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31.
The paper reports the results obtained in the complexometric determination of Bi(3+), Fe(3+) and Cr(3+) by using an Hg(2+)-sensitive membrane-electrode for the end-point indication. The determination of Bi(3+) and Fe(3+) is performed after addition of mercuric complexonate from which these cations release Hg(2+) by means of which the electrode senses the equivalence point. In the case of Cr(3+) an excess of complexone is added and the surplus is titrated with a standard solution of Hg(2+) in the presence of the Hg(2+)-sensitive membrane-electrode. 相似文献
32.
33.
34.
Malzert-Fréon A Abillon O Proust JE Gref R Benoît JP Boury F 《Colloids and surfaces. B, Biointerfaces》2005,42(2):97-106
In this paper, we compared the efficiency of polymer films, made of a poly(ethylene glycol) (PEG2,000)/poly(d,l-lactide) (PLA50) mixture, or a PEG2,000-PLA50 copolymer, to prevent adsorption of a model protein, the hen egg-white lysozyme (HEWL), at the air-water interface. This was achieved by analyzing the surface pressure/surface area curves, and the X-ray reflectivity data of the polymer films spread on a Langmuir trough, obtained in absence or in presence of the protein. For both the mixture and the copolymer, the amount of protein adsorbed at the air-water interface decreases when the density of the polymer surface coverage increases. It was shown that even in a condensed state, the polymer film made by the mixture can not totally prevent HEWL molecules to adsorb and penetrate the polymer mixed film, but however, protein molecules would not be directly exposed to the more hydrophobic phase, i.e. the air phase. It was also shown that the configuration adopted by the copolymer at the interface in its condensed state would prevent adsorption of HEWL molecules for several hours; this would be due in particular to the presence of PEG segments in the interfacial film. 相似文献
35.
Zdenìk Vít Daniela Gulková Ludìk Kalua Miroslav Zdrail 《Reaction Kinetics and Catalysis Letters》2004,83(2):237-244
The effect of support (SiO2-Al2O3, Al2O3,MgO) of the Rh-Mo(S) sulfide catalysts on the synergy in hydrodesulfurization (HDS) of thiophene and hydrodenitrogenation
(HDN) of pyridine was studied. The synergy in HDS was between 7–10 regardless of the kind of support used. The synergy in
HDN varied from none over the MgO supported sample to about 3 over SiO2-Al2O3 supported catalyst, in accord with the positive effect of increasing support acidities.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
36.
Adel Attia Markéta Zukalová Jiří Rathouský Arnošt Zukal Ladislav Kavan 《Journal of Solid State Electrochemistry》2005,9(3):138-145
A mesoporous electrode material whose structure is composed of anatase nanocrystals stabilized by alumina is reported. Powder X-ray diffraction shows the anatase phase only, but micro-Raman spectroscopy shows that the materials have a core-shell morphology with grains of bulk anatase covered by a thin rutile layer on the surface. This structure is unique when compared to analogous materials stabilized by zirconia (PNNL-1). Nitrogen adsorption isotherms demonstrate a monotonous increase in surface area and mesopore volume with increasing Al content. Thin film electrodes from these materials were characterized by lithium insertion electrochemistry. Cyclic voltammograms exhibit significant differences in Li accommodation in Al-free and Al-stabilized materials. 相似文献
37.
38.
Let {ø n (dμ)} be a system of orthonormal polynomials on the unit circle with respect to a measuredμ. Szegö's theory is concerned with the asymptotic behavior ofø n (dμ) when logμ′∈L 1. In what follows we will discuss the asymptotic behavior of the ratioø n (dμ 2)/ø n (dμ 1) on the unit circle whendμ 1 anddμ 2 are close in a sense (e.g.,dμ 2=gdμ 1, where g≥0 is such thatQ(e it )g(t) andQ(e it )/g(t) are bounded for a suitable polynomialQ) and μ 1 ′ >0 almost everywhere or (a somewhat weaker requirement) lim n→∞Φ n (dμ 1,0)=0 for the monic polynomial Φ n . The asymptotic behavior of the same fraction outside the unit circle was discussed in an earlier paper. 相似文献
39.
András Sütő 《Communications in Mathematical Physics》1987,111(3):409-415
The spectrum (H) of the tight binding Fibonacci Hamiltonian (H
mn=
m,n+1+
m+1,n
+
m,n
v(n),v(n)=
((n–1)), 1/ is the golden number) is shown to coincide with the dynamical spectrum, the set on which an infinite subsequence of traces of transfer matrices is bounded. The point spectrum is absent for any , and (H) is a Cantor set for 4. Combining this with Casdagli's earlier result, one finds that the spectrum is singular continuous for 16.On leave from the Central Research Institute for Physics, Budapest, Hungary 相似文献
40.
J. Kuriplach L. Lešták M. Rotter B. Sedlák M. Trhlík M. Finger T. Lešner J. Dupák P. Novák M. Vobecký 《Hyperfine Interactions》1987,34(1-4):339-342
First experimental results of160Tb nuclear orientation in yttrium single crystal matrix are described. The influence of external magnetic field in combination with the crystal field interaction is discussed. 相似文献