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21.
Vibrational frequencies vOH and vOD have been measured for isotopically-dilute HDO molecules in eleven solid hydrates at 90 K. The results have been used to prepare a plot of the ratio vOH/vOD versus vOH. The ratios fall on a smooth curve and decrease with decreasing frequencies vOH. The anharmonicity constants ωexe have been estimated. They were found to increase with decreasing vOH. 相似文献
22.
23.
John F. Berglund 《Semigroup Forum》1972,5(1):191-215
An inverse Clifford Semigroup is a semilattice of groups. Conditions are given for constructing a compact semitopological
(separately continuous multiplication) inverse Clifford semigroup on a compact Hausdorff semilattice. The conditions are necessary
and sufficient for decomposing a compact inverse Clifford semigroup containing a dense subgroup and locally compact maximal
groups into its semilattice of groups. A catalogue of examples is given to demonstrate the construction while exhibiting various
pathologies.
This work was supported in part by the S.R.C. 相似文献
24.
B. Alper H. Becker A. Berglund I. Blakey G. Blanar M. Bowler R. Cashmore M. Cerrada V. Chabaud C. Damerell C. Daum H. Dietl A. Dwurazny J. Gallivan A. Gillman M. Glaubman A. Gonzalez-Arroyo J. Hardwick A. Zalewska 《Physics letters. [Part B]》1980,94(3):422-426
Evidence is given for the existence of a spin-5 boson resonance from the analysis of the reaction π?p→K+K?n at 62 GeV incident momentum. A simplified amplitude analysis with a Breit-Wigner ansatz leads to a mass 2307 ± 6 MeV and a width of 245 ± 20 MeV. The quantum numbers of the resonance are JP = 5?, C = ?1, and very probably IG = 1+. 相似文献
25.
Agnieszka Mikolajczuk Elżbieta Perez Przyk Michael Berglund Philip Taylor 《Isotopes in environmental and health studies》2013,49(1):2-12
Compound specific isotopic analysis (CSIA) can provide information about the origin of analysed compounds – in this case, polycyclic aromatic hydrocarbons (PAHs). In the study, PAHs were extracted from three dust samples: winter and summer filter dust and tunnel dust. The measurement was performed using the method validated in our laboratory using pure, solid compounds and EPA 610 reference assortment. CSIA required an appropriate clean-up method to avoid an unresolved complex in the gas chromatographic analysis usually found in the chromatography of PAHs. Extensive sample clean-up for this particular matrix was found to be necessary to obtain good gas chromatography–combustion–isotope ratio mass spectrometry analysis results. The sample purification method included two steps in which the sample is cleaned up and the aliphatic and aromatic hydrocarbons are separated. The concentration of PAHs in the measured samples was low; so a large volume injection technique (100 μl) was applied. The δVPDB 13C was measured with a final uncertainty smaller than 1 ‰. Comparison of the δVPDB 13C signatures of PAHs extracted from different dust samples was feasible with this method and, doing so, significant differences were observed. 相似文献
26.
27.
Rüdiger Kessel Michael Berglund Roger Wellum 《Accreditation and quality assurance》2008,13(6):293-298
Use of repeated measurements in quantitative chemical analysis is common but leads to the problem of how to combine the measurement
values and produce a result with an uncertainty following the GUM. There is often confusion between repeated indications or
observations of an input quantity, for whose uncertainty the GUM prescribes a type A evaluation, and complete measurements
repeated on multiple sub-samples, as considered here. A solution for combining repeated measurement results and their individual
uncertainties based on simple interval logic is proposed here. The individual measurement values and their uncertainties are
compared with the calculated average value to see if this implies that another, possibly unknown, source of uncertainty is
present. The model of the individual results is modified for this possible between-replicate effect so that the repeated measurements
are consistent. Lack of consistency is a strong indication that the measurement is not fully under control and needs further
development or investigation. This is not always possible, however and the method given here is proposed to ensure that the
values of the repeated measurements agree with each other. A simple numerical example is given showing how the method can
be implemented in practice. 相似文献
28.
Suci PA Berglund DL Liepold L Brumfield S Pitts B Davison W Oltrogge L Hoyt KO Codd S Stewart PS Young M Douglas T 《Chemistry & biology》2007,14(4):387-398
Nanomedicine directed at diagnosis and treatment of infections can benefit from innovations that have substantially increased the variety of available multifunctional nanoplatforms. Here, we targeted a spherical, icosahedral viral nanoplatform to a pathogenic, biofilm-forming bacterium, Staphylococcus aureus. Density of binding mediated through specific protein-ligand interactions exceeded the density expected for a planar, hexagonally close-packed array. A multifunctionalized viral protein cage was used to load imaging agents (fluorophore and MRI contrast agent) onto cells. The fluorescence-imaging capability allowed for direct observation of penetration of the nanoplatform into an S. aureus biofilm. These results demonstrate that multifunctional nanoplatforms based on protein cage architectures have significant potential as tools for both diagnosis and targeted treatment of recalcitrant bacterial infections. 相似文献
29.
The influence of temperature on structure and properties of the cellulose Ibeta crystal was studied by molecular dynamics simulations with the GROMOS 45a4 force-field. At 300 K, the modeled crystal agreed reasonably with several sets of experimental data, including crystal density, corresponding packing and crystal unit cell dimensions, chain conformation parameters, hydrogen bonds, Young's modulus, and thermal expansion coefficient at room temperature. At high-temperature (500 K), the cellulose chains remained in sheets, despite differences in the fine details compared to the room-temperature structure. The density decreased while the a and b cell parameters expanded by 7.4% and 6%, respectively, and the c parameter (chain axis) slightly contracted by 0.5%. Cell angles alpha and beta divided into two populations. The hydroxymethyl groups mainly adopted the gt orientation, and the hydrogen-bonding pattern thereby changed. One intrachain hydrogen bond, O2'H2'...O6, disappeared and consequently the Young's modulus decreased by 25%. A transition pathway between the low- and high-temperature structures has been proposed, with an initial step being an increased intersheet separation, which allowed every second cellulose chain to rotate around its helix axis by about 30 degrees . Second, all hydroxymethyl groups changed their orientations, from tg to gg (rotated chains) and from tg to gt (non-rotated chains). When temperature was further increased, the rotated chains returned to their original orientation and their hydroxymethyl groups again changed their conformation, from gg to gt. A transition temperature of about 450 K was suggested; however, the transition seems to be more gradual than sudden. The simulated data on temperature-induced changes in crystal unit cell dimensions and the hydrogen-bonding pattern also compared well with experimental results. 相似文献
30.
CM Silva MF Duarte ML Mira MH Florêncio K Versluis AJ Heck 《Rapid communications in mass spectrometry : RCM》1999,13(12):1098-1103
Fast atom bombardment, combined with high-energy collision-induced tandem mass spectrometry, has been used to investigate gas-phase metal-ion interactions with captopril, enalaprilat and lisinopril, all angiotensin-converting enzyme inhibitors.Suggestions for the location of metal-binding sites are presented. For captopril, metal binding occurs most likely at both the sulphur and the nitrogen atom. For enalaprilat and lisinopril, binding preferably occurs at the amine nitrogen. Copyright 1999 John Wiley & Sons, Ltd. 相似文献