全文获取类型
收费全文 | 342篇 |
免费 | 6篇 |
专业分类
化学 | 211篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 34篇 |
物理学 | 100篇 |
出版年
2021年 | 3篇 |
2020年 | 5篇 |
2018年 | 3篇 |
2017年 | 5篇 |
2016年 | 10篇 |
2015年 | 5篇 |
2014年 | 7篇 |
2013年 | 16篇 |
2012年 | 19篇 |
2011年 | 26篇 |
2010年 | 11篇 |
2009年 | 9篇 |
2008年 | 12篇 |
2007年 | 19篇 |
2006年 | 21篇 |
2005年 | 15篇 |
2004年 | 10篇 |
2003年 | 10篇 |
2002年 | 9篇 |
2001年 | 3篇 |
2000年 | 7篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 4篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1986年 | 6篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1981年 | 10篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1969年 | 2篇 |
1965年 | 2篇 |
1964年 | 4篇 |
1958年 | 2篇 |
1956年 | 3篇 |
1939年 | 2篇 |
1938年 | 2篇 |
排序方式: 共有348条查询结果,搜索用时 15 毫秒
51.
52.
The influence of a magnetic field on a vibrating piezoelectric medium is studied. It is found that the magnetic induction weakly influences the vibrations of this medium. 相似文献
53.
The paper aims at the analysis of principal factors affecting interaction of radiocobalt with freshwater solids, important for migration of radiocobalt in surface streams. Uptake and release of radiocobalt by sediment from a small river have been studied as a function of pH and composition of aqueous phase, the cobalt concentration and contact time, using laboratory model experiments. A factor of primary importance is the contact time due to slow and two-step kinetics of radiocobalt uptake, which also strongly depends on the concentration of sediment in suspension. pH exerts the most significant effect on the interaction in the pH region of 5–7.5, where the uptake increases with pH. Ionic strength of water phase (I) and concentration of cobalt in water (c) affect the interaction only at rather high values of I or c and their variation can be neglected in the modelling of radiocobalt transport in streams under ordinary conditions. Desorption by river water of radiocobalt pre-adsorbed on the sediment passes through a maximum with desorption time, decreases with increasing adsorption time and increases upon drying of the sediment prior to desorption. Results obtained are compared with literature data and conclusions are drawn concerning the mechanism of radiocobalt uptake by the sediment. 相似文献
54.
F. Soška F. Beneš S. Jura B. Gross Z. šimša F. Kosek J. Horák J. Kašpar K. čermák J. Lipták M. Ryba E. F. Holländer A. Havránek E. Havránková A. Kochanovská J. Sommer F. Vilím P. Lukáš C. Rumler S. Kadečková F. Vávra M. Matyáš J. Beneš J. Kučera L. DvoŘák Z. KudĚlásek J. Hájek A. Marek Z. Malec J. Janků B. Sojka L. Karmazin M. Ryšavá L. Janko K. Huml 《Czechoslovak Journal of Physics》1961,11(11):852-862
55.
The influence of size and geometrical shape on the optical properties of randomly oriented metallic nanorods is investigated using the discrete dipole approximation (DDA). Our calculations provide a benchmark for an accurate characterisation of nanorod suspensions by frequently used optical spectroscopic techniques. Our DDA results confirm the longitudinal plasmon resonance to be primarily affected by the nanorod aspect ratio, and also verify that the quasi-static (dipole) approximation for ellipsoidal particles is only valid for very small sizes. For prolate ellipsoidal and cylindrical nanorods with an identical aspect ratio, the latter exhibit a longitudinal resonance at significantly longer wavelengths. The importance of phase retardation and multipole contributions for larger nanorod dimensions is discussed. Also, we investigate the influence on the optical spectra of electron surface scattering, which arises from the limited size of the nanorods in comparison to the electron mean free path. 相似文献
56.
Del Bene JE Elguero J Alkorta I Yañez M Mó O 《The journal of physical chemistry. A》2006,110(32):9959-9966
Ab initio equation-of-motion coupled-cluster singles and doubles (EOM-CCSD) calculations have been performed to investigate substituent effects on coupling constants for borazine and selected substituted borazines. For molecules in which F atoms are not bonded to adjacent atoms in the ring, F substitution increases the one-bond (11)B-(15)N coupling constants involving the atom at which substitution occurs but leaves the remaining one-bond B-N coupling constants essentially unchanged. For these molecules, the magnitudes of one-bond B-N coupling constants are only slightly dependent on the number of F atoms present. Fluorine substitution at adjacent B and N atoms in the borazine ring further increases the one-bond B-N coupling constant involving the substituted atoms and has the same effect on the other one-bond coupling constants as observed for corresponding molecules in which substitution occurs at alternate sites. In contrast to the effect of F substitution, substitution of Li at either N or B decreases one-bond B-N coupling constants relative to borazine. The effects of F and Li substitution on one-bond B-N coupling constants for borazine are similar to F and Li substitution effects on (13)C-(13)C coupling constants for benzene. 相似文献
57.
Karplus-type equations are derived for the variation of one-bond X-Y coupling constants 1J(X-Y) as a function of dihedral angle for molecules HmX-YHn, for X, Y, = 15N, 17O, 31P, and 33S. Coupling constants were obtained from ab initio EOM-CCSD calculations, with all terms evaluated. The relative orientation of lone pairs appears to be a primary factor determining the dependence of 1J(X-Y) on the dihedral angle. 相似文献
58.
Vibrationally highly excited molecules react extremely fast with atoms and probably with radicals. The phenomenon can be utilized for selectively enhancing the rate of reactions of specific bonds. On the basis of quasiclassical trajectory calculations, the paper analyzes mechanistic details of a prototype reaction, H + HF(v). At vibrational quantum numbers v above 2, the reaction exhibits capture-type behavior, that is, the reactive cross section diverges as the relative translational energy of the partners decreases, both for the abstraction and for the exchange channel. The mechanism of the reaction for both channels is different at low and at high translational energy. At low vibrational energy, the reaction is activated, which is switched to capture-type at high excitation. The reason is an attractive potential that acts on the attacking H atom when the HF molecule is stretched. In contrast to the 6-SEC potential surface of Mielke et al., the switch cannot be observed on the Stark-Werner potential surface, due to a small artificial barrier at high H-HF separation, preventing the reactants from obeying the attractive potential and also proving the importance of the latter. The exchange reaction can be observed even when the total energy available for the partners is below the exchange barrier, because at low translational energies the product F atom of a successful abstraction step can re-abstract that H atom from the intermediate product H2 molecule that was originally the attacker. 相似文献
59.
Ion yield measurements are presented |of 2–10 keV helium ions scattered from a copper (100) face. The scattering angle is 30°. The results are explained using a charge transfer model originally proposed by the authors. The model takes into account Auger neutralization as well as ionization and neutralization resulting from a violent collision. The present results are compared with previous] experiments in which a primary atom beam was used. Within the experimental errors the results |of both experiments can be explained using the same charge exchange parameters. A second result of the present investigation is that more convincing evidence is given for the occurrence of neutralization during the violent collision by a non-Auger process. It is probable that this process, as well as the ionization process, results from an interaction between the helium particle and the copper L shell electrons. 相似文献
60.
Spin-spin coupling constants (2h)J(F-F), (1)J(F-H), and (1h)J(H-F) have been obtained for cyclic complexes (FH)(n), with n=2-6, from ab initio equation-of-motion coupled cluster singles and doubles (EOM-CCSD) calculations. Although both the Fermi-contact (FC) term and (2h)J(F-F) increase and become positive as the cluster size increases, the FC term is not a good quantitative approximation to (2h)J(F-F). The paramagnetic spin-orbit (PSO) and spin-dipole (SD) terms which contribute to (2h)J(F-F) appear to be sensitive to the orientation of the hydrogen-bonded pair. However, the large increase in the FC term and (2h)J(F-F) as the size of the cluster increases is due primarily to the reorganization of sigma electron densities in both ground and excited states, and is another manifestation of cooperativity effects in hydrogen-bonded cyclic polymers. The FC term and (1)J(F-H) always increase upon complex formation, but (1)J(F-H) increases only slightly as the size of the cluster increases due to a concurrent decrease in the PSO term. The changes in (1)J(F-H) as a function of polymer size reflect the polarization of electron density away from H and toward F in the ground state, and the electron reorganization which occurs in the excited states which couple to the ground states through the FC and PSO operators. The FC term is a good approximation to (1h)J(H-F), and is always negative, indicating that the hydrogen bonds in the FH clusters are traditional hydrogen bonds. 相似文献