallinity on electrical properties of electron beam irradiated LDPE and HDPE

Two sets of low-density polyethylene (LDPE) and high-density polyethylene (HDPE) sheets were prepared using warm press system. Each set consisted of three subsets which were made in different cooling rate procedures: fast cooling with cassette; exposing in open air; and exposing in 0 °C water, to investigate the crystallinity effects. The samples were irradiated with 10 MeV electron beam in the dose range of 0–370 kGy using a Rhodotron accelerator system. The variation of electrical properties of all samples such as breakdown voltage, surface and volume resistivity were measured and graphed against the dose values. The radiation induced cross-linking and cooling procedure effects were investigated and compared in the obtained results.     

Application of 2-(3,4-dihydroxyphenyl)-1,3-dithialone self-assembled monolayer on gold electrode as a nanosensor for electrocatalytic determination of dopamine and uric acid

The electrooxidation of dopamine (DA), uric acid (UA) and their mixture on a gold electrode modified by a self-assembled monolayer of 2-(3,4-dihydroxyphenyl)-1,3-dithialone has been studied by cyclic voltammetry (CV), chronoamperometry and differential pulse voltammetry (DPV). CV was used to investigate the redox properties of the modified electrode at various scan rates and the apparent charge transfer rate constant (k(s)), and transfer coefficient (α) were calculated. The mediated oxidation of DA at the modified electrode under the optimum condition (pH = 7.0) in CV occurs at a potential about 220 mV less positive than that of the unmodified gold electrode. The values of electron transfer coefficients (α), catalytic rate constant (k) and diffusion coefficient (D) were calculated for DA, using electrochemical methods. DPV exhibited a linear dynamic range over the concentration range of 0.2-250.0 μM and a detection limit (3σ) of 0.07 μM for DA. The modified electrode was used for simultaneous determination of DA and UA by DPV. The results showed that the electrode is highly efficient for the catalytic electrooxidation of DA and UA, leading to a remarkable peak resolution (~350 mV) for two compounds. The electrode was used for the determination of DA in an injection sample.     

Nano-BF<Subscript>3</Subscript>·SIO<Subscript>2</Subscript>: a reusable and eco-friendly catalyst for synthesis of quinoxalines

2,3-Disubstituted quinoxalines were synthesized via condensation of α-diketones and 1,2-phenylenediamines. Nano-BF₃·SiO₂ as a "green" and reusable solid acid was used as the catalyst for the synthesis of quinoxalines. The reaction was carried out at room temperature under sonication with high to excellent yields.     

苯并噻唑和铁氧化物纳米粒子修饰的磁性棒碳糊电极上肼的电催化氧化反应：同时检测肼和苯酚

开发了一种磁性Fe3O4纳米粒子和2-(3,4-二羟苯基)苯并噻唑(DPB)修饰的磁性棒碳糊电极(MBCPE)用于电化学检测肼.首先将DPB自组装在Fe3O4纳米粒子上,然后将此复合物吸附于设计的MBCPE上. MBCPE电极将磁性纳米粒子吸引到电极表面.所得新型电极具有高的导电性和大的有效比表面积,因而对肼的电催化氧化反应有非常大的电流响应.采用伏安法、扫描电镜、电化学阻抗谱、红外光谱和紫外-可见光谱对修饰电极进行了表征.采用伏安法研究了在磷酸盐缓冲溶液(pH=7.0)中MBCPE/Fe3O4NPs/DPB电极上肼的电化学行为.作为电化学传感器, MBCPE/Fe3O4NPs/DPB电极对肼氧化反应表现出极高的电催化活性.在DPB存在下,肼的氧化电势下降,但其催化电流增加.电催化电流与肼浓度在0.1–0.4和0.7–12.0μmol/L二个区间内表现出线性关系,检测限为18.0 nmol/L.另外,研究了MBCPE/Fe3O4NPs/DPB电极同时检测肼和苯酚的性能.伏安实验结果显示,苯酚的线性区域为100–470μmol/L,检测限为24.3μmol/L.采用此电极检测了水样品中的肼和苯酚.     

The use of silica sulfuric acid as an efficient catalyst for deprotection of trimethylsilyl ethers to the corresponding alcohols under mild and heterogeneous conditions

Silica sulfuric acid was used as a suitable catalyst for the conversion of trimethylsilyl ethers to the corresponding alcohols in the presence of wet SiO2 in high yields at room temperature.     

Meson polarized distribution function and mass dependence of the nucleon parton densities

The polarized distribution functions of mesons, including pion, kaon and eta, using the proton structure function, are calculated. We are looking for a relationship between the polarized distribution of mesons and the polarized structure of nucleons. We show that the meson polarized parton distributions leads to zero total spin for the concerned mesons, considering the orbital angular momentum of quarks and gluons inside the meson. Two separate Monte Carlo algorithms are applied to compute the polarized parton distributions of the kaon. Via the mass dependence of quark distributions, the distribution function of the eta meson is obtained. A new method by which the polarized sea quark distributions of protons are evolved separately which cannot be performed easily using the standard solution of DGLAP equations - is introduced. The mass dependence of these distributions is obtained, using the renormalization group equation which makes their evolutions more precise. Comparison between the evolved distributions and the available experimental data validates the suggested solutions for separated evolutions.     

Direct Sulfonylation of Aromatic Rings with Aryl or Alkyl Sulfonic Acid Using Supported P2O5/Al2O3

Direct sulfonylation of aromatic rings with aryl or alkyl sulfonic acid supported P₂O₅/Al₂O₃ (w/w 50%) under heterogeneous conditions in short reaction time and high yields.