Spectrophotometric studies of copper (II)—bis-2-pyridyl glycol complex

An aqueous solution ofbis-2-pyridyl glycol forms a deep blue water-soluble complex with an aqueous solution of copper (II) salts. The complex has an absorption maximum at 600–650 mµ between pH range 3·0–8·7. The complex is stable for four days and obeys Lambert-Beer’s law in the concentration range of 5·08–50·80 ppm. of copper (II) in solution. The optical density of the complex remains constant between pH 3·8–5·9. The molar composition as determined by the method of continuous variation and by the slope ratio method has been found to be 1:1. The limits of interference due to some foreign ions during the estimation of copper (II) have been determined.     

Bose-Einstein condensates in rotating lattices

Strongly interacting bosons in a two-dimensional rotating square lattice are investigated via a modified Bose-Hubbard Hamiltonian. Such a system corresponds to a rotating lattice potential imprinted on a trapped Bose-Einstein condensate. Second-order quantum phase transitions between states of different symmetries are observed at discrete rotation rates. For the square lattice we study, there are four possible ground-state symmetries.     

Search for ZH → l+ l- bb production in 4.2 fb(-1) of pp collisions at sqrt[s] =1 .96 TeV

We present a search for the standard model Higgs boson produced in association with a Z boson in 4.2 fb(-1) of pp collisions, collected with the D0 detector at the Fermilab Tevatron at sqrt[s] =1 .96 TeV. Selected events contain one reconstructed Z → e+ e- or Z → μ+ μ- candidate and at least two jets, including at least one b-tagged jet. In the absence of an excess over the background expected from other standard model processes, limits on the ZH cross section multiplied by the branching ratios are set. The limit at M(H) = 115 GeV is a factor of 5.9 larger than the standard model prediction.     

PAST AND FUTURE MANAGEMENT OF A COLLAPSED FISHERY: THE BAY OF BISCAY ANCHOVY

Abstract We analyze the efficiency of the international management of the Bay of Biscay anchovy. While a sharing agreement between France and Spain has been in place since 1992, the fish stock collapsed in 2005 and the fishery closed from 2005 to spring 2010. We consider differences in production technologies between both countries and calibrate our model using data from 1987 to 2009. Our results suggest two sources of rent dissipation under the existing sharing agreement: inefficient quota allocation and production inefficiencies due to inflexible national regulations. We discuss several alternatives to improve management.     

Indentation of transversely isotropic power-law hardening materials: computational modelling of the forward and reverse problems

Using a combination of dimensional analysis and large deformation finite element simulations of triple indentations of 120 materials, a framework for capturing the indentation response of transversely isotropic materials is developed. By considering 4800 combinations of material properties within the bounds of the original set of 120 materials, forward algorithms that predict the indentation response of materials and reverse algorithms that predict the materials’ elastic and plastic properties from experimentally measured indentation responses are formulated for both longitudinal and transverse indentations. Issues of accuracy, reversibility, uniqueness and sensitivity within the context of the indentation of transversely isotropic materials are addressed carefully. Using 1400 combinations of material properties, it is demonstrated that there is perfect reversibility between the material properties and their indentation responses as predicted by the forward and reverse algorithms. On average, the differences between the results of the finite element analysis and those predicted by the forward algorithms for longitudinal or transverse indentations are less than 1%, thus demonstrating the high accuracy and uniqueness of the forward analysis. For longitudinal and transverse indentations, the reverse algorithms provide accurate results in most cases with an average error of 3 and 6%, respectively. A sensitivity analysis with a ±2% variation in the material properties in the forward algorithm and ±2% variation in the indentation responses in the reverse algorithms demonstrated the robustness of the algorithms developed in the present study, with the longitudinal indentations providing relatively less sensitivity to variability in indentation responses as compared to the transverse indentations.     

Transformation of a [4+6] Salicylbisimine Cage to Chemically Robust Amide Cages

In recent years, interest in shape‐persistent organic cage compounds has steadily increased, not least because dynamic covalent bond formation enables such structures to be made in high to excellent yields. One often used type of dynamic bond formation is the generation of an imine bond from an aldehyde and an amine. Although the reversibility of the imine bond formation is advantageous for high yields, it is disadvantageous for the chemical stability of the compounds. Amide bonds are, in contrast to imine bonds much more robust. Shape‐persistent amide cages have so far been made by irreversible amide bond formations in multiple steps, very often accompanied by low yields. Here, we present an approach to shape‐persistent amide cages by exploiting a high‐yielding reversible cage formation in the first step, and a Pinnick oxidation as a key step to access the amide cages in just three steps. These chemically robust amide cages can be further transformed by bromination or nitration to allow post‐functionalization in high yields. The impact of the substituents on the gas sorption behavior was also investigated.     

Search for long-lived particles decaying into electron or photon pairs with the D0 detector

In this Letter we report on a search for long-lived particles that decay into final states with two electrons or photons. Such long-lived particles arise in a variety of theoretical models, such as hidden valleys and supersymmetry with gauge-mediated breaking. By precisely reconstructing the direction of the electromagnetic shower we are able to probe much longer lifetimes than previously explored. We see no evidence of the existence of such long-lived particles and interpret this search as a quasi model-independent limit on their production cross section, as well as a limit on a long-lived fourth generation quark.     

Observation of ZZ production in p-p collisions at sqrt s=1.96 TeV

We present an observation for ZZ-->l+l-l'+l'- (l, l'=e or mu) production in p[over]p collisions at a center-of-mass energy of sqrt[s]=1.96 TeV. Using 1.7 fb(-1) of data collected by the D0 experiment at the Fermilab Tevatron Collider, we observe three candidate events with an expected background of 0.14(+0.03)_(-0.02) events. The significance of this observation is 5.3 standard deviations. The combination of D0 results in this channel, as well as in ZZ-->l+l- nu[over]nu, yields a significance of 5.7 standard deviations and a combined cross section of sigma(ZZ)=1.60+/-0.63(stat)+0.16_-0.17(syst) pb.     

EPR Evidence for Premonitory Charge-Ordering Fluctuations in Nanomanganite Pr0.57Ca0.41Ba0.02MnO3

Electron paramagnetic resonance (EPR) and magnetic properties of nanocrystalline Pr_0.57Ca_0.41Ba_0.02MnO₃ are studied and compared with those of the bulk material. The nanoscale samples prepared by the sol–gel method were annealed at different temperatures to obtain particles of different sizes. The crystallite and particle sizes were estimated by X-ray diffraction and transmission electron microscopy and found to be approximately equal to 30, 60 and 100 nm. Magnetization studies on the 60 and 100 nm particles show charge-ordering at 230 K similar to the bulk sample prepared by solid-state reaction, while in the 30 nm particles the charge-ordering signature is absent. At low temperatures all the three nanosamples show ferromagnetic transitions. This result is confirmed by the EPR intensity behavior as well. However, the EPR line width, which is reflective of the spin dynamics, shows a shallow minimum for the 30 nm particles at the temperature of 230 K, corresponding to the charge-ordering transition. We interpret this result as an indication of the presence of charge-ordering fluctuations in the nanoparticles of 30 nm size even though the static charge order is absent, thus heralding the occurrence of charge order in the larger particles. Authors' address: Subray V. Bhat, Department of Physics, Indian Institute of Science, Bangalore 560012, India