Effect of promotion of nickel sulfide catalyst with silver on kinetics of decarbonilation of stearic acid

Russian Chemical Bulletin - The kinetics of liquid-phase decarbonylation of stearic acid in n-dodecane on γ-Al2O3 supported nickel sulfide catalyst promoted with silver was experimentally...     

Poisoning Effect of Acid Soluble Oil on Triflic Acid-Catalyzed Isobutane Alkylation

The rate of the isobutane alkylation reaction with secondary butenes catalyzed by trifluoromethanesulfonic acid at –20°C is experimentally found to depend on the concentration of acid soluble oil (ASO), which poisons TfOH. With an increase in the ASO molar fraction from 0.13 to 0.16, the reaction rate decreases by a factor of ten. The Hammett acidity function was determined for TfOH solutions at 25°C in the concentration range from 0 to 0.2 ASO molar fractions. The results obtained suggest that the alkylation reaction rate is proportional to the proton activity in the acid phase determined by the Hammett acidity function.     

Activation of molecular hydrogen by transition-metal complexes. 2. Formation of complexes,of palladium (O) and (+1) with a metal-metal bond during hydrogenolysis of [Ph3PPd(OAc)2]2

Conclusions The reaction of dipalladium -diacetatediacetatoditriphenylphosphine [Ph₃PPd(OAc)₂]₂ with hydrogen leads to formation of complexes of Pd(0), (Ph₃P)₂Pd₂, and of Pd(+l), (Ph₃PPd(OAc)₂, with a metal-metal bond.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1687–1690, August, 1979.