Surface modification of polymers. V. Biomaterial applications

Polyethylene films were surface grafted with glycidyl methacrylate (GMA) by UV irradiating the film for 5 min together with benzophenone. Poly(ethylene glycol) (PEG) was attached to the grafted surface through reaction with the epoxy groups. This yielded a surface which consisted of 95% PEG as measured with ESCA. The adsorption of human transferrin onto this film was significantly reduced as compared with a pure polyethylene film. Heparin was also reacted with a GMA grafted PE surface. ESCA showed that heparin was grafted to the surface, and in vitro blood clotting tests on the heparinized PE surface showed a reduced thrombus formation. GMA grafted polystyrene wells were reacted with carbohydrazide, to the formed carbohydrazide surface a rabbit antibody raised against mouse urinary protein (RaMUP) was covalently coupled. The RaMUP coupled surfaces was used in the detection of mouse urinary protein (MUP) at low concentrations (ca. 1 ng/mL) with an ELISA technique.     

The hidden information content of price movements

Dynamic patterns of prices in different markets may motivate (strategic) consumers, who could be monitoring price movements over time, to game vendors. Do past price movements carry information about the probability and magnitude of future price drops?Conducting empirical work in the airline industry on near 1000 US domestic routes, we find that some price-metrics carry information about future price swings: these variables can assist in predicting the likelihood and magnitude of price drops. These price-metrics yield significantly different signals which also vary as the prediction horizon changes.     

Monitoring microstructural material changes in paper through microscopic speckle correlation rate measurements

A system for real-time digital speckle correlation rate measurements is developed and applied on printing paper in the micro-scale. The system consists of a continuous laser and a CCD camera connected to a PC. To measure on objects in the micro-scale the system is connected to a stereomicroscope where one of the channels is used for imaging and the other channel is used for illumination of the object surface. The system is evaluated through measurements on printing paper over an area of 1 mm² and with a spatial resolution of 30 μm on the object. The results show that the system is able to monitor the dynamics in paper during both wetting and drying in real-time over a time scale ranging from one-tenth of a second to several hours.     

Intense mass-separated beams of halogens and beta-delayed neutron emission from heavy bromine isotopes

Improved production yields of short-lived halogens were obtained from a ThO₂ target, irradiated with 600 MeV protons, in combination with a negative surface ionization source. Mass-separated samples were studied by decay spectroscopy. Production yields of radioactive isotopes of chlorine, bromine, iodine and astatine are presented. Half-lives and relative neutron emission probabilities were measured for the heavy bromine isotopes^89?92Br. Normalizing to earlier publishedP _n values for⁸⁹Br, the results are:⁸⁹Br (4.30±0.14s,P _n =13.6±0.8%),⁹⁰Br (1.92±0.06s,P _n =24.8±1.5%),⁹¹Br (0.53 ±0.03 s,P _n =30.1 ±2.1%), and⁹²Br (0.31 ±0.02 s,P _n =34.6±2.5%). Energy spectra ofβ-delayed neutrons were measured.     

SPECTRAL CHARACTERIZATION OF LIGHT-REDUCIBLE CYTOCHROME IN A PLASMA MEMBRANE-ENRICHED FRACTION AND IN OTHER MEMBRANES FROM CAULIFLOWER INFLORESCENCES

Abstract— Low temperature spectroscopy has been used to characterize microsomal fractions obtained from cauliflower inflorescences ( Brasska oleracea L.) by differential centrifugation and partition in an aqueous polymer two-phase system. The plasma membrane-enriched fraction (U₃) was found to contain one dominant b -cytochrome, which could be reduced both by blue light and by dithionite. An action spectrum of the blue light-induced absorbance change [LIAC, Δ(A₄₃₀—A₄₁₀)] associated with the reversible reduction of this b -type cytochrome indicated that the primary light-receptor was a flavin-like compound. Another microsomal fraction (L₃) containing membranes from mitochondria, endoplasmic reticulum and other organelles also contained light-reducible cytochrome. One of these could be identified as cytochrome c oxidase, and another may be identical to cytochrome b ₅ of the endoplasmic reticulum.     

Kovasznay Mode Decomposition of Velocity-Temperature Correlation in Canonical Shock-Turbulence Interaction

The correlation coefficient R_uT between the streamwise velocity and temperature is investigated for the case of canonical shock-turbulence interaction, motivated by the fact that this correlation is an important component in compressible turbulence models. The variation of R_uT with the Mach number, the turbulent Mach number, and the Reynolds number is predicted using linear inviscid theory and compared to data from DNS. The contributions from the individual Kovasznay modes are quantified. At low Mach numbers, the peak post-shock R_uT is determined by the acoustic mode, which is correctly predicted by the linear theory. At high Mach numbers, it is determined primarily by the vorticity and entropy modes, which are strongly affected by nonlinear and viscous effects, and thus less well predicted by the linear theory.