Zur Analyse von Eisen und-Stahl

Ohne Zusammenfassung     

Evaluation of finite-plasticity theories for torsion-tension members made of tresca materials

Finite-incremental Tresca and von Mises theories are developed for solid circular-section torsion-tension members subjected to proportionate and nonproportionate loading. The materials are assumed to be isotropic and even. Two Tresca theories and a von Mises theory are compared with test data obtained from torsion-tension members. Three different kinds of steels were tested; they are hot-rolled mild steel, annealed mild steel, and hot-rolled SAE 1017 steel. The fully plastic values of axial load and torque predicted by the Tresca theories agree with the experimental results; however, the deformations, in the strain-hardening region, predicted by both of the Tresca theories were greater than observed. The von Mises theory is nonconservative in predicting the fully plastic loads of torsion members and torsion-tension members and in predicting the deformations of torsion members in the strain-hardening region, but gives good correlation between predicted and experimental deformations for the torsion-tension members in the strain-hardening region.     

Aqueous-phase synthesis of PAA in PVDF membrane pores for nanoparticle synthesis and dichlorobiphenyl degradation

This paper deals with bimetallic (Fe/Pd) nanoparticle synthesis inside the membrane pores and application for catalytic dechlorination of toxic organic compounds form aqueous streams. Membranes have been used as platforms for nanoparticle synthesis in order to reduce the agglomeration, encountered in solution phase synthesis which leads to a dramatic loss of reactivity. The membrane support, polyvinylidene fluoride (PVDF) was modified by in situ polymerization of acrylic acid in aqueous phase. Subsequent steps included ion exchange with Fe²⁺, reduction to Fe⁰ with sodium borohydride and Pd deposition. Various techniques, such as STEM, EDX, FTIR and permeability measurements, were used for membrane characterization and showed that bimetallic (Fe/Pd) nanoparticles with an average size of 20–30 nm have been incorporated inside of the PAA-coated membrane pores. The Fe/Pd-modified membranes showed a high reactivity toward a model compound, 2,2′-dichlorobiphenyl and a strong dependence of degradation on Pd (hydrogenation catalyst) content. The use of convective flow substantially reduces the degradation time: 43% conversion of dichlorobiphenyl to biphenyl can be achieved in less than 40 s residence time. Another important aspect is the ability to regenerate and reuse the Fe/Pd bimetallic systems by washing with a solution of sodium borohydride, because the iron becomes inactivated (corroded) as the dechlorination reaction proceeds.     

Structure, stability and dissociation of silanitriles RSiN (R = H2B, H2N, H2P)

Structure, stability, and dissociation of H₂BSiN, H₂NSiN, H₂PSiN and their isomers H₂BNSi, H₂NNSi, H₂PNSi have been studied in detail using ab initio MP2 and CCSD(T) methods. After dissociation of H₂BNSi, H₂NNSi, H₂PNSi and their isomers, the fragmented atoms have been considered to be either in their ground state or in their valence excited state in various dissociation channels. Only allowed dissociations of these molecules are considered. Various dissociation channels of H₂BNSi, H₂NNSi, H₂PNSi and their isomers have been explored and interesting trends are observed for the dissociation of stable isomers H₂BNSi, H₂NNSi, H₂PNSi and less stable isomers H₂BSiN, H₂NSiN, H₂PSiN. The effect of substituents on their structural properties has been discussed. The potential energy surfaces for the RSiN ? RNSi isomerization reactions have been analyzed. The structural properties of these molecules agree well with the theoretical values wherever available.     

Modulation of residual stress in diamond like carbon films with incorporation of nanocrystalline gold

Residual stress modulation in the diamond-like carbon coatings with incorporation of gold nanoparticles was studied critically. The films were deposited on glass and Si (1 0 0) substrates by using capacitatively coupled plasma chemical vapor deposition. Stresses in the films were determined from the broadening of the optical absorption tail and were found to decrease from 2.3 GPa to 0.48 GPa with increasing gold content (2-7 at.% Au) in the DLC matrix. Gold incorporation also made the films harder than the corresponding DLC coatings. Modulation of stress with nanocrystalline gold content in the DLC matrix was related to the relative amount of sp²/sp³ content in the DLC films.     

A possible connection between neutrino mass generation and the lightness of a NMSSM pseudoscalar

One of the interesting properties of the NMSSM is that it can accommodate a light pseudoscalar of order 10 GeV. However, such scenarios are challenged by several experimental constraints, especially those related to the fermionic decays of the pseudoscalar. In this Letter, we extend the NMSSM field content by two gauge singlets, with lepton numbers +1 and −1. This serves the twin purpose of generating neutrino masses via the inverse seesaw mechanism and keeping the option of a very light pseudoscalar experimentally viable by opening dominant invisible decay channels of the pseudoscalar which help it evade the existing bounds.     

All particle primary nucleon spectrum derived from the latest jacee data

The all particle primary nucleon spectrum has been estimated on the basis of the latest Japanese American Emulsion Experiments on the balloon borne emulsion chamber measurements of the fluxes of p, He, C, N, O, Ne, Mg, Si, Fe and low energy fit extrapolated results have been found to follow the power law fit of the formN(E) dE=2·03E ^–2·7 dE (cm² s sr GeV/nucleon)^–1. The concept of nuclear fragmentation has been used to estimate the nucleon flux from nuclei spectra. The derived result agrees with the predicted primary spectrum after Yodh, Ellsworth, Stanev and Gaisser.Equipe de Recherche associée au C.N.R.S.Av. H. Fellow, on leave fromIndian Association for the Cultivation of Science, Jadavpur, Calcutta 700032, India.     

Few-valence-particle excitations around doubly magic 132Sn

Prompt γ-ray cascades in neutron-rich nuclei around doubly-magic ¹³²Sn have been studied using a ²⁴⁸Cm fission source. Yrast states located in the N = 82 isotones ¹³⁴Te and ¹³⁵I are interpreted as valence proton and neutron particle-hole core excitations with the help of shell model calculations employing empirical nucleon-nucleon interactions from both ¹³²Sn and ²⁰⁸Pb regions.     

Studies on elemental charge-changing cross-section for relativistic U+Al collisions using CR-39 (DOP) detector

Summary A search has been made on the charge-changing partial cross-sections by using 0.927 GeV/n²³⁸U ion from LBL BEVALAC projected at an angle 30° on²⁷Al target and CR-39 (DOP) was used as analyser. The irradiated plastic sheets were duly etched for one hour in 6.25N NaOH solution and about 1680 cone lengths at both the surfaces of the CR-39 (DOP) sheets were optically measured. The cone length distribution exhibits the existence of U fragments in the charge range 84≤Z≤91 and the estimated partial cross-sections range from 60 to 400 mb. The present data are in accord with the fit to the extrapolated data of Binnset al.