首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   196篇
  免费   10篇
  国内免费   9篇
化学   74篇
晶体学   1篇
力学   21篇
综合类   3篇
数学   43篇
物理学   73篇
  2020年   2篇
  2018年   2篇
  2015年   3篇
  2014年   7篇
  2013年   37篇
  2012年   4篇
  2011年   6篇
  2010年   2篇
  2008年   4篇
  2007年   4篇
  2006年   3篇
  2005年   3篇
  2004年   5篇
  2003年   6篇
  2002年   7篇
  2001年   7篇
  2000年   8篇
  1999年   2篇
  1998年   2篇
  1997年   11篇
  1996年   5篇
  1995年   3篇
  1994年   6篇
  1993年   9篇
  1992年   7篇
  1991年   6篇
  1990年   2篇
  1989年   3篇
  1988年   2篇
  1987年   2篇
  1985年   2篇
  1984年   3篇
  1983年   4篇
  1982年   2篇
  1981年   2篇
  1980年   1篇
  1979年   4篇
  1978年   1篇
  1977年   2篇
  1976年   3篇
  1975年   5篇
  1974年   2篇
  1972年   2篇
  1971年   2篇
  1969年   1篇
  1968年   1篇
  1958年   1篇
  1955年   1篇
  1948年   1篇
  1935年   1篇
排序方式: 共有215条查询结果,搜索用时 31 毫秒
121.
SOMNATH DE 《Pramana》2014,82(6):1039-1047
We have studied the production of single isolated prompt photons in high-energy proton–proton collisions at the RHIC ( \(\sqrt {s}\) = 200 GeV) and the LHC ( \(\sqrt {s}\) = 7 TeV) energies within the framework of perturbative QCD upto next-to leading order of strong coupling (α s). We have used five different parametrizations of parton distribution function (PDF) starting from the old CTEQ4M to the new CT10 distributions and compared our results with the recent single-prompt photon data from the PHENIX and the CMS Collaborations. The prompt photon cross-section is found to be described equally well by all the PDFs within the experimental errors at the RHIC and the LHC energies. The deviation in the single-prompt photon yield for different PDF sets is within ±20% when compared to CTEQ4M, indicating the upper bound of uncertainty in determining the gluon density. The diphoton measurement could be a potential candidate to constrain the gluon distribution inside the proton.  相似文献   
122.
采用热分解法制备了Ba Zn F4∶Yb,Er纳米颗粒。通过荧光分光光度计、X射线粉末衍射仪(XRD)和透射电子显微镜(TEM)对样品进行了表征。合成样品的形貌为球形,晶相为四方相,平均粒径为8 nm。当敏化剂Yb3+和激活剂Er3+的掺杂摩尔分数分别为20%和4%时,样品的发光性能较好。绿光和红光发射对应的辐射跃迁分别为Er3+离子的2H11/2→4I15/2(绿光)和4S3/2→4I15/2(绿光),以及Er3+离子的4F9/2→4I15/2(红光)。  相似文献   
123.
This work reexamines and updates earlier investigations on the phase behaviour of the Gay-Berne liquid crystal model, concentrating on the effect of varying temperature. Constant volume and constant pressure Monte Carlo simulations are combined for systems consisting of N = 500 molecules along different isotherms over the reduced temperature range 0.60 ≤ T ≤ 1.25. As in previous simulation studies of the model, the study identifies nematic and smectic B phases on compressing the isotropic fluid, the particular phase sequence depending on temperature. The nematic phase is found to be stable with respect to the isotropic phase for reduced temperatures T ≥ 0.75. In the temperature range 0.75 ≤ T ≤ 1.25, the phase boundaries of the isotropic-nematic transition are obtained by computing the Helmholtz free energy of both phases from thermodynamic integration. From the simulation data, the relative volume change at the isotropic-nematic transition is about 2%, and this value appears to be rather insensitive to changes in temperature. On compressing the nematic phase, the Gay-Berne fluid undergoes a strong first-order transition to the smectic B phase. This transition is studied by using constant pressure simulation, and the coexistence properties are estimated from the limits of mechanical stability of the nematic phase. Larger relative volume changes are found at the transition than those suggested by previous studies, with typical values increasing up to 10.5% as the temperature is decreased. The results are consistent with the existence of strong coupling between nematic and smectic order parameters. For temperatures T ≤ 0.70 the nematic phase is no longer stable, and the phase sequence isotropic-smectic B is observed. Therefore, the Gay-Berne model exhibits an isotropic-nematic-smectic B triple point. Extrapolating the present simulation data, this triple point is located approximately at reduced temperature TINB ? 0.70 and reduced pressure PINB ? 1.825.  相似文献   
124.
The synthesis, luminescence properties, experimental determination and theoretical calculation of the emission quantum yield of Eu(NTA)3.2L complexes, where NTA is naphtoiltri-fluroacetone and L denotes H2O or DMSO (dimethyl sulphoxide), were reported. The compounds were characterized by elemental analysis (carbon, hydrogen and europium), thermal analysis, UV-visible absorption and photoluminescence spectroscopies. The experimental quantum yields were determined based on a method previously proposed by Bril and collaborators. The Eu(NTA)3.2DMSO compound shows a high value for the Ω2 intensity parameter (35.8 × 10?20 cm2), reflecting the hypersensitive nature of the 5D07F2 transition and indicating that the lanthanide ion is in a highly polarizable chemical environment. The experimental quantum yield measured for that compound, 0.75, is one of the highest so far reported for solid-state europium complexes. The theoretical calculations of the quantum yield were carried out by solving an appropriate set of rate equations and by using empirical spectroscopic parameters and energy transfer rates. The theoretical results agree well with the experimental data for both complexes. The photostability of Eu(NTA)3.2DMSO at 358K was evaluated in order to verify whether this complex can be applied as a phosphor for blue light emitting devices.  相似文献   
125.
Experiments have been performed to determine the path of entry into and exit from the phosphorescent triplet state T0 of quinoxaline in a durene host. First of all the decay of phosphorescence after flash excitation was followed at 4.2 and 1.34 °K. It was found that for both perdeutero- and perhydroquinoxaline the lifetime is shortened by a factor of about three when the temperature is lowered from 4.2 to 1.34 °K. At 1.34 °K relaxation between the spin components (i.e. re-orientation of the triplet spin angular momentum) is slow relative to the decay, and the observed reduction in lifetime indicates that entry into and exit from T0, are through the same spin component. Similar decay experiments were then carried out at 1.34 °K in a 10 kG magnetic field or in a somewhat weaker field so chosen that the effect of microwave saturation of one of the E.S.R. transitions between the components could be observed. From the results it follows that on intersystem crossing the molecules enter the manifold T0 through the top zero-field component and thus initially have their spins aligned. Decay departs almost exclusively from the same component, even in the case of perhydroquinoxaline, where at least 45 per cent of it must be radiationless. The decay route agrees with out-of-plane polarization of phosphorescence for the free molecule. Finally, spin alignment on intersystem crossing is discussed from the theoretical point of view. It appears that the phenomenon is clear-cut only in molecules such as those of the aza-aromatics, where strong spin-orbit coupling of the atomic type occurs betwen ππ? and nπ? states.  相似文献   
126.
Amending soil with organic matter is common in agricultural and logging practices. Such amendments have benefits to soil fertility and crop yields. These benefits may be increased if material is preprocessed before introduction into soil. We analyzed the efficiency of microaerobic fermentation (MF), also referred to as Bokashi, in preprocessing fibrous lignocellulosic (FLC) organic materials using varying produce amendments and leachate treatments. Adding produce amendments increased leachate production and fermentation rates and decreased the biological oxygen demand of the leachate. Continuously draining leachate without returning it to the fermentors led to acidification and decreased concentrations of polysaccharides (PS) in leachates. PS fragmentation and the production of soluble metabolites and gases stabilized in fermentors in about 2?C4?weeks. About 2?% of the carbon content was lost as CO2. PS degradation rates, upon introduction of processed materials into soil, were similar to unfermented FLC. Our results indicate that MF is insufficient for adequate preprocessing of FLC material.  相似文献   
127.
Directional wave field decomposition can be accomplished with the aid of pseudo-differential operators. A fast numerical scheme requires sparse matrix representations of these operators. This paper focuses on designing sparse matrices for the propagator while keeping the accuracy high at the cost of ignoring critical-angle phenomena. The matrix representation follows from a rational approximation for the square root operator and the derivatives. The parameterization thus introduced lends itself to an overall optimization procedure that minimizes the errors for a chosen discretization rate. As such, the approach leads to an accurate propagator up to the (local) critical angle on a coarse numerical grid. This revised version was published online in November 2006 with corrections to the Cover Date.  相似文献   
128.
本文提出并实现了一种新的穆斯堡尔谱——时间相关穆斯堡尔谱。这是利用两步衰变119mTe→119Sb→119Sn而获得的。测量了110keV 119mTe加1015稳定Te/cm2注入并经600℃退火的样品在不同测量时间内的穆斯堡尔谱,分析了各谱线随ξ的变化。这里ξ是我们定义的参量,它等于ΦTe,由退火时刻ta关键词:  相似文献   
129.
130.
The longitudinal form factors of the ground and 2.18 MeV (3+, T = 0) states, and the transverse form factors of the 3.56 MeV (0+, T = 1) and 5.37 MeV (2+, T = 1) states of 6Li are compared with the predictions based on fully antisymmetrized α-d and t-τ cluster models. The longitudinal form factors are adequately described by the α-d model, but the transverse form factors seem to be more consistent with a t-τ model which is close to the shell-model limit. Estimates are made for the ground state t and α spectroscopic factors. The 3.56 MeV M1 transition current density is calculated for both models and compared with experiment.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号