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41.
42.
Journal of Thermal Analysis and Calorimetry - The synthesis of Schiff bases of chitosan is performed by the reaction of chitosan with different heteroaryl aldehydes, i.e., furfuraldehyde,...  相似文献   
43.
Simple, efficient, and mild method for α-thiocyanation of ketones in presence of heteropolyacid has been developed. This methodology offered α-oxothiocyanates in good to excellent yields at room temperature in a highly selective manner. The catalyst could be efficiently recovered from the reaction and reused.  相似文献   
44.
    
A simple, efficient, and ecofriendly procedure has been developed for the synthesis of quinoline and its derivatives in a one-pot reaction of aniline with crotonaldehyde or methyl vinyl ketone using phosphomolybdic acid as solid acid catalyst in miceller media. The catalyst was easily recycled and reused.  相似文献   
45.
    
A sensitive, selective and robust densitometric high-performance thin-layer chromatographic method was developed and validated for five marker compounds, namely betulin, lupeol, oleanolic acid, 3-acetyloleanolic acid and β-sitosterol, known for their various therapeutic activities. The marker compounds have been isolated from the stem bark of Betula utilis, well characterized by the spectral analysis, and their simultaneous quantitative determination carried out by high-performance thin-layer chromatography (HPTLC) method. The resolution of marker compounds was carried out on silica-gel 60 plates, using n-hexane:ethyl acetate (8:2 v/v) as the mobile phase. The HPTLC densitometry was performed at 500-nm wavelength after the post chromatographic derivatization with ceric ammonium sulfate reagent. The optimized method provided good linear relation (r>0.9960) for all the investigated analytes. The method is simple, and reproducible, which may be applied for quantitative analysis of the above-mentioned marker compounds.  相似文献   
46.
    
A series of well‐defined poly(3‐hexylthiophene)s (P3HT) of different molecular weight (MW) and high regioregularity was investigated for charge transport properties in as‐cast and melt‐crystallized films. The semicrystalline structure of the P3HT was characterized by X‐ray scattering and Atomic force microscopy. Crystallization by cooling from the melt led to a substantial increase in crystallinity and a stronger alignment of the crystals in comparison to as‐cast films. The increase in crystallinity went along with an increase in hole mobility of up to an order of magnitude as measured by the space charge limited current method. Additionally, the hole mobility depended on the long period of P3HT lamellae and consequently on the MW. In compliance with the long period, the charge carrier mobility first increased with the MW before decreasing again at the onset of chain folding. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013 , 51, 943–951  相似文献   
47.
    
The Bergman cyclopolymerization of polymerizable surfactant monomer was carried out within the hexagonal channels of functional hybrid nanocomposite formed by co-assembly with silica.  相似文献   
48.
In this study, I discuss the development of the ideas of Josiah Willard Gibbs' Elementary Principles in Statistical Mechanics and the fundamental role they played in forming the modern concepts in that field. Gibbs' book on statistical mechanics became an instant classic and has remained so for almost a century.  相似文献   
49.
The paper discusses the solution to an elastodynamic problem of an infinite medium excited by loads acting over a semi-infinite rectangular boundary whose height 2a is assumed small compared to the wavelengths of interest. The solution is developed using the method of matched-asymptotics in conjunction with an application of the Wiener-Hopf technique for the outer problems and the Muskhelishvili-Kolosov complex functions for the inner problems. The solutions are matched mutually and the resulting stress behaviour, as far as it is described by the inner limit to the outer solution, is also derived.  相似文献   
50.
A class of topological excitations-the odd-winding number vortices-in a spinless 2D chiral p-wave (px+ipy) superconductor traps Majorana fermion states in the vortex cores. For a dilute gas of such vortices, the lowest energy fermionic eigenstates are intrinsically nonlocal. We predict two testable signatures of this unusual quantum nonlocality in quasiparticle tunneling experiments. We discuss why the associated teleportationlike phenomenon does not imply the violation of causality.  相似文献   
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