全文获取类型
收费全文 | 980篇 |
免费 | 24篇 |
国内免费 | 2篇 |
专业分类
化学 | 617篇 |
晶体学 | 3篇 |
力学 | 22篇 |
数学 | 52篇 |
物理学 | 312篇 |
出版年
2019年 | 6篇 |
2018年 | 5篇 |
2017年 | 8篇 |
2016年 | 21篇 |
2015年 | 13篇 |
2014年 | 15篇 |
2013年 | 39篇 |
2012年 | 44篇 |
2011年 | 62篇 |
2010年 | 31篇 |
2009年 | 29篇 |
2008年 | 45篇 |
2007年 | 48篇 |
2006年 | 50篇 |
2005年 | 59篇 |
2004年 | 38篇 |
2003年 | 29篇 |
2002年 | 29篇 |
2001年 | 30篇 |
2000年 | 25篇 |
1999年 | 13篇 |
1998年 | 11篇 |
1997年 | 9篇 |
1996年 | 10篇 |
1995年 | 10篇 |
1994年 | 14篇 |
1993年 | 19篇 |
1992年 | 19篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1986年 | 9篇 |
1985年 | 6篇 |
1984年 | 7篇 |
1983年 | 9篇 |
1982年 | 17篇 |
1981年 | 10篇 |
1980年 | 17篇 |
1979年 | 18篇 |
1978年 | 24篇 |
1977年 | 9篇 |
1976年 | 8篇 |
1975年 | 13篇 |
1974年 | 13篇 |
1973年 | 16篇 |
1972年 | 14篇 |
1971年 | 5篇 |
1970年 | 6篇 |
1968年 | 7篇 |
排序方式: 共有1006条查询结果,搜索用时 15 毫秒
101.
102.
We reformulate the leaky mode condition of planar Bragg waveguides as two simple, separate conditions on the propagation constant; a phase match condition and a loss formula. These relations enable efficient numerical calculations of the mode properties. Furthermore, we use the phase match condition as a starting point to discuss the dispersion of waveguides with advanced cladding structures. In particular, we point out that chirped claddings, where the effective reflection point is dependent on frequency, do not give dispersion characteristics significantly different from metallic waveguides or waveguides with periodic claddings. 相似文献
103.
In this study a comparison between GaP layers, grown by metalorganic vapour phase epitaxy on either (111) oriented GaP substrates or (001) oriented GaP substrates, is made with respect to the near-band-edge luminescence. Spectrally resolved cathodoluminescence, CL, images were recorded at ˜ 25 K with detection on either the bound exciton emission or the donor-to-acceptor pair emission. The intensity variations observed in the CL images are interpreted in terms of aggregation of impurities around threading dislocations. Contrary to the layers grown on (001) oriented substrates, the layers grown on (111) oriented substrates show a segregation effect of the acceptor constituent involved in the donor-to-acceptor pair emission. 相似文献
104.
Castro EV Novoselov KS Morozov SV Peres NM dos Santos JM Nilsson J Guinea F Geim AK Neto AH 《Physical review letters》2007,99(21):216802
We demonstrate that the electronic gap of a graphene bilayer can be controlled externally by applying a gate bias. From the magnetotransport data (Shubnikov-de Haas measurements of the cyclotron mass), and using a tight-binding model, we extract the value of the gap as a function of the electronic density. We show that the gap can be changed from zero to midinfrared energies by using fields of less, approximately < 1 V/nm, below the electric breakdown of SiO2. The opening of a gap is clearly seen in the quantum Hall regime. 相似文献
105.
Bertil Storåkers Denis Elaguine 《Journal of the mechanics and physics of solids》2005,53(6):1422-1447
Axisymmetric contact at finite Coulomb friction and arbitrary profiles is examined analytically and numerically for dissimilar linear elastic solids. Invariance and generality are aimed at and an incremental procedure is developed resulting in a reduced benchmark problem corresponding to a rigid flat indentation of an elastic half-space. The reduced problem, being independent of loading and contact region, was solved by a finite element method based on a stationary contact contour and characterized by high accuracy. Subsequently, a tailored cumulative superposition procedure was developed to resolve the original problem to determine global and local field values. Save for the influence of the coefficients of friction and contraction ratio, it is shown that at partial slip the evolving relative stick-slip contour is independent of any convex and smooth contact profile at monotonic loading. For flat and conical profiles with rounded edges and apices, results are illustrated for relations between force, depth and contact contours together with surface stress distributions. The solution for dissimilar solids in a full space is transformed to a half-space problem and solved for a combination of material parameters in order to first determine interface traction distributions. Subsequently, full field values for the two solids were computed individually. In order to predict initiation of fracture and plastic flow, results are reported for the location and magnitude of maximum tensile stress and effective stress, respectively, for a range of geometrical and material parameters. In two illustrations, predicted results are compared with experimental findings related to initiation of brittle fracture and load-depth relations at nanoindentation. 相似文献
106.
Large eddy simulations of natural convection along a vertical isothermal surface have been carried out using a parallel CFD code SMAFS (Smoke Movement And Flame Spread) developed by the first author to study the dynamics of the natural convection flow and the associated convective heat transfer, with sub-grid scale turbulence modeled using the Smagorinsky model. In the computation, the filtered governing equations are discretized using finite volume method, with the variables at the cell faces in the finite volume discrete equations approximated by a second order bounded QUICK scheme and the diffusion term computed based on central difference scheme. The computation was time marched explicitly, with momentum equations solved based on a second order fractional-step Adams–Bashford scheme and enthalpy computed using a second order Runge–Kutta scheme. The Poisson equation for pressure from the continuity equation was solved using a multi-grid solver. The results including the temperature and velocity profiles of the boundary layer and the local heat transfer rate are analyzed. Comparison is made with experimental data and good agreement is found. 相似文献
107.
Jonas Nilsson Fredrik Noborn Alejandro Gomez Toledo Waqas Nasir Carina Sihlbom Göran Larson 《Journal of the American Society for Mass Spectrometry》2017,28(2):229-241
Purification and liquid chromatography-tandem mass spectrometry (LC-MS/MS) characterization of glycopeptides, originating from protease digests of glycoproteins, enables site-specific analysis of protein N- and O-glycosylations. We have described a protocol to enrich, hydrolyze by chondroitinase ABC, and characterize chondroitin sulfate-containing glycopeptides (CS-glycopeptides) using positive mode LC-MS/MS. The CS-glycopeptides, originating from the Bikunin proteoglycan of human urine samples, had ΔHexAGalNAcGlcAGalGalXyl-O-Ser hexasaccharide structure and were further substituted with 0-3 sulfate and 0-1 phosphate groups. However, it was not possible to exactly pinpoint sulfate attachment residues, for protonated precursors, due to extensive fragmentation of sulfate groups using high-energy collision induced dissociation (HCD). To circumvent the well-recognized sulfate instability, we now introduced Na+ ions to form sodiated precursors, which protected sulfate groups from decomposition and facilitated the assignment of sulfate modifications. Sulfate groups were pinpointed to both Gal residues and to the GalNAc of the hexasaccharide structure. The intensities of protonated and sodiated saccharide oxonium ions were very prominent in the HCD-MS2 spectra, which provided complementary structural analysis of sulfate substituents of CS-glycopeptides. We have demonstrated a considerable heterogeneity of the bikunin CS linkage region. The realization of these structural variants should be beneficial in studies aimed at investigating the importance of the CS linkage region with regards to the biosynthesis of CS and potential interactions to CS binding proteins. Also, the combined use of protonated and sodiated precursors for positive mode HCD fragmentation analysis will likely become useful for additional classes of sulfated glycopeptides. 相似文献
108.
Barwick Vicki Ellison Stephen L. R. Gjengedal Elin Magnusson Bertil Molinier Olivier Patriarca Marina Sibbesen Lorens Vanlaethem Nicole Vercruysse Isabelle 《Accreditation and quality assurance》2017,22(5):253-263
Accreditation and Quality Assurance - Eurachem held a workshop on method validation in analytical sciences in Gent, Belgium, on 9–10 May 2016. A summary of the working group discussions is... 相似文献
109.
Dag Viktor Nilsson 《Mathematical Methods in the Applied Sciences》2017,40(4):1053-1080
We consider a two‐dimensional inviscid irrotational flow in a two layer fluid under the effects of gravity and interfacial tension. The upper fluid is bounded above by a rigid lid, and the lower fluid is bounded below by a rigid bottom. We use a spatial dynamics approach and formulate the steady Euler equations as a Hamiltonian system, where we consider the unbounded horizontal coordinate x as a time‐like coordinate. The linearization of the Hamiltonian system is studied, and bifurcation curves in the (β,α)‐plane are obtained, where α and β are two parameters. The curves depend on two additional parameters ρ and h, where ρ is the ratio of the densities and h is the ratio of the fluid depths. However, the bifurcation diagram is found to be qualitatively the same as for surface waves. In particular, we find that a Hamiltonian‐Hopf bifurcation, Hamiltonian real 1:1 resonance, and a Hamiltonian 02‐resonance occur for certain values of (β,α). Of particular interest are solitary wave solutions of the Euler equations. Such solutions correspond to homoclinic solutions of the Hamiltonian system. We investigate the parameter regimes where the Hamiltonian‐Hopf bifurcation and the Hamiltonian real 1:1 resonance occur. In both these cases, we perform a center manifold reduction of the Hamiltonian system and show that homoclinic solutions of the reduced system exist. In contrast to the case of surface waves, we find parameter values ρ and h for which the leading order nonlinear term in the reduced system vanishes. We make a detailed analysis of this phenomenon in the case of the real 1:1 resonance. We also briefly consider the Hamiltonian 02‐resonance and recover the results found by Kirrmann. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
110.
Hertzian fracture at unloading 总被引:1,自引:0,他引:1
Denis Elaguine Bertil Storåkers 《Journal of the mechanics and physics of solids》2006,54(11):2453-2473
Hertzian fracture through indentation of flat float glass specimens by steel balls has been examined experimentally. Initiation of cone cracks has been observed and failure loads together with contact and fracture radii determined at monotonically increasing load but also during unloading phases. Contact of dissimilar elastic solids under decreasing load may cause crack inception triggered by finite interface friction and accordingly the coefficient of friction was determined by two different methods. In order to make relevant predictions of experimental findings, a robust computational procedure has been developed to determine global and local field values in particular at unloading at finite friction. It was found that at continued loading it is possible to specify in advance how the contact domain divides into invariant regions of stick and slip. The maximum tensile stress was found to occur at the free surface just outside the contact contour, the relative distance depending on the different elastic compliance properties and the coefficient of friction. In contrast, at unloading invariance properties are lost and stick/slip regions proved to be severely history dependant and in particular with an opposed frictional shear stress at the contact boundary region. This causes an increase of the maximum tensile stress at the contour under progressive unloading. Predictions of loads to cause crack initiation during full cycles were made based on a critical stress fracture criterion and proved to be favourable as compared to the experimental results. 相似文献