Numerical simulation and validation of the Peltier pulse marking of solid/liquid interfaces

We describe a numerical approach of the solidification of binary alloys to study the motion of a crystal/melt interface submitted to current pulses involving a modification of the dopant concentration field. For the thermal aspect, the Thomson effect, the Peltier effect and Joule heating have been included in the heat flow. For the solutal segregation, our model is based on mass transports which occur in the liquid phase, namely diffusion and convection. Numerical computations are validated by comparison with experimental data and thus could find applications in the prediction of the effects of Peltier pulse marking in crystal growth.     

The structures and vibrational spectra of crystals and glasses in the silica-alumina system

Solar furnace melting and fast-quench techniques have been used to prepare SiO₂Al₂O₃ glasses to high alumina content (near 60 mol% Al₂O₃), which have been studied by Raman spectroscopy. These spectra may not be simply interpreted. The structures of crystalline compounds in the SiO₂Al₂O₃ system are discussed in relation to their vibrational spectra. On the basis of this discussion and other considerations, a structural model for the silica-alumina glass system is proposed, which is consistent with the stable or metastable immiscibility suggested along this join. The essential features of this model include a modified silica structure at low alumina content, and “structure-broken” regions at high alumina compositions, with silicon in tetrahedral coordination, but aluminium assuming a variety of bonding geometries. These are proposed to include aluminate tetrahedra with higher polymerization than simple corner-sharing, and less well-defined polyhedra of higher average coordination number.     

Real Time Imaging of Quantum and Thermal Fluctuations: The Case of a Two-Level System

A quantum system in contact with a heat bath undergoes quantum transitions between energy levels upon absorption or emission of energy quanta by the bath. These transitions remain virtual unless the energy of the system is measured repeatedly, even continuously in time. Isolating the two indispensable mechanisms in competition, we describe in a synthetic way the main physical features of thermally activated quantum jumps. Using classical tools of stochastic analysis, we compute in the case of a two-level system the complete statistics of jumps and transition times in the limit when the typical measurement time is small compared to the thermal relaxation time. The emerging picture is that quantum trajectories are similar to those of a classical particle in a noisy environment, subject to transitions à la Kramer in a multi-well landscape, but with a large multiplicative noise.     

Local electrochemical investigation of copper patina

The patination of copper is known for its complexity and heterogeneous formation. For a deeper investigation, a locally resolved surface analysis was considered. An exact determination of the accessed area and a potentiostatic control in a three-electrode configuration was reached with the use of the electrochemical microcell technique, which enables local electrochemical measurement such as local electrochemical impedance spectroscopy and cyclic voltammetry. Such a technique provides a unique way for performing the investigation of heterogeneities on electrode surfaces. The local electrochemical measurements on the artificially patinated surface have allowed distinguishing areas of different reactivity even when the analysis of the surface revealed a homogenous chemical composition of patina. Local measurements with the electrochemical microcell showed the presence of small defects on the patina layer that can be modelled by considering a hemispherical diffusion process at small active areas surrounded by larger less reactive domains.