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971.
Testing goodness of fit for the distribution of errors in multivariate linear models 总被引:2,自引:0,他引:2
M.D. Jimnez Gamero J. Muoz García R. Pino Mejías 《Journal of multivariate analysis》2005,95(2):301-322
In this paper, to test goodness of fit to any fixed distribution of errors in multivariate linear models, we consider a weighted integral of the squared modulus of the difference between the empirical characteristic function of the residuals and the characteristic function under the null hypothesis. We study the limiting behaviour of this test statistic under the null hypothesis and under alternatives. In the asymptotics, the rank of the design matrix is allowed to grow with the sample size. 相似文献
972.
Montecchi M. Nichelatti E. Montereali R.M. Piccinini M. Somma F. 《Optical and Quantum Electronics》2004,36(1-3):43-56
An analytical expression of the complex permittivity is derived for absorbing centres featuring inhomogeneous absorption-line broadening. Such an expression gives the dispersion law of the real part of the permittivity when the imaginary part has a Gaussian lineshape. Our mathematical approach starts from an overlap integral of Lorentzian-type dielectric susceptibilities weighted by a Gaussian probability distribution of the resonance absorption energies. The analytical solution found is consistent with the Kramers–Kronig relation. We demonstrate that, like in the case of homogeneous absorption-line broadening, the refractive index increases at photon energies lower than the resonance absorption energy also for inhomogeneous absorption-line broadening; if the absorbing centres emit Stokes-shifted radiation, such an increase can be exploited for passive and active waveguiding applications. An example is reported regarding active waveguides based on colour centres in a lithium fluoride crystal. 相似文献
973.
A liquid chromatography-mass spectrometry method for the determination of the coccidiostats metronidazole, ronidazole, dimetridazole,
secnidazole, tinidazole and ipronidazole in feedstuff was developed. The 5-nitroimidazoles were extracted from animal feed
with a pH 2 phosphate buffer solution followed by a solid phase extraction procedure based on HLB cartridges. The liquid chromatographic
separation of the extracts was performed on a C18 bonded silica column applying a gradient of elution with pH 4.3 ammonium acetate buffer solution and acetonitrile. Quantification
for each 5-nitroimidazole was carried out monitoring its molecular ion [M + H]+ obtained by positive electrospray ionisation mode. A pool of feedstuffs was used to optimise and validate the method. Linearity,
quantification limit, intra-day and inter-day reproducibility and accuracy were estimated using this pool of feedstuffs spiked
with the drugs. For the confirmatory assay, several fragment ions from each 5-nitroimidazole were obtained and monitored.
The method was applied successfully to determine 5-nitroimidazoles in feedstuff at level of 0.05 mg kg−1. 相似文献
974.
G. Halambalakis N. Rousseau O. Briot S. Ruffenach R.L. Aulombard P.R. Edwards K.P. ODonnell T. Wojtowicz P. Ruterana 《Superlattices and Microstructures》2004,36(4-6):721
We have studied the optical properties of Eu doped GaN thin films. We have grown high quality Eu doped GaN thin films by using Gas Source Molecular Beam Epitaxy (GSMBE), with 1.4% Eu concentration. The Full Width at Half Maximum (FWHM) of the X-ray diffraction in an omega scan was found to be 288 arcsecs. Low Eu concentration (0.08%) doped GaN thin films were grown, where Eu-related photoluminescence at 622 and 613 nm was detected using above band-gap excitation at 2 K. For high Eu concentration of 30% GaN:Eu crystal photoluminescence (PL) and cathodoluminescence (CL) spectra show strong and intense transitions at 622 and 664 nm, but also at 593 nm for CL spectra, with a similar transition observed from the low Eu concentration sample. 相似文献
975.
In order to check whether superconductivity occurs in the acceptor doped fullerenes C60(MF6)2 (M=As, P, Sb) and to study their magnetic and structural properties, we have carried out magnetic, EPR and NMR measurements of these compounds. Temperature dependences of magnetic susceptibility down to 5 K and field dependences of magnetic moment at 5 K show no ‘bulk’ transition in superconducting state. Some reasons of the absence of superconductivity, such as insufficient charge transfer between C60 and intercalated species and inhomogeneity of the compounds under study, are discussed. 相似文献
976.
977.
Recently, Miracle proposed that the intermediate structure in metallic glasses could be usefully characterized as an ordered face centered cubic packing of solute-centered coordination clusters. In this paper we examine the stability of such solute ordered arrangements in binary hard sphere mixtures subject to density maximization through local particle moves. 相似文献
978.
A theoretical approach was made to find out a complete fluorine incorporation zone on a ternary diagram which serves as a useful graphical representation to select the flows of the supplied reagents for incorporation of the suitable amount of fluorine into cladding glass of optical fiber preform made by the MCVD process using CCl2F2 as a source of fluorine under oxygen abundance, oxygen deficiency and intermediate oxygen state conditions. The possible mechanism for incorporation of fluorine into cladding glass of optical fiber is also evaluated on the basis of the thermodynamical data. The fluorine incorporation mechanism in silica glass by the MCVD process is found to be dependent on the CCl2F2/SiCl4 ratio in the input gas mixture. Fluorine doping is found to be effective for removing the strained Si–O–Si bonds, which govern the optical transparency in deep ultra-violet (DUV) and vacuum ultra-violet (VUV) regions. The maximum refractive index depression of ?0.5 × 10?3 is obtained with incorporation of fluorine into silica cladding glass by the MCVD process using CCl2F2 as a dopant precursor with suitable flow of SiCl4 vapor along with O2 through backward deposition pass. The structure of fluorine doped silica glass preform samples containing 1.70–1.79 mol% fluorine incorporated by the MCVD process based on the analyses of 19F MAS spectra done by high-resolution 19F NMR spectroscopy reveal the presence of two distinct types of fluorine environments. The majority of the fluorine environments are formed in SiO1.5F polyhedral and less abundant species is observed to be highly unusual, yielding a fivefold coordinated silicon of the type SiO2F polyhedral which become increased with increasing the fluorine content. 相似文献
979.
980.
ZHANG Zhi-Li WANG Hong-Tao WANG Xiao-Wei MA Xiao-Yan LIU Jun-Yi R.J. Griff B.T. Golding 《有机化学》2003,23(Z1):10-10
Cobalamin-dependent methionine synthase plays a crucial role in folate metabolism and such would appear to be an excellent target for rational antifolate drug design. However, to date, no anticancer agents directed at this enzyme are available, but the enzyme is efficiently and specifically inhibited by N2O and this has proven invaluable for evaluating the biochemical consequence of enzyme inhibition and for mechanistic studies. [1,2] 2,5-Diamino-4-oxo-6-(3-butenyl) pyrimidine, a key intermediate in synthetic inhibitors of methionine synthase, was first synthesized using γbutenyl-β-ketoester and guanidine carbonate (Scheme 1). [3] 相似文献