Two-loop virtual top-quark effect on Higgs-boson decay to bottom quarks

In most of the mass range encompassed by the limits from the direct search and the electroweak precision tests, the Higgs boson of the standard model preferably decays to bottom quarks. We present, in analytic form, the dominant two-loop electroweak correction, of O(GF2mt4), to the partial width of this decay. It amplifies the familiar enhancement due to the O(GFmt2) one-loop correction by about +16% and thus more than compensates the screening by about -8% through strong-interaction effects of order O(alphasGFmt2).     

Cyanines comprising barbiturate group facilitate NIR-light assisted ATRP under anaerobic and aerobic conditions at two wavelengths using Fe(III) catalyst

Cyanines with heptamethine pattern namely 5-(6-(2-(3-ethyl-1,1-dimethyl-1H-benzo[e]indol-2(3H)-ylidene)ethylidene)-2-(2-(3-ethyl-1,1-dimethyl-1H-benzo[e]indol-3-ium-2yl) vinyl) cyclo-hex-1-en-1-yl)-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-olate comprising a barbiturate group facilitate controlled radical polymerization using FeBr₃ in the ppm range applying radiation at 790 nm. Tris(4-methoylphenyl)phosphine, Tris(2-pyridylmethyl)amine or tetrabutylammonium bromide served as ligand. The latter showed the best performance resulting in a system needing no amino nitrogen for photo-ATRP. Ethyl α-bromophenylacetate worked as initiator. The cyanine interacts with FeBr₃ resulting in a new absorption band at 877 nm that also resulted in formation of polymer exhibiting similar molecular weight but higher dispersity compared to that obtained by 790 nm radiation by exposure with a light-emitting diode (LED) emitting at 870 nm. This explains the reactivity of the system while other cyanines such as 2-[2-[3-[2-(1,3-Dihydro-1,3,3-trimethyl-2H-indol-2-ylidene)-ethylidene]-2-(1-phenyl- 1H-tetrazol-5-ylsulfanyl)-1-cyclohexen-1-yl]-ethenyl]-1,3,3-trimethyl-3H-indolium chloride showed no activity by exposure at 790 nm in combination with FeBr₃/Br⁻. Controlled radical polymerization was confirmed by successful chain extension and block copolymerization experiments resulting in polymers, which exhibit a dispersity of about 1.3. Interestingly, the new system comprising the aforementioned barbiturate substituted cyanine, FeBr₃/Br⁻ and ethyl α-bromophenylacetate showed a certain oxygen tolerance. Polymers obtained exhibited similar dispersity as those made under inert conditions.     

Physical boundaries within aggregates – differences between amorphous,para‐crystalline,and crystalline Structures

The structural properties of finely divided inorganic materials such as metal and metalloid oxides, silicates or carbonates of both synthetic and natural origin are compared by means of electron microscopy and tomography. The structure of the outer surfaces of various compact or compacted agglomerates may suggest some striking similarities between various amorphous silica on the one hand and crystalline titania and alumina on the other however the details of the interior fine structure are completely different. Inside of the crystalline aggregates of, for example, alumina and titania distinct grain boundaries between the inter‐grown primary crystallites exist. Also physical boundaries between different solid phases and crystalline/amorphous transitions in core/shell structures can occur. No physical grain or phase boundaries were found inside of synthetic amorphous silica or para‐crystalline carbon black thus, the aggregate is the constituent particle. Synthetic amorphous silica from different production technologies (fumed/pyrogenic, precipitated, aerogel, gel) may exhibit different macro‐morphology but distinct similarities of the amorphous silica networks. Computational studies on silica and titania underline the stability of constituent particles and aggregates as observed by means of TEM after dispersing the original materials by ultra‐sonication.     

Command surfaces, 20. Fixation of surface-assisted homogeneous alignment of nematic liquid crystals by cationic photopolymerization

The surface-assisted alignment of a nematic liquid crystal yields a persistent ordered structure upon cationic photopolymerization of liquid-crystalline epoxides. Linearly polarized light irradiation of a photocrosslinkable polymer containing azobenzene moieties played a crucial role in this procedure since the photoinduced alignment is not deteriorated by heating for polymerization.     

Comparison of two force fields in MD-simulations of α-helical structures in keratins

Molecular dynamic (MD) simulations based on two different force fields, CVFF and CFF91, were carried out in order to check their feasibility for the structural investigation of the wool intermediate filament (IF) monomeric unit. Selecting an ideal α-helix as start conformation, all MD-simulations with CVFF in vaccum show the α-helix to be unstable. Independently of the amino acid sequence of the α-helix, a new helical structure with a larger diameter arises during the MD-simulation, due to a shift of the intrahelical hydrogen bonds. However in simulations with surrounding water the α-helix remains stable throughout the simulations with the CVFF force field. In contrast to this, MD-simulations in vaccume based on the CFF91 force field are able to determine different stabilities for the α-helical start conformation of various IF-segments, that agree well with secondary structure predictions. The simulation results obtained with CFF91 in vacuum can like wise be verified using an explicit water environment. We found that higher partial charges attributed to the atoms of the amide groups that form the intrahelical hydrogen bonds are the reason for the superiority of the CFF91 force field.     

Cyclization reaction of polyacrylonitrile and poly(styrene-co-acrylonitrile) studied by PVT measurements

Pressure, volume, temperature (PVT) measurements reveal that during the intramolecular cyclization reaction of poly(acrylonitrile) (PAN) and poly(styrene-co-acrylonitrile) (SAN) the volume decreases. This volume contraction becomes smaller with increasing styrene content in the random copolymers and should be related to the simultaneous decrease of longer acrylonitrile homo-sequences. The onset temperature of the cyclization reaction is raised with higher styrene contents in the random copolymers. Thus, it can be excluded that the cyclization reaction has a major influence on the discoloration process of SAN samples having relatively small acrylonitrile contents (less than 50 mol-%) during thermal annealing below 300°C.     

NMR chemical shifts in amino acids: effects of environments in the condensed phase

We present calculations of NMR chemical shifts in crystalline phases of some representative amino acids such as glycine, alanine, and alanyl-alanine. We explore the effects of environment on the chemical shifts in selected glycine geometries ranging from the crystalline phase to completely isolated molecules. In the crystalline and dilute molecular limits, the calculated distinct NMR chemical shifts are attributed to intermolecular hydrogen-bonds and dipole electric field effects, respectively.     

Zur Konstruktion eindimensionaler homogener Markoffscher Prozesse

Summary The aim of this paper is the construction of a class of semi-groups of homogeneous onedimensional Markov processes with respect to a given infinitesimal operator. This is done namely by the method of stochastic integration represented in the book of Skorokhod. The Lipschitzian conditions — needed there — are weakened to uniform continuity by a method of approximation of semi-groups. Also to these semi-groups we can construct Markov processes as solutions of stochastic integral equations. The representation is connected with the result of Meyer, Watanabe, Motoo.     

Frobeniusautomorphismen endlicher Gruppen

Ohne ZusammenfassungHerrnGottfried Köthe zum 60. Geburtstag am 25. 12. 1965 gewidmet