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Doklady Physics - A new composite material based on zinc oxide photosensitized to daylight with an organic dye of the phthalocyanine group has been proposed. The photoactivity of the material... 相似文献
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S. M. Frolov V. I. Zvegintsev V. S. Ivanov V. S. Aksenov I. O. Shamshin D. A. Vnuchkov D. G. Nalivaichenko A. A. Berlin V. M. Fomin 《Doklady Physical Chemistry》2017,474(1):75-79
First experimental investigations were carried out into the detonation combustion of hydrogen in a demonstrator of an original-design air-breathing ramjet while blowing with an air flow at Mach 4 to 8 in an impulse wind tunnel, and for the first time under these conditions, continuous spin and longitudinal pulsed modes of detonation combustion of hydrogen in an annular combustor were detected. 相似文献
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E. V. Prut R. S. Smykovskaya O. P. Kuznetsova Yu. I. Deryabina V. G. Volik A. A. Berlin 《Doklady Physical Chemistry》2017,473(1):52-53
New biodegradable composites based on keratin and polyethylene have been produced under shear deformation. It has been demonstrated that the introduction of keratin leads to an increase in elastic modulus and to a decrease in ultimate tensile strength and elongation at break of the compositions. Elongation at break εb depends on the keratin dispersity; the highest εb values are observed for the compositions containing the smallest keratin particles. It has been shown that the compositions are susceptible to mold fungi; i.e., they are biodegradable. 相似文献
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Marc Ostermeier Dipl.‐Chem. Marie‐Anne Berlin Dipl.‐Chem. Robert M. Meudtner Dr. Serhiy Demeshko Dr. Franc Meyer Prof. Dr. Christian Limberg Prof. Dr. Stefan Hecht Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(33):10202-10213
2,6‐Bis(1,2,3‐triazol‐4‐yl)pyridine (btp) ligands with substitution patterns ranging from strongly electron‐donating to strongly electron‐accepting groups, readily prepared by means of Cu‐catalyzed 1,3‐dipolar cycloaddition (the “click” reaction), were investigated with regard to their complexation behavior, and the properties of the resulting transition‐metal compounds were compared. Metal–btp complexes of 1:1 stoichiometry, that is, [Ru(btp)Cl2(dmso)] and [Zn(btp)Br2], could be isolated and were crystallographically characterized: they display octahedral and trigonal‐bipyramidal coordination geometries, respectively, and exhibit high aggregation tendencies due to efficient π–π stacking leading to low solubilities. Metal–btp complexes of 1:2 stoichiometry, that is, [Fe(btp)2]2+ and [Ru(btp)2]2+, could also be synthesized and their metal centers show the expected octahedral coordination spheres. The iron compounds exhibit quite a complex magnetic behavior in the solid state including spin crossover near room temperature, and hysteresis and locking into high‐spin states on tempering at 400 K, depending on the substituents on the btp ligands. Cyclic voltammetry studies of [Ru(btp)2]2+ reveal strong modulation of the oxidation potentials by more than 0.6 V and a clear linear correlation to the Hammett constant (σpara) of the substituent at the pyridine core. Isothermal titration calorimetry was used to measure the thermodynamics of the FeII–btp complexation process and enabled accurate determination of the complexation enthalpies, which display a linear relationship with the σpara values for the terminal phenyl substituents. Detailed NMR spectroscopic studies finally revealed that in the case of FeII complexation, dynamics are rapid for all investigated btp derivatives in acetonitrile, while replacing FeII by RuII or changing the solvent to dichloromethane effectively slows down ligand exchange. The results nicely demonstrate the utility of substituent parameters, originally developed for linear free‐energy relationships to explain reactivity in organic reactions, in coordination chemistry, and to illustrate the potential to custom‐design btp ligands and complexes thereof with predictable properties. The fast equilibration of the [Fe(btp)2]2+ complexes together with their tunable stability and interesting magnetic properties should enable the design of dynamic metallosupramolecular materials with advantageous properties. 相似文献
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Ar. A. Berlin V. N. Kislenko Yu. G. Medvedevskikh 《Theoretical and Experimental Chemistry》1990,26(3):337-341
Using a kinetic model of the routes of unbranched radical-chain processes, an expression was found for the rate of the aqueous solution. The possible conditions for the occurrence of the process over a wide range of concentrations of persulfate and the organic compound were analyzed.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 26, No. 3, pp. 360–365, May–June, 1990. 相似文献
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