Synthesis and structure of phosphorylated nitrocyclohexenes

Diene condensations of 2-nitro-and 2-bromo-2-nitroethenylphosphonates with 2,3-dimethyl-1,3-butadiene, as well as with 2,4-dihydro-and 3-methyl-2,4-dihydrothiophene 1,1-dioxides that generate 1,3-butadiene and isoprene under the reaction conditions were effected. (6-Nitrocyclohex-3-en-1-yl)phosphonates and their dehydrogenation and/or dehydrohalogenation products, namely nitrocyclohexadienyl-and nitrophenylphosphonates were prepared. The structure of the obtained compounds was proved by IR and ¹H and ³¹P NMR spectroscopy, and independent synthesis.     

Reactions of 1,2-Dinitroethenes with Thiourea and N,N'-Diphenylthiourea

Russian Journal of Organic Chemistry -     

Synthesis of β-aminophosphonic acids of cyclohexane, norbornane, and bicyclooctane series

New method for preparation of the previously unknown β-aminophosphonic acids of cyclohexane, norbornane, and bicyclooctane series from the corresponding nitrocycloalkenylphosphonates is developed. The structure of all compounds obtained is studied by the spectral (IR and ¹H and ³¹P NMR) methods.     

Reactions of 2-Nitro- and 2-Bromo-2-nitroethenylphosphonates with Anthracene

Bis(2-chloroethyl) 2-nitro- and 2-bromo-2-nitroethenylphosphonates react with anthracene along two competing pathways: [4+2] cycloaddition and electrophilic substitution; in the case of the bromo derivative, the resulting products undergo dehydrobromination under the reaction conditions to form anthracene- and dihydroanthracene-containing nitroethenylphosphonates.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 5, 2005, pp. 729–733.Original Russian Text Copyright © 2005 by Anisimova, Kuzhaeva, Berkova, Deiko, Berestovitskaya.     

Reaction of alkyl-3-nitro-and-3-bromo-3-nitroacrylates with 2-(2-nitroethenyl)furan

The diene condensation of β-nitro and β-bromo-β-nitroacrylates with 2-(2-nitroethenyl)furan as 1,3-diene leads to a mixture of regioisomeric tetrahydrobenzofurans transforming under the reaction conditions into benzofurancarboxylates due to the easy dehydrohalogenation, denitration, and dehydration. In the case of a gem-bromonitroacrylate reaction takes two routes: diene synthesis and alkylation of the furan ring, the latter process prevailing. The structure of products formed was established by spectral methods. The investigation of geometry of 2-(1-methoxycarbonyl-2-nitroethenyl)-5-(2-nitroethenyl)furan by XRD analysis showed that its vinyl fragments have the coplanar chelate-like structure with the cisoid orientation of the CO₂Me and NO₂ groups. The ester group deviates from the plane of the the carbon-carbon multiple bond.     

Seasonal variations of the muon flux in the MUSTANG super telescope data

The temperature effect of the muon cosmic ray (CR) component is studied using the MUSTANG super telescope data (Greifswald, Germany) from 2007 throughout its period of operation. The original hourly data obtained with the telescope are adjusted for the temperature effect using a vertical atmospheric temperature profile at standard isobaric levels derived from the Global Forecast System (GFS) model. The model’s accuracy and applicability is evaluated using atmospheric sounding data collected over a number of years.     

Specific Features of Reaction between 1,2-Dinitro- and 1-Nitro-2-Thioethenes and Hydrazine

Russian Journal of Organic Chemistry -     

Synthesis of 11-amino-9,10-dihydro-9,10-(ethano)anthracen-12-ylphosphonic acid

Synthesis of a new representative of β-aminophosphonic acids and related esters, namely, 11-amino-9,10-dihydro-9,10-(ethano)anthracen-12-ylphosphonic acid and the respective bis(2-chloroethyl)-phosphonate was carried out.