Thermal behavior of the maleic anhydride modified poly(3-hydroxybutyrate)

Poly(3-hydroxybutyrate), PHB has been structurally modified through reaction with maleic anhydride, MA. Transesterification reaction was carried out fixing the PHB and MA and besides time and temperature the concentration of the triethylamine (used as catalyst) was changed. Glass transition, melting and crystallization temperature obtained from DSC curves and thermal degradation temperatures obtained from TG traces were used to evaluate the influence of the reaction conditions on the modification of PHB according to factorial design. On the base of the results the optimum conditions are to perform the PHB modification reaction with MA reaction at 110°C for 1 h with 5% v/v triethylamine.     

Lie point symmetries of the Lane-Emden systems

It is shown that a Lie point symmetry of the Lane-Emden system is a Noether symmetry if and only if its parameters belong to the critical hyperbola.     

A Borsuk–Ulam Theorem for Maps from a Sphere to a Generalized Manifold

H. J. Munkholm obtained a generalization for topological manifolds of the famous Borsuk–Ulam type theorem proved by Conner and Floyd. The purpose of this paper is to prove a version of Conner and Floyd's theorem for generalized manifolds.     

Influence of the loading path on the strength of fiber-reinforced composites subjected to transverse compression and shear

The influence of the loading path on the failure locus of a composite lamina subjected to transverse compression and out-of-plane shear is analyzed through computational micromechanics. This is carried out using the finite element simulation of a representative volume element of the microstructure, which takes into account explicitly fiber and matrix spatial distribution within the lamina. In addition, the actual failure mechanisms (plastic deformation of the matrix and interface decohesion) are included in the simulations through the corresponding constitutive models. Two different interface strength values were chosen to explore the limiting cases of composites with strong or weak interfaces. It was found that failure locus was independent of the loading path for the three cases analyzed (pseudo-radial, compression followed by shear and shear followed by compression) in the composites with strong and weak interfaces. This result was attributed to the fact that the dominant failure mechanism in each material was the same in transverse compression and in shear. Failure is also controlled by the same mechanisms under a combination of both stresses and the failure locus depended mainly on the magnitude of the stresses that trigger fracture rather than in the loading path to reach the critical condition.     

Hermitian quadratic eigenvalue problems of restricted rank

We consider a quadratic eigenvalue problem such that the second order term is a Hermitian matrix of rank r, the linear term is the identity matrix, and the constant term is an arbitrary Hermitian matrix . Of the n+r solutions that this problem admits, we show at least n-r to be real and located in specific intervals defined by the eigenvalues of A, whence at most 2r are nonreal occuring in possibly repeated conjugate pairs.     

Supersymmetry and bosonization in three dimensions

We discuss on the possible existence of a supersymmetric invariance in purely fermionic planar systems and its relation to the fermion-boson mapping in three-dimensional quantum field theory. We consider, as a very simple example, the bosonization of free massive fermions and show that, under certain conditions on the masses, this model displays a supersymmetric-like invariance in the low energy regime. We construct the purely fermionic expression for the supercurrent and the non-linear supersymmetry transformation laws. We argue that the supersymmetry is absent in the limit of massless fermions where the bosonized theory is non-local.     

Magnetic order in LaEuSrCuO studied [2pt] by Fe Mössbauer spectroscopy

⁵⁷Fe M?ssbauer effect studies of La_1.65Eu_0.20Sr_0.15CuO₄ doped with 0.5 at% ⁵⁷Fe performed in the temperature region 300 K > T > 4.2 K give an onset temperature for magnetic ordering of K. This temperature practically is the same as that found in Nd doped La_2-xSr_xCuO₄. It indicates that the magnetic ordering temperature in the LTT phase of rare earth (RE) doped La_2-xSr_xCuO₄ is independent of the RE moment. The direction of the ⁵⁷Fe magnetic moment in the magnetically ordered state is within the CuO₂ plane, while it has been found to be parallel to the c-axis in Nd doped La_2-xSr_xCuO₄. Received: 23 June 1998 / Accepted: 14 July 1998     

Annealing effects on the magnetization of Co–Ni–B amorphous nanoparticles

Chemically prepared (Co_xNi_1−x)_1−yB_y (x=0.5, 0.75, 1; y≈0.4) amorphous fine particles were characterized by X-ray diffraction, DTA and TGA, and in situ magnetic measurement as a function of annealing temperature in an inert atmosphere. Magnetic measurement performed in as-prepared and 150°C annealed samples shows an increase of the saturation magnetization and magnetic moment after thermal treatment. Room temperature magnetization increases by factors of 3.5, 1.8, and 1.5, for x=0.5, 0.75, and 1, respectively. These measurements may indicate a local re-ordering of the amorphous phase at temperatures much lower than the full crystallization temperature.     

Infrared and Raman spectroscopic investigation of Eu3+-doped mono and Di-urethanesil hybrid siliceous materials

The general features of two series of sol-gel derived materials, designatedurethanesils (Ut), have been investigated by infrared and Raman spectroscopies with the goal of elucidating the chemical environment of the Eu³⁺ cations. The host frameworks of the two families of ormolytes studied have been represented by m-Ut(350) and d-Ut(300), where m stands for mono, d stands for di, 350 and 300 are the average molecular weights of the organic precursors (poly(ethylene glycol) methyl ether, PEGME, and poly(ethylene glycol), PEG, respectively). The hybrid matrix of the mono-xerogels is composed by a siliceous backbone bonded by means of urethane linkages (-NHC (=O)O-) to pendant methyl end capped oligopolymer chains with approximately 7 oxyethylene units, whereas that of the di-xerogels is based on a siliceous network grafted through urethane groups to both ends of poly(oxyethylene) segments containing about 6 (OCH₂CH₂) repeat units. Both classes of materials have been doped with europium triflate (Eu(CF₃SO₃)₃). The doped samples have been identified by m-Ut(350)_nEu(CF₃SO₃)₃ and d-Ut(300)_nEu(CF₃SO₃), where n is the molar ratio of (OCH₂CH₂) repeat units per Eu³⁺ ion. Materials with n ranging from ∞ to 5 have been analyzed. The spectral data obtained provide evidence that the cations begin to coordinate to the ether oxygen atoms of the oligopolymer chains at n=40 in the mono-urethanesils and at n=10 in the di-urethanesils. In mono-urethanesils samples with n>40 and in di-urethanesils materials with n>10, the Eu³⁺ coordinate exclusively to the carbonyl oxygen atoms of the urethane linkages. Paper presented at the 8th EuroConference on Ionics, Carvoeiro, Algarve, Portugal, Sept. 16–22, 2001.