全文获取类型
收费全文 | 178篇 |
免费 | 5篇 |
专业分类
化学 | 113篇 |
数学 | 8篇 |
物理学 | 62篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2015年 | 4篇 |
2014年 | 2篇 |
2013年 | 8篇 |
2012年 | 15篇 |
2011年 | 10篇 |
2010年 | 1篇 |
2009年 | 7篇 |
2008年 | 19篇 |
2007年 | 10篇 |
2006年 | 8篇 |
2005年 | 11篇 |
2004年 | 19篇 |
2003年 | 10篇 |
2002年 | 11篇 |
2001年 | 10篇 |
2000年 | 6篇 |
1998年 | 3篇 |
1996年 | 4篇 |
1994年 | 1篇 |
1993年 | 4篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1977年 | 1篇 |
1973年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有183条查询结果,搜索用时 15 毫秒
51.
A combinatorial scaffolding procedure for the synthesis and spatial arrangement of tripartite structures was developed. [reaction: see text] 相似文献
52.
[reaction: see text] A new one-pot procedure for the synthesis of substituted pyrrolidine derivatives with commercially available cyclopropyl ketones, aldehydes, and amines by a metal iodide promoted three-component reaction was developed. 相似文献
53.
Hocherman and Rosenau conjectured that long-wave unstable Cahn-Hilliard-type interface models develop finite-time singularities when the nonlinearity in the destabilizing term grows faster at large amplitudes than the nonlinearity in the stabilizing term (Phys.˜ D 67, 1993, pp. 113–125). We consider this conjecture for a class of equations, often used to model thin films in a lubrication context, by showing that if the solutions are uniformly bounded above or below (e.g., are nonnegative), then the destabilizing term can be stronger than previously conjectured yet the solution still remains globally bounded. For example, they conjecture that for the long-wave unstable equation m > n leads to blowup. Using a conservation-of-volume constraint for the case m > n > 0, we conjecture a different critical exponent for possible singularities of nonnegative solutions. We prove that nonlinearities with exponents below the conjectured critical exponent yield globally bounded solutions. Specifically, for the above equation, solutions are bounded if m < n + 2. The bound is proved using energy methods and is then used to prove the existence of nonnegative weak solutions in the sense of distributions. We present preliminary numerical evidence suggesting that m ≥ n + 2 can allow blowup. © 1998 John Wiley & Sons, Inc. 相似文献
54.
55.
Niyazov RA Weinstein LB Adams G Ambrozewicz P Anciant E Anghinolfi M Asavapibhop B Asryan G Audit G Auger T Avakian H Bagdasaryan H Ball JP Barrow S Battaglieri M Beard K Bektasoglu M Bellis M Benmouna N Berman BL Bertozzi W Bianchi N Biselli AS Boiarinov S Bonner BE Bouchigny S Bradford R Branford D Brooks WK Burkert VD Butuceanu C Calarco JR Carman DS Carnahan B Cetina C Chen S Ciciani L Cole PL Coleman A Cords D Corvisiero P Crabb D Crannell H Cummings JP De Sanctis E Dashyan N DeVita R 《Physical review letters》2004,92(5):052303
We have measured the 3He(e,e'pp)n reaction at 2.2 GeV over a wide kinematic range. The kinetic energy distribution for "fast" nucleons (p>250 MeV/c) peaks where two nucleons each have 20% or less, and the third nucleon has most of the transferred energy. These fast pp and pn pairs are back to back with little momentum along the three-momentum transfer, indicating that they are spectators. Calculations by Sargsian and by Laget also indicate that we have measured distorted two-nucleon momentum distributions by striking one nucleon and detecting the spectator correlated pair. 相似文献
56.
A new approach to mineralization of biocompatible hydrogel scaffolds: an efficient process toward 3-dimensional bonelike composites 总被引:3,自引:0,他引:3
As a first step toward the design and fabrication of biomimetic bonelike composite materials, we have developed a template-driven nucleation and mineral growth process for the high-affinity integration of hydroxyapatite with a poly(2-hydroxyethyl methacrylate) (pHEMA) hydrogel scaffold. A mineralization technique was developed that exposes carboxylate groups on the surface of cross-linked pHEMA, promoting high-affinity nucleation and growth of calcium phosphate on the surface, along with extensive calcification of the hydrogel interior. Robust surface mineral layers a few microns thick were obtained. The same mineralization technique, when applied to a hydrogel that is less prone to surface hydrolysis, led to distinctly different mineralization patterns, in terms of both the extent of mineralization and the crystallinity of the apatite grown on the hydrogel surface. This template-driven mineralization technique provides an efficient approach toward bonelike composites with high mineral-hydrogel interfacial adhesion strength. 相似文献
57.
Rvachev MM Benmokhtar F Penel-Nottaris E Aniol KA Bertozzi W Boeglin WU Butaru F Calarco JR Chai Z Chang CC Chen JP Chudakov E Cisbani E Cochran A Cornejo J Dieterich S Djawotho P Duran W Epstein MB Finn JM Fissum KG Frahi-Amroun A Frullani S Furget C Garibaldi F Gayou O Gilad S Gilman R Glashausser C Hansen JO Higinbotham DW Hotta A Hu B Iodice M Iomni R de Jager CW Jiang X Jones MK Kelly JJ Kox S Kuss M Laget JM De Leo R Lerose JJ Liatard E Lindgren R Liyanage N Lourie RW Malov S 《Physical review letters》2005,94(19):192302
We have studied the quasielastic 3He(e,e(')p)2H reaction in perpendicular coplanar kinematics, with the energy and the momentum transferred by the electron fixed at 840 MeV and 1502 MeV/c, respectively. The 3He(e,e(')p)2H cross section was measured for missing momenta up to 1000 MeV/c, while the A(TL) asymmetry was extracted for missing momenta up to 660 MeV/c. For missing momenta up to 150 MeV/c, the cross section is described by variational calculations using modern 3He wave functions. For missing momenta from 150 to 750 MeV/c, strong final-state interaction effects are observed. Near 1000 MeV/c, the experimental cross section is more than an order of magnitude larger than predicted by available theories. The A(TL) asymmetry displays characteristic features of broken factorization with a structure that is similar to that generated by available models. 相似文献
58.
Amarian M Auerbach L Averett T Berthot J Bertin P Bertozzi W Black T Brash E Brown D Burtin E Calarco J Cates G Chai Z Chen JP Choi S Chudakov E Cisbani E de Jager CW Deur A DiSalvo R Dieterich S Djawotho P Finn JM Fissum K Fonvieille H Frullani S Gao H Gao J Garibaldi F Gasparian A Gilad S Gilman R Glamazdin A Glashausser C Goldberg E Gomez J Gorbenko V Hansen JO Hersman B Holmes R Huber GM Hughes E Humensky B Incerti S Iodice M Jensen S Jiang X Jones C Jones G Jones M Jutier C Ketikyan A 《Physical review letters》2004,93(15):152301
The generalized forward spin polarizabilities gamma(0) and delta(LT) of the neutron have been extracted for the first time in a Q2 range from 0.1 to 0.9 GeV2. Since gamma(0) is sensitive to nucleon resonances and delta(LT) is insensitive to the Delta resonance, it is expected that the pair of forward spin polarizabilities should provide benchmark tests of the current understanding of the chiral dynamics of QCD. The new results on delta(LT) show significant disagreement with chiral perturbation theory calculations, while the data for gamma(0) at low Q2 are in good agreement with a next-to-leading-order relativistic baryon chiral perturbation theory calculation. The data show good agreement with the phenomenological MAID model. 相似文献
59.
60.