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排序方式: 共有949条查询结果,搜索用时 15 毫秒
941.
942.
Burel-Deschamps L Mével M Loizeau D Ayadi F Yaouanc JJ Clément JC Jaffrès PA Giamarchi P 《Journal of fluorescence》2008,18(5):835-841
We report here a study on the physicochemical properties of cationic phospholipids liposomes used for lipoplex formulation
and DNA transfer. The original cationic phospholipids synthesized in our laboratory are first presented with the liposome
formulation process. The second part deals with the liposomes fusogenic properties studied by fluorescence resonant energy
transfer (FRET). The nature of the cationic polar head and the formulation with or without a neutral colipid have a great
influence on the FRET signal. The third part reports the study of the viscosity of the liposome by fluorescence anisotropy
measurements. It has been observed that the vectors having a saturated lipid chain exhibit a more pronounced anisotropy than
those having unsaturated lipid chains. Finally, liposomes formed by a mixture of phospholipids and DC-Chol (a rigid lipid)
leads to increase the anisotropy denoting a more rigid liposome. 相似文献
943.
Two main reasons assure the transparency in the visible of some glass–ceramics (TGC): their crystal sizes are much smaller than the wavelength of light or the difference between the refractive index of glass matrix and crystal phase is small. The majority of traditional TGC have nano-size crystals and small to moderate crystallized volume fraction, usually between 3% and 70%. In this article we present a new type of transparent glass–ceramics having large (micrometric) grain size and very high crystallized volume fraction, which reaches up to 97%. Their high transparency mainly results from simultaneous variations of the glass matrix and crystal compositions during crystallization, which considerably decreases the difference between the respective refractive indexes, and this factor prevails, regardless of crystal size. Preliminary tests of their optical properties indicate that this new family of TGC can be further developed by doping with transition metals and rare-earths. 相似文献
944.
We introduce a model of interacting singularities of Navier–Stokes equations, named pinçons. They follow non-equilibrium dynamics, obtained by the condition that the velocity field around these singularities obeys locally Navier–Stokes equations. This model can be seen as a generalization of the vorton model of Novikov that was derived for the Euler equations. When immersed in a regular field, the pinçons are further transported and sheared by the regular field, while applying a stress onto the regular field that becomes dominant at a scale that is smaller than the Kolmogorov length. We apply this model to compute the motion of a pair of pinçons. A pinçon dipole is intrinsically repelling and the pinçons generically run away from each other in the early stage of their interaction. At a late time, the dissipation takes over, and the dipole dies over a viscous time scale. In the presence of a stochastic forcing, the dipole tends to orientate itself so that its components are perpendicular to their separation, and it can then follow during a transient time a near out-of-equilibrium state, with forcing balancing dissipation. In the general case where the pinçons have arbitrary intensity and orientation, we observe three generic dynamics in the early stage: one collapse with infinite dissipation, and two expansion modes, the dipolar anti-aligned runaway and an anisotropic aligned runaway. The collapse of a pair of pinçons follows several characteristics of the reconnection between two vortex rings, including the scaling of the distance between the two components, following Leray scaling . 相似文献
945.
Maxinne Denis Damien Le Borgne Rodolphe Sonnier Sylvain Caillol Cdric Totee Claire Negrell 《Molecules (Basel, Switzerland)》2022,27(15)
Novel phosphorylated cardanol molecules based on phosphonate (PO3CR) and phosphate (PO4CR) functions were synthetized. Those molecules have two main actions which are described in this article: the reduction in volatile organic compounds (VOC) and the development of flame retardant (FR) properties conferred on alkyd resins used as coatings for wood specimen. Phosphorylated cardanol compounds have been successfully grafted by covalent bonds to alkyd resins thanks to an auto-oxidative reaction. The impact of the introduction of PO3CR and PO4CR on the film properties such as drying time and flexibility has been studied and the thermal and flame retardant properties through differential scanning calorimeter, thermogravimetric analysis and pyrolysis-combustion flow calorimeter. These studies underscored an increase in the thermal stability and FR properties of the alkyd resins. In the cone calorimeter test, the lowest pHRR was obtained with 3 wt% P of phosphate-cardanol and exhibited a value of 170 KW.m−2, which represented a decrease of almost 46% compared to the POxCR-free alkyd resins. Moreover, a difference in the mode of action between phosphonate and phosphate compounds has been highlighted. The most effective coating which combined excellent FR properties and good coating properties has been obtained with 2 wt% P of phosphate-cardanol. Indeed, the film properties were closed to the POxCR-free alkyd resin and the pHRR decreased by 41% compared to the reference alkyd resin. 相似文献
946.
Abderrahmen Abdelli Oumayma Bejaoui Hajer Bougatef Sarra Ouni Assaâd Sila Hedi M'rabet Xavier Moreau Mohamed Lotfi Efrit Damien Prim 《Journal of heterocyclic chemistry》2023,60(1):96-105
An efficient synthesis of new γ,δ-insaturated δ-lactam and glutarimide derivatives bearing a phosphonomethyl group from a common allylphosphonate precursor is described. Our approach is based on a two-step procedure involving the preparation of phosphonated-1,5-ketoester and −1,5-diester followed by an amidation–heterocyclization sequence. The first step proceeds via Michael's addition of ethyl acetoacetate and diethyl malonate on an allylphosphonate starting material. The second step consists of a base-promoted intramolecular amidation-cyclization sequence with primary amines, which accounts for the construction of δ-lactams and glutarimide skeletons. We performed the evaluation of angiotensin I-converting enzyme (ACE) inhibition using an in vitro enzyme assay on six new compounds. Five compounds showed potent ACE inhibitory activity, with IC50 values ranging from 0.02 to 0.27 mg/ml. Compared with Captopril, used as a reference drug, two new glutarimide derivatives exhibited higher efficiency ACE inhibition activity. 相似文献
947.
Dr. Romain Plais Dr. Gilles Clavier Dr. Jean-Yves Salpin Dr. Anne Gaucher Prof. Dr. Damien Prim 《European journal of organic chemistry》2023,26(9):e202201281
Anion recognition represents an active area of research in supramolecular chemistry. The last two decades have been marked by spectacular advances in the design of new anion receptors. Moreover, the development of approaches combining experimental and theoretical studies has proved to be particularly relevant, allowing for a better understanding and rationalization of the phenomena involved in anion complexation processes. In this context, the combination of weak interactions within the same receptor and their synergistic effects, called cooperativity, has attracted increasing interest within the scientific community. This Review focuses on the combination of anion-π and hydrogen bonds and the emerging concept of cooperativity. The most relevant anion-π donor families are presented. The concept of cooperativity is illustrated using the most recent examples present in current literature. 相似文献
948.
Louis Godeffroy Dr. Paolo Ciocci Dr. Nathaly Ortiz Peña Dr. Damien Alloyeau Dr. Jean-Marc Noël Dr. Jean-François Lemineur Dr. Frédéric Kanoufi 《Angewandte Chemie (International ed. in English)》2023,62(29):e202304950
This work proposes a novel method for measuring the intrinsic activity of single metal-based nanoparticles towards water reduction in neutral media at industrially relevant current densities. Instead of using gas nanobubbles as proxy, the method uses optical microscopy to track the local footprint of the reaction through the precipitation of metal hydroxide, which is associated to the local pH increase during electrocatalysis. The results show the electrocatalytic activities of different types of metal nanoparticles and bifunctionnal core-shell nanostructures made of Ni and Pt, and demonstrate the importance of metal hydroxide nano-shells in enhancing electrocatalysis. This method should be generalizable to any electrocatalytic reaction involving pH changes such as nitrate or CO2 reduction. 相似文献
949.
Nathan Downs Nawin Raj Jennifer Vanos Alfio V. Parisi Harry Butler Ravinesh Deo Damien Igoe Benjamin Dexter Melanie Beckman-Downs Joanna Turner Stijn Dekeyser 《Photochemistry and photobiology》2023,99(4):1193-1207
Current shading strategies used to protect outdoor playgrounds from harmful solar radiation include the placement of artificial cloth weaves or permanent roofing over a playground site, planting trees in proximity to playground equipment, and using vegetation or surface texture variations to cool playground surfaces. How and where an artificial shade structure is placed or a tree is planted to maximize the shade protection over specific playground areas, requires careful assessment of local seasonal sun exposure patterns. The Playground Shade Index (PSI) is introduced here as a design metric to enable shade and solar ultraviolet exposure patterns to be derived in an outdoor space using conventional aerial views of suburban park maps. The implementation of the PSI is demonstrated by incorporating a machine learning design tool to classify the position of trees from an aerial image, thus enabling the mapping of seasonal shade and ultraviolet exposure patterns within an existing 7180 m2 parkland. This is achieved by modeling the relative position of the sun with respect to nearby buildings, shade structures, and the identified evergreen and deciduous tree species surrounding an outdoor playground. 相似文献