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941.
A model equation governing the primitive dynamics of wave packets near an extremum of the linear dispersion relation at finite wavenumber is derived. In two spatial dimensions, we include the effects of weak variation of the wave in the direction transverse to the direction of propagation. The resulting equation is contrasted with the Kadomtsev–Petviashvilli and Nonlinear Schrödinger (NLS) equations. The model is derived as an approximation to the equations for deep water gravity-capillary waves, but has wider applications. Both line solitary waves and solitary waves which decay in both the transverse and propagating directions—lump solitary waves—are computed. The stability of these waves is investigated and their dynamics are studied via numerical time evolution of the equation. 相似文献
942.
In this paper, silver nanostructures with controlled morphologies, such as plates, rods, belts, sheets and their self-assembled films have been prepared on copper and aluminum substrates by a surfactant-assisted colloidal chemical method. The X-ray powder diffraction (XRD) and the selected area electron diffraction (SAED) patterns indicated that the Ag nanostructures grew on the substrates with cubic symmetry and single-crystalline in nature. An oriented attachment with surfactant-assisted mechanism and a cooperative effect of surfactant and chloride ion on the morphology of Ag nanostructures were investigated systematically and synthetically. 相似文献
943.
944.
John M. Kokosa Ih Chu Ludwig Bauer Richard S. Hlgan 《Journal of heterocyclic chemistry》1978,15(5):785-791
The reaction of 3,5-lutidine 1-oxide ( 1 ) with t-butyl mereaptan in acetic anhydride, with or without triethylamine, was reinvestigated. There was obtained 2-t-butylthio-3,.5-lutidine as the major product, a small quantity of 3-(t-bulylthio)methyl-5-picoline, 1-acetyl-2,3-diacetoxy-3,5-dirnethyl-6-t-butylthio-1,2,3,6-tetrahydropyridine (which represents a structure revision) and l-acetyl-2,6-dihydroxy-3-t-butylthio-3,5-dimethyl-1,2,3,6-tetrahydropyridine. A similar reaction of 1 with 1-adamantyl mercaptan furnished 2-(l-adamantylthio)-3,5-lutidine and 1-acetyl-2,3-diacetoxy-3,5-dimethyl-6-(1-adamantylthio)-1,2,3,6-tetrahydropyridine. The structures of these new tetrahydropyridines were established primarily by carbon-13 nmr spectra. 相似文献
945.
Garcia BA Platt MD Born TL Shabanowitz J Marcus NA Hunt DF 《Rapid communications in mass spectrometry : RCM》2006,20(20):2999-3006
Articular cartilage contains both chondrocyte cells and extracellular matrix (ECM) components. Currently, comprehensive information concerning the protein composition of human articular cartilage tissue is somewhat lacking. In this report we detail the use of tandem mass spectrometry (MS/MS) for a preliminary global identification of proteins from human articular knee cartilage tissue from patients diagnosed with osteoarthritis. Knee cartilage supernatant was fractionated using one-dimensional sodium dodecyl sulfate polyacrylamide gel electrophoresis (1D-SDS-PAGE), in-gel digested and peptide sequences were then determined by performing on-line nano-liquid chromatography (LC)/MS/MS experiments using an ion trap mass spectrometer. Altogether, over 100 different proteins from nearly 700 unique peptide sequences were detected by MS/MS. The majority of the proteins identified are involved in ECM organization (35%), signal transduction and cell communication (14%), immune response (11%) and metabolism and energy pathways (11%). Proteins observed included several well-known cartilage components as well as lower abundant lesser known ECM proteins. Possible degradation products in the cartilage sample, such as from cartilage link protein, could also be detected by our mass spectrometry methods. We show here that mass spectrometry can be utilized as a tool for a fast, accurate and sensitive analysis of a complex mixture of cartilage proteins. It is believed that this type of proteomic analysis will aid future work centered on investigating the pathology of this and other related joint diseases. 相似文献
946.
Waldo JP Mehta S Neuenswander B Lushington GH Larock RC 《Journal of combinatorial chemistry》2008,10(5):658-663
The iodocyclization of O-methyloximes of 2-alkyn-1-ones affords 4-iodoisoxazoles, which undergo various palladium-catalyzed reactions to yield 3,4,5-trisubstituted isoxazoles. The palladium-catalyzed processes have been adapted to parallel synthesis utilizing commercially available boronic acid, acetylene, styrene, and amine sublibraries. Accordingly, a diverse 51-member library of 3,4,5-trisubstituted isoxazoles has been generated. 相似文献
947.
Dr. Deepak Gupta Dr. Alae E. Lakraychi Dr. Buddha D. Boruah Simon De Kreijger Dr. Ludovic Troian-Gautier Prof. Benjamin Elias Prof. Michael De Volder Prof. Alexandru Vlad 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(42):e202201220
Controlling redox activity of judiciously appended redox units on a photo-sensitive molecular core is an effective strategy for visible light energy harvesting and storage. The first example of a photosensitizer - electron donor coordination compound in which the photoinduced electron transfer step is used for light to electrical energy conversion and storage is reported. A photo-responsive Ru-diimine module conjugated with redox-active catechol groups in [Ru(II)(phenanthroline-5,6-diolate)3]4− photosensitizer can mediate photoinduced catechol to dione oxidation in the presence of a sacrificial electron acceptor or at the surface of an electrode. Under potentiostatic condition, visible light triggered current density enhancement confirmed the light harvesting ability of this photosensitizer. Upon implementation in galvanostatic charge-discharge of a Li battery configuration, the storage capacity was found to be increased by 100 %, under 470 nm illumination with output power of 4.0 mW/cm−2. This proof-of-concept molecular system marks an important milestone towards a new generation of molecular photo-rechargeable materials. 相似文献
948.
Yingze Zhou Fandi Chen Hamidreza Arandiyan Peiyuan Guan Yunjian Liu Yuan Wang Chuan Zhao Danyang Wang Dewei Chu 《Journal of Energy Chemistry》2021,(6):516-542
With the increasing demands for electrical energy storage technologies,rechargeable zinc ion batteries (ZIBs) have been rapidly developed in recent years owing ... 相似文献
949.
Archiv der Mathematik - Motivated by recent results on the minimal base of a permutation group, we introduce a new local invariant attached to arbitrary finite groups. More precisely, a subset... 相似文献
950.
We report experimental results on the decay of wave turbulence in an elastic plate obtained by stopping the forcing from a stationary turbulent state. In the stationary case, the forcing is seen to induce some anisotropy and a spectrum in disagreement with the weak turbulence theory. After stopping the forcing, almost perfect isotropy is restored. The decay of energy is self-similar and the observed decaying spectrum is in better agreement with the prediction of the weak turbulence theory. The dissipative part of the spectrum is partially consistent with the theoretical prediction based on previous work by Kolmakov. This suggests that the nonagreement with the weak turbulence theory is mostly due to a spurious effect of the forcing related to the finite size of the system. 相似文献