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71.
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73.
A complex of samarium diiodide (SmI(2)) with tetraglyme catalyzes the intermolecular pinacol coupling of aromatic or aliphatic aldehydes at loadings of 10 mol % in the presence of Me(2)SiCl(2) and Mg. Diastereoselectivity of up to 95/5 (+/-/meso) has been achieved for aliphatic aldehydes and up to 19/81 (+/-/meso) for aromatic aldehydes. De values of up to 99% have been achieved in intramolecular pinacol coupling reactions using the SmI(2)/tetraglyme/Mg/Me(2)SiCl(2) catalytic system. 相似文献
74.
Maxence Valla James W. Harris Rajamani Gounder William N. P. van der Graaff Evgeny A. Pidko Emiel J. M. Hensen Paola Ferrini Jan Dijkmans Bert Sels Ive Hermans Christophe Copéret 《Helvetica chimica acta》2016,99(12):916-927
In recent years, various protocols on preparing Lewis acidic Sn‐β zeolite hydrothermally and postsynthetically have been reported. However, very little is known about the effects of different synthesis protocols on the Sn(IV) speciation in the final material. Even the effects of individual synthesis parameters within a certain preparation method have not been studied systematically. Here, we demonstrate that hydrothermally synthesized Sn‐β zeolites prepared via very similar recipes show significantly different 119Sn‐NMR spectra, suggesting different Sn site speciation. Among postsynthetically prepared Sn‐β zeolites, less variation in the resulting 119Sn‐NMR spectra have been observed, indicating a more reproducible synthesis procedure compared to hydrothermal synthesis in fluoride media. This work highlights the importance of 119Sn‐NMR measurements to elucidate the precise local geometry of the Sn heteroatoms in Sn‐β, and the need to quantify the number of reactive Sn sites on each sample that participate in a given catalytic reaction, in order to accurately compare materials prepared by different routes. 相似文献
75.
Extending previous results by A. Eskin and G. Margulis, and answering their conjectures, we prove that a random walk on a finite volume homogeneous space is always recurrent as soon as the transition probability has finite exponential moments and its support generates a subgroup whose Zariski closure is semisimple. 相似文献
76.
Alain Valla Virginie Prat Alain Laurent Zo Andriamialisoa Dominique Cartier Michel Giraud Roger Labia Pierre Potier 《Helvetica chimica acta》2001,84(11):3423-3427
Aromatic analogs of 9‐methylidene and 13‐demethyl‐9‐methylideneretinol, ‐retinal, and ethyl 13‐demethyl‐9‐methylideneretinoate were synthesized via a new β‐methylidene‐aldehyde synthon. 相似文献
77.
Paul Armand Joël Benoist Riadh Omheni Vincent Pateloup 《Computational Optimization and Applications》2014,59(3):405-433
The paper proposes a primal-dual algorithm for solving an equality constrained minimization problem. The algorithm is a Newton-like method applied to a sequence of perturbed optimality systems that follow naturally from the quadratic penalty approach. This work is first motivated by the fact that a primal-dual formulation of the quadratic penalty provides a better framework than the standard primal form. This is highlighted by strong convergence properties proved under standard assumptions. In particular, it is shown that the usual requirement of solving the penalty problem with a precision of the same size as the perturbation parameter, can be replaced by a much less stringent criterion, while guaranteeing the superlinear convergence property. A second motivation is that the method provides an appropriate regularization for degenerate problems with a rank deficient Jacobian of constraints. The numerical experiments clearly bear this out. Another important feature of our algorithm is that the penalty parameter is allowed to vary during the inner iterations, while it is usually kept constant. This alleviates the numerical problem due to ill-conditioning of the quadratic penalty, leading to an improvement of the numerical performances. 相似文献
78.
We have used angle-resolved photoemission spectroscopy to determine the bulk electronic structure of Sr(2)RuO(4) above and below the Fermi liquid crossover near 25 K. Our measurements indicate that the properties of the system are highly orbital dependent. The quasi-2D gamma band displays Fermi liquid behavior while the remaining low energy bands show exotic properties consistent with quasi-1D behavior. In the Fermi liquid state below 25 K, the gamma band dominates the electronic properties, while at higher temperatures the quasi-1D beta and alpha bands become more important. 相似文献
79.
Let G be a connected simply connected almost
-simple algebraic group with
non-compact and
a cocompact congruence subgroup. For any homogeneous manifold
of finite volume, and a
, we show that the Hecke orbit T
a
(x
0
H) is equidistributed on
as
, provided H is a non-compact commutative reductive subgroup of G. As a corollary, we generalize the equidistribution result of Hecke points ([COU], [EO1]) to homogeneous spaces G/H. As a concrete application, we describe the equidistribution result in the rational matrices with a given characteristic
polynomial.
The second author partially supported by DMS 0333397.
Received: May 2005 Revision: March 2006 Accepted: June 2006 相似文献
80.
This paper is a study of the car sequencing problem, when feature spacing constraints are soft and colors of vehicles are taken into account. Both pseudo-polynomial algorithms and lower bounds are presented for parts of the problem or family of instances. With this set of lower bounds, we establish the optimality (up to the first non-trivial criteria) of 54% of best known solutions for the benchmark used for the Roadef Challenge 2005. We also prove that the optimal penalty for a single ratio constraint N/P can be computed in O(P) and that determining the feasibility of a car sequencing instance limited to a pair of simple ratio constraints can be achieved by dynamic programming. Finally, we propose a solving algorithm exploiting these results within a local search approach. To achieve this goal, a new meta-heuristic (star relinking) is introduced, designed for the optimization of an aggregation of criteria, when the optimization of each single criterion is a polynomial problem. 相似文献