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11.
Designing Excited States: Theory‐Guided Access to Efficient Photosensitizers for Photodynamic Action
12.
Reaction of thiophene-2-methylamine with one or two equivalents of PPh2Cl in the presence of NEt3, proceeds in thf to give thiophene-2-(N-diphenylphosphino)methylamine, 1a and thiophene-2-(N,N-bis(diphenylphosphino))methylamine, 2a respectively, under anaerobic conditions. Oxidations of 1a and 2a with aqueous hydrogen peroxide, elemental sulfur or gray selenium in thf gives the corresponding oxides, sulfides and selenides [Ph2P(E)NHCH2-C4H3S] (E: O 1b, S 1c, Se 1d) and [(Ph2P(E))2NCH2-C4H3S], (E: O 2b, S 2c, Se 2d) respectively, in high yield. Furthermore, two novel Ru(II) complexes with the P-N ligands 1a and 2a were synthesized starting with the complex [Ru(η6-p-cymene)(μ-Cl)Cl]2. The complexes were fully characterized by analytical and spectroscopic methods. 31P-{1H} NMR, DEPT, 1H-13C HETCOR or 1H-1H COSY correlation experiments were used to confirm the spectral assignments. The molecular structure of thiophene-2-(N-diphenylthiophosphino)methylamine was also elucidated by single-crystal X-ray crystallography. Following activation by NaOH, compounds 3 and 4 catalyze the transfer hydrogenation of acetophenone derivatives to 1-phenylethanol derivatives in the presence of iso-PrOH as the hydrogen source. [Ru(Ph2PNHCH2-C4H3S)(η6-p-cymene)Cl2], 3 and [Ru((PPh2)2NCH2-C4H3S)(η6-p-cymene)Cl]Cl, 4 complexes are suitable catalyst precursors for the transfer hydrogenation of acetophenone derivatives in 0.1 M iso-PrOH solution. Notably 4 acts as an excellent catalyst giving the corresponding alcohols in excellent conversions up to 99% (TOF ? 744 h−1). This transfer hydrogenation is characterized by low reversibility under the experimental conditions. 相似文献
13.
Sevgi Tatar Ulu 《中国化学》2011,29(6):1256-1260
A sensitive, simple and selective high‐performance liquid chromatographic (HPLC) method was developed for the determination of ciprofloxacin in biological fluids. The method is based on the reaction between the drug and 4‐chloro‐7‐nitrobenzofurazan (NBD‐Cl) in borate buffer of pH 9.0 to yield a highly fluorescent derivative that is measured at 535 nm after excitation at 464 nm. The calibration curves were linear over the concentration ranges of 25–3000 and 50–3000 ng·mL?1 for plasma and urine, respectively. The mean recovery of ciprofloxacin from plasma and urine was 98.37% and 98.40%, respectively. The method was found to be sensitive, precise, accurate, and reproducible. All of the validation parameters were within the acceptance range. 相似文献
14.
In this paper the non-existence of global solutions of two fourth-order hyperbolic equations with dynamic boundary conditions is considered. The method of proof makes use of the generalized convexity method due to Ladyzhenskaya and Kalantarov [4]. 相似文献
15.
The Raman spectroscopy technique was used to characterize the microstructure and the crystallization properties of the as‐cast and heat‐treated binary TeO2 WO3, TeO2 CdF2 and ternary TeO2 CdF2 WO3 glasses and glass ceramics. The results were compared with those obtained by using the X‐ray diffraction technique. The effect of the WO3 and CdF2 contents on the TeO2 glass network and the intensity ratios of the deconvoluted Raman peaks were determined. The shifts in the Raman band wavenumbers and the intensity values for each band were investigated. The Raman results indicated that the glasses were mainly formed by the [TeO4] and [TeO3] units. The [TeO4] units convert to [TeO3] units with the addition of WO3 and CdF2 into tellurite glasses. All the crystalline phases such as α‐TeO2, δ‐TeO2 and γ‐TeO2 existing in the TeO2 WO3, TeO2 CdF2 and TeO2‐ WO3 CdF2 glasses were determined. The transformation of the metastable γ‐TeO2 phase into stable α‐TeO2 was observed for the (1 − x)TeO2 xWO3 (where x = 0.15, 0.20, 0.25), 0.90Te2 0.10CdF2, the 0.85TeO2 0.10CdF2 0.05WO3 and 0.80TeO2 0.10CdF2 0.10WO3 glasses, and the transformation of the metastable δ‐TeO2 phase into the stable α‐TeO2 was also observed for the TeO2 CdF2 WO3 glass system. In addition, an unidentified phase formation, labeled ε, was determined. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
16.
Enver Tatar Ramazan Dikici 《International Journal of Mathematical Education in Science & Technology》2013,44(8):1027-1036
The purpose of this study was to determine the efficiency of 4MAT method of instruction in which learning style and cerebral hemispheres are taken into account in teaching the binary operation and its properties in mathematics. The sample of this study comprised 58 ninth grade students in two separate classes in a high school. One of the classes was selected as the experimental group in which 4MAT method of instruction was used; and the other class was selected as the control group in which the traditional teaching was given, and this selection was performed randomly. The data have been obtained primarily from three scales, namely ‘mathematical knowledge test’, ‘mathematical attitude scale’ and ‘knowledge test on binary operation and its properties’. It has been determined that 4MAT method of instruction was more efficient than the traditional method in teaching of the binary operation subject in mathematics. 相似文献
17.
We consider the Cauchy problem for the fractional differential equation
D1+αu+Dβu=Δu+h(t,x)|u|p