全文获取类型
收费全文 | 4143篇 |
免费 | 87篇 |
国内免费 | 22篇 |
专业分类
化学 | 2711篇 |
晶体学 | 25篇 |
力学 | 161篇 |
数学 | 651篇 |
物理学 | 704篇 |
出版年
2021年 | 27篇 |
2020年 | 31篇 |
2019年 | 33篇 |
2018年 | 39篇 |
2017年 | 38篇 |
2016年 | 61篇 |
2015年 | 74篇 |
2014年 | 86篇 |
2013年 | 229篇 |
2012年 | 170篇 |
2011年 | 199篇 |
2010年 | 125篇 |
2009年 | 116篇 |
2008年 | 171篇 |
2007年 | 165篇 |
2006年 | 177篇 |
2005年 | 196篇 |
2004年 | 158篇 |
2003年 | 145篇 |
2002年 | 157篇 |
2001年 | 61篇 |
2000年 | 70篇 |
1999年 | 65篇 |
1998年 | 47篇 |
1997年 | 73篇 |
1996年 | 75篇 |
1995年 | 76篇 |
1994年 | 55篇 |
1993年 | 59篇 |
1992年 | 50篇 |
1991年 | 55篇 |
1990年 | 39篇 |
1989年 | 44篇 |
1988年 | 35篇 |
1987年 | 32篇 |
1985年 | 79篇 |
1984年 | 62篇 |
1983年 | 50篇 |
1982年 | 65篇 |
1981年 | 72篇 |
1980年 | 53篇 |
1979年 | 66篇 |
1978年 | 68篇 |
1977年 | 78篇 |
1976年 | 52篇 |
1975年 | 53篇 |
1974年 | 50篇 |
1973年 | 38篇 |
1971年 | 36篇 |
1968年 | 27篇 |
排序方式: 共有4252条查询结果,搜索用时 15 毫秒
211.
212.
Dr. Sophie A.‐L. Thétiot‐Laurent Dr. Jérôme Boissier Dr. Anne Robert Prof. Dr. Bernard Meunier 《Angewandte Chemie (International ed. in English)》2013,52(31):7936-7956
After malaria, schistosomiasis (or bilharzia) is the second most prevalent disease in Africa, and is occurring in over 70 countries in tropical and subtropical regions. It is estimated that 600 million people are at risk of infection, 200 million people are infected, and at least 200 000 deaths per year are associated with the disease. All schistosome species are transmitted through contact with fresh water that is infested with free‐swimming forms of the parasite, which is known as cercariae and produced by snails. When located in the blood vessels of the host, larval and adult schistosomes digest red cells to acquire amino acids for growth and development. Vaccine candidates have been unsuccessful up to now. Against such devastating parasitic disease, the antischistosomal arsenal is currently limited to a single drug, praziquantel, which has been used for more than 35 years. Because the question of the reduction of the activity of praziquantel was raised recently, it is thus urgent to create new and safe antischistosomal drugs that should be combined with praziquantel to develop efficient bitherapies. 相似文献
213.
2,4-dichlorophenyl-4-bromomethyl-phenoxyacetate 3 was prepared by NBS treatement of 2,4-dichlorophenyl-4-methylphenoxyacetate 2. This ester is a key intermediate in the preparation of 2,4-dichlorophenyl-Nα-Fmoc-aminoacyl-4-oxymethylphenoxy-acetates suitable for anchorage of the first amino acid on amine-functionalized polymers. 相似文献
214.
The modulated phase of (C3H7NH3)CuCl4 stable between 386 and 412 K has been analyzed by single-crystal X-ray diffraction. The structure was solved in the frame of the superspace group approach. The modulation is characterized by a wavelike displacement of the CuCl4 layer. 相似文献
215.
Bis(trimethylsilyl) peroxide can be readily obtained by reaction of trimethylchlorosilane with the hexamethylenetetramine-hydrogene peroxide complex. 相似文献
216.
Aloysius Soon Joel Wallman Bernard Delley Catherine Stampfl 《Current Applied Physics》2013,13(8):1707-1712
We present a trend study of a large variety of dopants at the cation site in Cu2O (i.e. substituting Cu), focussing largely on the early 3d-, 4d-, and 5d-transition metals (TMs) in which many of them are known to be non-magnetic. We also include s-, sp- and d10-metals for comparison. We find that doping with sp-elements results in zero spin moment while dopants with a partially filled d-band show a stronger tendency to magnetize and 3d-TM dopants exhibit a larger magnetic moment than most of the 4d- and 5d-TM dopants. From this trend study, we also find a correlation between their substitution enthalpy and associated interatomic relaxations. In particular, Ti-doped Cu2O appears to be an interesting system, given its “peculiar” ability to exhibit a spin moment when doped with a non-magnetic substituent like Ti. We also find that the interaction between two doped Ti atoms in Ti2:Cu2O is predominantly antiferromagnetic, and interestingly (and unexpectedly), this interaction rapidly declines as a function of inter-dopant distance, as in the case for the magnetic late-TM dopants like Co2:Cu2O. 相似文献
217.
Mehrdad Nikravech Kamal Baba Bernard Leneindre Frédéric Rousseau 《Chemical Papers》2012,66(5):502-510
Processing the aerosol of metal salts in non-equilibrium plasma represents a promising technique that combines the advantages
of spray pyrolysis with the high reactivity of plasmas at nearlaboratory temperature in order to produce mixed-oxides and
perovskite materials. The aim of this paper is to describe the principles of this new technique and to present the various
applications and latest developments. This technique’s capacity to deposit various mixed metal oxides with precise stoichiometry
is demonstrated. It is shown that oxidant plasma species play a key role in the chemical transformation of starting materials
into oxides at laboratory temperature, while the configuration of the reactor determines the morphology and texture of the
deposited layers. Two different reactor configurations are presented. The porous layers of La
x
Sr1−x
MnO3 as the cathode for fuel cells were synthesised in a wave shock reactor configuration, while nanostructured ZnO-Al layers
to form a transparent conductive cathode for photovoltaic cells were deposited in the spray plasma reactor of the latest generation
for this technique. The experimental results emphasise the role of plasma species in the rate of chemical reactions and in
the chemical composition of the deposited layers. 相似文献
218.
ABSTRACT: The reaction of tetrabutylammonium tribromide (TBABr3) with mono and disubstituted alkynes in methanol at 20°C leads to the formation of mainly the corresponding α,α-dibromo, β,β-dimethoxyalkane and the E-(α,β)-dibromoalkene. The additions are faster using sonication. 相似文献
219.
We consider the vector space of globally differentiable piecewise polynomial functions defined on a three-dimensional polyhedral domain partitioned into tetrahedra. We prove new lower and upper bounds on the dimension of this space by applying homological techniques. We give an insight of different ways of approaching this problem by exploring its connections with the Hilbert series of ideals generated by powers of linear forms, fat points, the so-called Fröberg–Iarrobino conjecture, and the weak Lefschetz property. 相似文献
220.