1,1‐Organoboration of bis(trimethylstannyl)ethyne with trimethylsilyl‐ and dimethylsilyl‐dialkylboryl‐substituted alkenes: organometallic‐substituted allenes

The reactions of bis(trimethylstannyl)ethyne, Me₃Sn–C?C–SnMe₃ ( 4 ), with trimethylsilyl‐ or dimethylsilyl‐dialkylboryl‐substituted alkenes 1 – 3 afford organometallic‐substituted allenes 5 , 6 and 8 , 9 in high yield. In the case of (E)‐2‐trimethylsilyl‐3‐diethylboryl‐2‐pentene ( 1) , a butadiene derivative 7 could be detected as an intermediate prior to rearrangement into the allene. All reactions were monitored by ²⁹Si and ¹¹⁹Sn NMR, and the products were characterized by an extensive NMR data set (¹H, ¹¹B, ¹³C, ²⁹Si, ¹¹⁹Sn NMR). Copyright © 2003 John Wiley & Sons, Ltd.     

The core of zero-dimensional monomial ideals

The core of an ideal is the intersection of all its reductions. We describe the core of a zero-dimensional monomial ideal I as the largest monomial ideal contained in a general reduction of I. This provides a new interpretation of the core in the monomial case as well as an efficient algorithm for computing it. We relate the core to adjoints and first coefficient ideals, and in dimension two and three we give explicit formulas.     

Performance analysis of 1300 nm SLEDs – impact of temperature and length scaling

The impact of self-heating and cavity length on the spectral emission properties of SLEDs is investigated using a state-of-the-art simulation tool. Simulated data are compared to measurements for two InP-based benchmark devices operating around 1300 nm, and excellent agreement is achieved in either case.     

40 GHz Mode-Locked Semiconductor Lasers: Theory, Simulations and Experiment

We study both theoretically and experimentally typical operation regimes of 40 GHz monolithic mode-locked lasers. The underlying Traveling Wave Equation model reveals quantitative agreement for characteristics of the fundamental mode-locking as pulse width and repetition frequency tuning, as well as qualitative agreement with the experiments for other dynamic regimes. Especially the appearance of stable harmonic mode-locking at 80 GHz has been predicted theoretically and confirmed by measurements. Furthermore, we derive and apply a simplified Delay-Differential-Equation model which guides us to a qualitative analysis of bifurcations responsible for the appearance and the breakup of different mode-locking regimes. Higher harmonics of mode-locking are predicted by this model as well.     

Uniform oriented matroids without the isotopy property

We give an easy general construction for uniform oriented matroids with disconnected realization space. This disproves the longstanding isotopy conjecture for simple line arrangements or order types in the plane.The research of Bernd Sturmfels and Neil White was supported in part by the Institute for Mathematics and Its Applications with funds provided by the National Science Foundation.     

Computing Final Polynomials and Final Syzygies Using Buchberger’s Gröbner Bases Method

Final polynomials and final syzygies provide an explicit representation of polynomial identities promised by Hilbert’s Nullstellensatz. Such representations have been studied independently by Bokowski [2,3,4] and Whiteley [23,24] to derive invariant algebraic proofs for statements in geometry. In the present paper we relate these methods to some recent developments in computational algebraic geometry. As the main new result we give an algorithm based on B. Buchberger’s Gröbner bases method for computing final polynomials and final syzygies over the complex numbers. Degree upper bound for final polynomials are derived from theorems of Lazard and Brownawell, and a topological criterion is proved for the existence of final syzygies. The second part of this paper is expository and discusses applications of our algorithm to real projective geometry, invariant theory and matrix theory.     

Gelfand numbers of operators with values in a Hilbert space

In the paper we prove two inequalities involving Gelfand numbers of operators with values in a Hilbert space. The first inequality is a Rademacher version of the main result in [Pa-To-1] which relates the Gelfand numbers of an operator from a Banach spaceX intol ₂ ⁿ with a certain Rademacher average for the dual operator. The second inequality states that the Gelfand numbers of an operatoru froml ₁ ^N into a Hilbert space satisfy the inequality