全文获取类型
收费全文 | 1300篇 |
免费 | 46篇 |
国内免费 | 4篇 |
专业分类
化学 | 951篇 |
晶体学 | 3篇 |
力学 | 23篇 |
数学 | 222篇 |
物理学 | 151篇 |
出版年
2023年 | 16篇 |
2022年 | 17篇 |
2021年 | 20篇 |
2020年 | 27篇 |
2019年 | 37篇 |
2018年 | 13篇 |
2017年 | 7篇 |
2016年 | 40篇 |
2015年 | 35篇 |
2014年 | 32篇 |
2013年 | 55篇 |
2012年 | 76篇 |
2011年 | 63篇 |
2010年 | 42篇 |
2009年 | 35篇 |
2008年 | 61篇 |
2007年 | 54篇 |
2006年 | 50篇 |
2005年 | 48篇 |
2004年 | 60篇 |
2003年 | 45篇 |
2002年 | 36篇 |
2001年 | 13篇 |
2000年 | 20篇 |
1999年 | 17篇 |
1998年 | 14篇 |
1997年 | 20篇 |
1996年 | 21篇 |
1995年 | 24篇 |
1994年 | 13篇 |
1993年 | 15篇 |
1992年 | 11篇 |
1991年 | 15篇 |
1988年 | 9篇 |
1987年 | 17篇 |
1986年 | 8篇 |
1985年 | 13篇 |
1984年 | 15篇 |
1983年 | 13篇 |
1982年 | 16篇 |
1981年 | 7篇 |
1980年 | 11篇 |
1979年 | 11篇 |
1978年 | 11篇 |
1977年 | 13篇 |
1975年 | 9篇 |
1973年 | 16篇 |
1972年 | 7篇 |
1931年 | 7篇 |
1884年 | 8篇 |
排序方式: 共有1350条查询结果,搜索用时 15 毫秒
21.
Elena Eggl Martin Dierolf Klaus Achterhold Christoph Jud Benedikt Günther Eva Braig Bernhard Gleich Franz Pfeiffer 《Journal of synchrotron radiation》2016,23(5):1137-1142
While large‐scale synchrotron sources provide a highly brilliant monochromatic X‐ray beam, these X‐ray sources are expensive in terms of installation and maintenance, and require large amounts of space due to the size of storage rings for GeV electrons. On the other hand, laboratory X‐ray tube sources can easily be implemented in laboratories or hospitals with comparatively little cost, but their performance features a lower brilliance and a polychromatic spectrum creates problems with beam hardening artifacts for imaging experiments. Over the last decade, compact synchrotron sources based on inverse Compton scattering have evolved as one of the most promising types of laboratory‐scale X‐ray sources: they provide a performance and brilliance that lie in between those of large‐scale synchrotron sources and X‐ray tube sources, with significantly reduced financial and spatial requirements. These sources produce X‐rays through the collision of relativistic electrons with infrared laser photons. In this study, an analysis of the performance, such as X‐ray flux, source size and spectra, of the first commercially sold compact light source, the Munich Compact Light Source, is presented. 相似文献
22.
The microwave part of the dielectric spectrum (ν ? 1 GHz) is considered of aqueous phospholipid solutions in the limit of high water content. A continuum model is presented which allows to calculate in the water relaxation region the frequency-dependent complex permittivity of solutions in which the bilayers form globular single-walled vesicles as well as multilamellar liposomes. The model is not only capable of explaining the strikingly small values of the extrapolated static permittivity and of the main dielectric relaxation time which became evident in many measurements on colloidal aqueous solutions of phospholipids. It also allows the positive and negative step-like changes in the dielectric properties of solutions, which have been found at the main (order-disorder) phase transition temperature of the bilayers, to be explained by dimensional changes as resulting from vesicle growth and fusion. 相似文献
23.
Alexander Horn Ilja Mingareev Alexander Werth Martin Kachel Udo Brenk 《Applied Physics A: Materials Science & Processing》2008,93(1):165-169
Lead-free piezoelectric ceramics Bi0.5(Na1-x-yKxAgy)0.5TiO3 [BNKAT(x/y)] have been synthesized by the mixed oxide method. The effects of the amount of K+ and Ag+ on the electrical properties were examined. X-ray diffraction patterns indicate that K+ and Ag+ ions partially substitute for the Na+ ions in Bi0.5Na0.5TiO3 and form a solid solution during sintering. At room temperature, the ceramics exhibit good performances with piezoelectric
constant d33=189 pC/N, electromechanical coupling factor kp=35.0%, remanent polarization Pr=39.5 μC/cm2, and coercive field Ec=3.3 kV/mm, respectively. The curves of the dielectric constant εr and loss tangent tan δ versus temperature show that the transition temperature from ferroelectric to anti-ferroelectric phase
decreases with increasing the K+ content for the compositions researched. The dependencies of kp and polarization versus electric (P–E) hysteresis loops on temperature reveal that the depolarization temperature Td of BNKAT(0.15/0.015) ceramics, which have good piezoelectric properties (d33=134 pC/N, kp=32.5%) and strong ferroelectricity (Pr=39.5 μC/cm2, Ec=4.1 kV/mm) at room temperature, is above 160 °C.
PACS 77.22.-d; 77.65.Bn; 77.80.Bh; 77.80.Dj; 77.84.Dy 相似文献
24.
J. Dorenbosch F. Udo J. V. Allaby U. Amaldi G. Barbiellini M. Baubillier F. Bergsma A. Capone W. Flegel F. Grancagnolo M. Jonker L. Lanceri M. Metcalf C. Nieuwenhuis J. Panman R. Plunkett C. Santoni K. Winter I. Abt F. W. Büsser H. Daumann P. D. Gall T. Hebbeker F. Niebergall P. Stähelin P. Gorbunov E. Grigoriev V. Kaftanov V. Khovansky A. Rosanov A. Baroncelli L. Barone B. Borgia C. Bosio M. Diemoz U. Dore F. Ferroni E. Longo L. Luminari P. Monacelli S. Morganti F. de Notaristefani L. Tortora V. Valente CHARM Collaboration 《Zeitschrift fur Physik C Particles and Fields》1989,41(4):567-589
A determination of sin2 θ w based on measurements of elastic scattering of muon-neutrinos and muon-anti-neutrinos on atomic electrons is described. These purely leptonic processes were studied using the CHARM calorimeter exposed to neutrino and antineutrino wide-band beams at the CERN super proton synchrotron. A total of 83±16 neutrino-electron and 112±21 antineutrino-electron events have been detected. From the measurement of the ratio of muon-neutrino and muon-antineutrino cross-sections a value of sin2 θ w =0.211±0.037 was obtained. 相似文献
25.
Phase resolved optical emission spectroscopy of coaxial microplasma jet operated with He and Ar 总被引:1,自引:0,他引:1
26.
27.
28.
Matthias Lffler Benedikt Schlicke Heike Schirmer Arnulf-Dieter Schlüter 《Macromolecular Symposia》1994,87(1):5-10
The polymer analogous aromatization of double-stranded Diels-Alder polymers to give fully unsaturated, all-carbon ladder polymers by means of dehydration and dehydrogenation is described. The polymers obtained were characterized by solid state 13C NMR spectroscopy. 相似文献
29.
Miriam R. B. Porzberg Laust Moesgaard Catrine Johansson Udo Oppermann Jacob Kongsted Jasmin Mecinovi 《Molecules (Basel, Switzerland)》2022,27(3)
Epigenetic readout of the combinatorial posttranslational modification comprised of trimethyllysine and asymmetric dimethylarginine (H3K4me3R8me2a) takes place via biomolecular recognition of tandem Tudor-domain-containing protein Spindlin1. Through comparative thermodynamic data and molecular dynamics simulations, we sought to explore the binding scope of asymmetric dimethylarginine mimics by Spindlin1. Herein, we provide evidence that the biomolecular recognition of H3K4me2R8me2a is not significantly affected when R8me2a is replaced by dimethylarginine analogues, implying that the binding of K4me3 provides the major binding contribution. High-energy water molecules inside both aromatic cages of the ligand binding sites contribute to the reader–histone association upon displacement by histone peptide, with the K4me3 hydration site being lower in free energy due to a flip of Trp151. 相似文献
30.