全文获取类型
收费全文 | 779篇 |
免费 | 21篇 |
国内免费 | 2篇 |
专业分类
化学 | 524篇 |
晶体学 | 3篇 |
力学 | 29篇 |
数学 | 74篇 |
物理学 | 172篇 |
出版年
2022年 | 7篇 |
2021年 | 14篇 |
2020年 | 9篇 |
2019年 | 8篇 |
2018年 | 6篇 |
2017年 | 6篇 |
2016年 | 26篇 |
2015年 | 18篇 |
2014年 | 20篇 |
2013年 | 46篇 |
2012年 | 56篇 |
2011年 | 58篇 |
2010年 | 23篇 |
2009年 | 22篇 |
2008年 | 39篇 |
2007年 | 43篇 |
2006年 | 37篇 |
2005年 | 44篇 |
2004年 | 23篇 |
2003年 | 20篇 |
2002年 | 27篇 |
2001年 | 9篇 |
2000年 | 20篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1996年 | 10篇 |
1995年 | 4篇 |
1994年 | 7篇 |
1993年 | 8篇 |
1992年 | 9篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1986年 | 3篇 |
1985年 | 9篇 |
1984年 | 12篇 |
1983年 | 5篇 |
1982年 | 7篇 |
1981年 | 9篇 |
1980年 | 13篇 |
1979年 | 4篇 |
1978年 | 14篇 |
1977年 | 7篇 |
1976年 | 13篇 |
1975年 | 9篇 |
1974年 | 5篇 |
1973年 | 11篇 |
1972年 | 7篇 |
1880年 | 3篇 |
排序方式: 共有802条查询结果,搜索用时 15 毫秒
81.
Froelich O Desos P Bonin M Quirion JC Husson HP Zhu J 《The Journal of organic chemistry》1996,61(19):6700-6705
The asymmetric synthesis of a series of 2-(1-aminoalkyl) piperidines using (-)-2-cyano-6-phenyloxazolopiperidine 1 is described. LiAlH(4) reduction of 1 followed by hydrogenolysis led to the diamine 3. The same strategy applied to C-2-methylated compound 7 afforded [(2S)-2-methylpiperidin-2-yl]methanamine (9). Addition of lithium derivatives to the cyano group of 1 resulted in the formation of an intermediate imino bicyclic system (11a-c) which could be diastereoselectively reduced to substituted diamino alcohols 13a-c. The addition of an excess of PhLi to 1 in the presence of LiBr furnished disubstituted amine 19, the precursor of diphenyl[(2S)-piperidin-2-yl]methanamine (22). 相似文献
82.
Dr. Benoit Colasson Dr. Thomas Devic Dr. Joël Gaubicher Dr. Charlotte Martineau-Corcos Prof. Philippe Poizot Dr. Vincent Sarou-Kanian 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(37):9589-9596
The synthesis and characterization of a polyrotaxanated covalent organic network (CON) based on the association between the viologen and pillar[5]arene (P[5]OH) units are reported. The mechanical bond allows for the irreversible insertion of n-type redox centers (P[5]OH macrocycles) within a pristine structure based on p-type viologen redox centers. Both redox units are active on a narrow potential range and, in water, the presence of P[5]OH greatly increases the electroactivity of the material. 相似文献
83.
Benoit Carbain 《Tetrahedron letters》2010,51(20):2717-7899
We report an efficient synthetic approach to phospha-isosteres of important intermediates of the shikimic acid pathway by the application of the Hunsdiecker-Barton halodecarboxylation to cyclohexenylcarboxylic acids. As examples, phospha-shikimic acid, its 3-dehydro derivative and the respective monomethyl esters were synthesized. The approach has proven equally useful in the synthesis of isosteres of the antiviral agent oseltamivir. 相似文献
84.
85.
Stefano Caramori Dr. Jérôme Husson Dr. Marc Beley Prof. Carlo A. Bignozzi Prof. Roberto Argazzi Dr. Philippe C. Gros Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(8):2611-2618
Mixtures of polypyridine FeII and CoII complexes are used as electron mediators in Ru–thienyltpy‐sensitised solar cells (tpy=terpyridine). The use of the metalorganic redox couples allows for improved charge‐collection efficiency with respect to the classical iodide/iodine couple which, when associated to Ru–tpy2 dyes, usually produces poor performance. The improved charge collection is explained by a combination of effective dye regeneration and decreased recombination with the oxidised electrolyte on the basis of data obtained by transient spectroscopy and photoelectrochemical measurements. The efficiency of the regeneration cascade is also critically dependent upon the ability of the CoII complex to intercept FeIII centres, as clearly indicated by chronocoulometry experiments. 相似文献
86.
D. Boettle M. Burzio P. Cinato G. Eilenberger J. -B. Jacob T. Martinson F. Masetti A. Mcguire M. Sotom P. Vogel J. Benoit 《Fiber and Integrated Optics》1996,15(4):267-279
The expected traffic growth from new broadband services will require network capacities that can be beneficially provided by optical WDM transport networks. Optical packet techniques are essential for large networks to provide flexibility and granularity. A layered network architecture with a transparent optical layer and optical packet layers has been elaborated. Four switching concept options for large optical ATM switch fabrics in the public network and small access nodes are presented. The technology for the related key functions of space and wavelength switching was developed in the RACE ATMOS project and the feasibility of concepts and technologies was verified in four system demonstrators. 相似文献
87.
Excellent diastereofacial and endo/exo stereoselectivities have been obtained in cycloaddition of the chiral azomethine ylide generated from 4-phenyloxazolidine acetic acid (−)-8-phenylmenthyl ester 1e. 相似文献
88.
89.
Hanane Belghit Cyril Colas Sébastien Bristeau Benoit Maunit 《International journal of environmental analytical chemistry》2015,95(2):93-105
Chlordecone (CLD) is a persistent toxic chlorinated pesticide which contaminates different ecosystems in French West Indies. A soil remediation process including zero-valent iron (ZVI) has produced promising results but failed to completely degrade CLD, and the analytical procedures used yielded little information on the transformation products. To fill these gaps, dechlorination of aqueous CLD by micrometric particles of ZVI has been investigated. Aliquots of water with 25% (v/v) of acetone spiked with 100 ppm CLD were taken at different times during a 30-day ZVI treatment and directly analysed by ultra-high-performance liquid chromatography in negative electrospray ionisation mode. CLD has been totally transformed after 14 days into 14 dechlorinated degradation products, including 9 isomeric compounds. The maximum chloride concentrations appearing in the medium represent 44% of that which would result from total dechlorination of CLD. The CLD transformation products identified by accurate mass measurements on an ultra-high-resolution Q-TOF mass spectrometer (Q-TOF-MS) were C10H3Cl9O2, C10H4Cl8O2, C10H5Cl7O2, C10H6Cl6O2 and C10H7Cl5O2. The results show the interest of LC-Q-TOF-MS for identifying transformation products of organic contaminants, and the effectiveness of micrometric ZVI particles to totally transform CLD into less chlorinated products. 相似文献
90.