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101.
102.
103.
Dayal S Lou Y Samia AC Berlin JC Kenney ME Burda C 《Journal of the American Chemical Society》2006,128(43):13974-13975
The effect of linker chain length on the energy transfer from CdSe quantum dots (QDs) to silicon phthalocyanine (Pc) photodynamic therapy agents was investigated by steady-state and femtosecond time-resolved spectroscopy with 500 nm light for the specific excitation of the QD energy donor. The conjugation between the QD and the Pc was achieved with linker chains varying from 4 to 9 bond lengths by incorporating 1-6 methylene groups into the axial ligand of the Pc. With increasing chain length, the energy-transfer efficiency increased, which appears to be opposed to a purely F?rster-type resonance energy-transfer behavior that is commonly discussed for the energy transfer in QD conjugates. The obtained results provide strong evidence for a capping-layer-mediated energy transfer in the QD-based donor-acceptor conjugates. 相似文献
104.
P. P. Levin N. L. Zaichenko A. S. Tatikolov A. I. Shienok L. S. Kol’tsova I. M. Shcherbakova O. Yu. Os’kina I. R. Mardaleishvili A. O. Ait A. A. Berlin 《High Energy Chemistry》2016,50(4):259-265
Using the method of microsecond flash photolysis with UV and visible light, the spectral and kinetic characteristics of intermediate products of photolysis in toluene and methanol solutions of a new biphotochromic compound have been studied, in which two photochromic moieties, spironaphthoxazine and azomethine, are linked to each other in such a way that there is conjugation between π-electronic systems of the moieties in the ground state of the molecule. Two intermediate products have detected, whose relative efficiency of formation substantially depends on the solvent and the wavelength of excitation light. 相似文献
105.
Zubova EA Balabaev NK Musienko AI Gusarova EB Mazo MA Manevitch LI Berlin AA 《The Journal of chemical physics》2012,136(22):224906
We carry out a molecular dynamics simulation of the first stages of constrained melting in crystalline polyethylene (PE). When heated, the crystal undergoes two structural phase transitions: from the orthorhombic (O) phase to the monoclinic (M) phase, and then to the columnar (C), quasi-hexagonal, phase. The M phase represents the tendency to the parallel packing of planes of PE zigzags, and the C phase proves to be some kind of oriented melt. We follow both the transitions O→M and M→C in real time and establish that, at their beginning, the crystal tries (and fails) to pass into the partially ordered phases similar to the RI and RII phases of linear alkanes, correspondingly. We discuss the molecular mechanisms and driving forces of the observed transitions, as well as the reasons why the M and C phases in PE crystals substitute for the rotator phases in linear alkanes. 相似文献
106.
M. Venugopal B. Sankar Reddy C. Devendranath Reddy K. D. Berlin 《Journal of heterocyclic chemistry》2001,38(1):275-279
Several 2‐alkylcarbamato/thiocarbamato/aryloxy/trichloromethyl‐2,3‐dihydro‐5‐propoxy‐1H‐1,3,2‐benzodiazaphosphole 2‐oxides ( 4 and 6 ) were synthesised by reacting 4‐propoxy‐o‐phenylenediamine ( 1 ) with various N‐dichlorophosphinyl carbamates ( 3 ), aryl phosphorodichloridates ( 5a‐f ) and trichloromethyl phosphonic dichloride ( 5g ) in the presence of triethylamine at 45‐65 °C. Their ir, 1H, 13C, 31P nmr and mass spectral data are discussed. The compounds were screened for antifungal activity against Curvularia lunata and Aspergillus niger and for antibacterial activity against Bacillus subtilis and Escherichia coli. Most of these compounds exhibited moderate activity in the assays. 相似文献
107.
A. A. Berlin B. G. Gerasimov A. A. Ivanov A. P. Masliukov O. G. Selskaya L. I. Belova 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(7):991-998
The thermal and thermooxidative stability of polyisoprene containing polyazophenylene fragments of different composition was investigated. Elevated inhibiting activity of polyazophenylene -methane fragments was found to be caused by the intramolecular synergism due to the combination of the reaction of peroxy radicals with mobile hydrogen atoms of methylene bridge groups and decomposition of hydroperoxides under the influence of polyconjugated blocks. 相似文献
108.
N. V. Ulitin I. I. Nasyrov T. R. Deberdeev A. A. Berlin 《Russian Journal of Physical Chemistry B, Focus on Physics》2012,6(6):752-760
A mathematical model of the kinetics of the radical polymerization of styrene in the presence of dibenzyl trithiocarbonate by the reversible addition-fragmentation chain transfer mechanism with cross-termination of radicals and intermediates and quadratic termination of intermediates is developed. The adequacy of the polymerization mechanism underlying the model and the related mathematical formalism are tested by comparing the calculated and measured values of the average molecular-weight characteristics of resulting polystyrene. 相似文献
109.
110.
A. A. Berlin I. A. Novakov A. Ya. Lyapunov A. V. Nistratov E. N. Titova L. S. Bekhli S. Yu. Gugina D. V. Pyl’nov 《Polymer Science Series D》2012,5(3):133-137
The results of an investigation of the influence of stillage residues of polyfluorinated alcoholtelomeres on the properties of polydienurethane compositions and elastomers based on them are presented. It is shown that such modification allows one to raise the sedimentation stability of the compositions and increase the characteristics of physicochemical and dynamic properties of elastomers. 相似文献