Investigation of the Crystallisation Behaviour of Lead Titanate (PT), Lead Zirconate (PZ) and Lead Zirconate Titanate (PZT) by EXAFS-Spectroscopy and X-Ray Diffraction

Two solid solutions of lead zirconium titanates PbZr _x Ti_{1 – x} O₃ (x = 0.1 and 0.35) as well as the reference compounds lead titanate and lead zirconate were prepared from zirconium and titanium n-propoxide, dissolved in 2-methoxyethanol, by sol-gel process. The amorphous products after pyrolysis of the dried gels and the crystalline phases were studied by EXAFS spectroscopy to monitor the structural changes from the amorphous oxide mixture to the crystalline ceramics after calcination. Additionally, the crystalline phases were identified by X-ray diffraction (XRD).It follows from the analysis of the EXAFS data that the local order of the amorphous phases seems to be completely different from that of the crystalline phase. There is no indication of a preformation of the local order of the perovskite structure. The analysis of our EXAFS spectra can be interpreted very consistently with the assumption that in the amorphous samples a segregation exists on molecular level and the low crystallisation temperatures are a consequence of very short diffusion paths.     

Finite elements for parabolic equations backwards in time

Summary Several regularization methods for parabolic equations backwards in time together with the usual additional constraints for their solution are considered. The error of the regularization is estimated from above and below. For a boundary value problem in time-method, finite elements as well as a time discretization are introduced and the error with respect to the regularized solution is estimated, thus giving an overall error of the discrete regularized problem. The algorithm is tested in simple numerical examples.     

Borel summability of the 1/N expansion for theN-vector [O(N) non-linear σ] models

We construct an analytic interpolation in 1/N for theN-vector [O(N) non-linear ] models withN-component fields on a lattice. This interpolation, valid at sufficiently high temperatures, extends over a large domain in the complex plane containing the half plane Re(1/N)>0. We use this result to show that the 1/N expansion of the free energy density and of the correlation functions is Borel summable in the thermodynamic limit and at high temperature.On leave from C.P.T., Ecole Polytechnique, F-91128 Palaiseau Cédex, France