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51.
We study the pattern formation in a lattice of locally coupled phase oscillators with quenched disorder. In the synchronized regime quasiregular concentric waves can arise which are induced by the disorder of the system. Maximal regularity is found at the edge of the synchronization regime. The emergence of the concentric waves is related to the symmetry breaking of the interaction function. An explanation of the numerically observed phenomena is given in a one-dimensional chain of coupled phase oscillators. Scaling properties, describing the target patterns are obtained. 相似文献
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Proton-detected scalar coupling based assignment strategies in MAS solid-state NMR spectroscopy applied to perdeuterated proteins 总被引:1,自引:0,他引:1
Assignment of proteins in MAS (magic angle spinning) solid-state NMR relies so far on correlations among heteronuclei. This strategy is based on well dispersed resonances in the 15N dimension. In many complex cases like membrane proteins or amyloid fibrils, an additional frequency dimension is desirable in order to spread the amide resonances. We show here that proton detected HNCO, HNCA, and HNCACB type experiments can successfully be implemented in the solid-state. Coherences are sufficiently long lived to allow pulse schemes of a duration greater than 70 ms before incrementation of the first indirect dimension. The achieved resolution is comparable to the resolution obtained in solution-state NMR experiments. We demonstrate the experiments using a triply labeled sample of the SH3 domain of chicken α-spectrin, which was re-crystallized in H2O/D2O using a ratio of 1/9. We employ paramagnetic relaxation enhancement (PRE) using EDTA chelated CuII to enable rapid data acquisition. 相似文献
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Björn Bieniek Darius Pohl Ludwig Schultz Bernd Rellinghaus 《Journal of nanoparticle research》2011,13(11):5935-5946
The near-surface oxidation-induced lattice relaxation and compositional changes of FeNi alloy nano-particles are investigated.
Using a newly developed transfer system, the particle structure was characterised by means of aberration-corrected HR-TEM
prior to exposing the particles to ambient air. This allows for a comparison of oxidised and un-oxidised particles, respectively.
Independent of the oxidation, the surface-near and/or interface-near metal lattice was found to be expanded by up to 3%. EELS
profiles clearly reveal an enrichment of Fe at the particle surfaces. MD simulations in combination with HR-TEM contrast simulations
were conducted to investigate the effect of the Fe enrichment on the structural relaxation. The results show that a surface-near
over-stoichiometric enrichment of Fe indeed causes a dilation that counteracts a compression of the lattice at the particle
surface as obtained for homogeneously alloyed particles. Besides, the large lattice mismatch between the metallic cores and
the NiFe2O4 shells causes the formation of step dislocations in the close vicinities of the interface. In essence, the surface-near lattice
relaxation in oxide free particles is found to be due to a segregation of Fe to the surface, whereas in the case of shell–core
particles, no systematic influence of the oxide on the lattice relaxation was found. 相似文献
57.
T Blochowicz S Schramm S Lusceac M Vogel B Stühn P Gutfreund B Frick 《Physical review letters》2012,109(3):035702
We study dynamically highly asymmetric binary mixtures comprised of small methyl tetrahydrofuran (MTHF) molecules and polystyrene. Combined use of dielectric spectroscopy, ^{2}H nuclear magnetic resonance, incoherent quasielastic neutron scattering, and depolarized dynamic light scattering allows us to selectively probe the dynamics of the components in a broad dynamic range. It turns out that the mixtures exhibit two glass transitions in a wide concentration range although being fully miscible on a macroscopic scale. In between both glass transition temperatures, the dynamics of the small molecules show strong confinement effects, e.g., a crossover from Vogel-Fulcher to Arrhenius behavior of the time constants. Moreover, the dynamical behavior of small molecules close to the slow matrix is consistent with mode coupling theory predictions for a type-A glass transition, which was expected from recent theoretical and simulation studies in comparable systems. 相似文献
58.
Signatures of the non-Abelian statistics of quasiparticles in the ν=5/2 quantum Hall state are predicted to be present in the current-voltage characteristics of tunneling through one or two quantum Hall puddles of Landau filling ν(a) embedded in a bulk of filling ν(b) with (ν(a),ν(b))=(2,5/2) and (ν(a),ν(b))=(5/2,2). 相似文献
59.
The decomposition of chloroform by the combination of hydrodynamic and acoustic cavitation (Hydrodynamic-Acoustic-Cavitation/HAC) has been investigated. The flow rate and the hole diameter of the orifice plate remarkably affect the conversion of chloroform in the combined system. The conversion increases with increasing fluid velocity without any restriction. With a 2.8mm orifice plate the conversion reaches an optimal value. A synergistic effect has been obtained by the hybrid method of acoustic and hydrodynamic cavitation. The total synergistic effect achieves 17% and 73% per pass, respectively. The analysis of the energy efficiencies shows different results. Due to high optimization potential, this hybrid method can be visualized as a new step for wastewater treatment. 相似文献
60.