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31.
N. M. Aristova G. V. Belov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(3):700-703
Refined thermodynamic functions (entropy, enthalpy increments, and reduced Gibbs energy) of scandium trifluoride ScF3 in the crystalline and liquid states in the temperature range 5–2500 K are presented. 相似文献
32.
A. G. Belov 《Moscow University Computational Mathematics and Cybernetics》2018,42(3):114-118
The problem is considered of modeling simultaneous confidence intervals for the mean values of multiple responses in a linear multivariate normal regression model with predictor variables defined in intervals. To solve it, a numerical way of calculating the critical value that determines the simultaneous confidence interval of a given level is used. Simultaneous confidence intervals are numerically modelled and analyzed by comparison for regression, the mean value of multiple responses, and individual observation. 相似文献
33.
O. M. Chukanova K. A. Alferov A. V. Chernyak G. P. Belov 《Polymer Science Series B》2013,55(1-2):14-21
Terpolymers of carbon monoxide with ethylene and styrene are synthesized in the presence of supported palladium catalyst in toluene and heptane medium for the first time. The terpolymerization rate exceeds the rate of carbon monoxide and ethylene copolymerization. The maximum terpolymer yield amounts 7.9 g per g of supported catalyst per hour or 321 g per g of palladium per hour. The influence of reaction temperature, pressure, 1.4-benzoquinone amount and co-monomers mole ratio on the yield and the composition of terpolymer have been studied. The NMR 13C data obtained testify to a distribution of ethylene and styrene units in terpolymer with the predominance of short blocks at equal contents of comonomer units. 相似文献
34.
Nataliya A. Samoylova Nikita M. Belov Victor A. Brotsman Dr. Ilya N. Ioffe Dr. Natalia S. Lukonina Dr. Vitaliy Yu. Markov Dr. Adrian Ruff Alexey V. Rybalchenko Paul Schuler Olesya O. Semivrazhskaya Prof. Dr. Bernd Speiser Prof. Dr. Sergey I. Troyanov Prof. Dr. Tatiana V. Magdesieva Dr. Alexey A. Goryunkov 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(52):17969-17979
Novel difluoromethylenated [70]fullerene derivatives, C70(CF2)n (n=1–3), were obtained by the reaction of C70 with sodium difluorochloroacetate. Two major products, isomeric C70(CF2) mono‐adducts with [6,6]‐open and [6,6]‐closed configurations, were isolated and their homofullerene and methanofullerene structures were reliably determined by a variety of methods that included X‐ray analysis and high‐level spectroscopic techniques. The [6,6]‐open isomer of C70(CF2) constitutes the first homofullerene example of a non‐hetero [70]fullerene derivative in which functionalisation involves the most reactive bond in the polar region of the cage. Voltammetric estimation of the electron affinity of the C70(CF2) isomers showed that it is substantially higher for the [6,6]‐open isomer (the 70‐electron π‐conjugated system is retained) than the [6,6]‐closed form, the latter being similar to the electron affinity of pristine C70. In situ ESR spectroelectrochemical investigation of the C70(CF2) radical anions and DFT calculations of the hyperfine coupling constants provide evidence for the first example of an inter‐conversion between the [6,6]‐closed and [6,6]‐open forms of a cage‐modified fullerene driven by an electrochemical one‐electron transfer. Thus, [6,6]‐closed C70(CF2) constitutes an interesting example of a redox‐switchable fullerene derivative. 相似文献
35.
A. V. Solnyshkin A. A. Bogomolov D. Yu. Karpenkov I. L. Kislova A. N. Belov 《Technical Physics》2016,61(4):541-546
The electric response of layered 2-2 connectivity magnetoelectric composites to the action of a modulated heat flow, which is detected by a dynamic method, is studied. The kinetics of the pyroelectric response of the composite material to a pulsed thermal action is calculated. The experimental results and calculation data suggest that a modulated heat action induces a signal due to both the pyroelectric and piezoelectric effects. The latter effect is caused by the mechanical interaction of the layers of lead zirconate titanate ceramic and nickel–zinc (Ni–Zn) ferrite. 相似文献
36.
37.
Maxim A. Gorlach Mingzhao Song Alexey P. Slobozhanyuk Andrey A. Bogdanov Pavel A. Belov 《固体物理学:研究快报》2016,10(12):900-904
Employing nonlocal homogenization approach, we investigate the properties of a metamaterial consisting of parallel metallic wires with dielectric coating. We demonstrate that manipulation of dielectric contrast between wire dielectric shell and host material at fixed frequency results in dynamic switching of metamaterial dispersion regime from elliptic to the hyperbolic one, i.e. the topological transition takes place. It is proved that such transition can be induced by the variation of the metamaterial temperature. Our findings thus pave a way to the implementation of a tunable ‘elliptic‐hyperbolic’ metamaterial. 相似文献
38.
The potential of seismic exploration instruments for estimating the surface layers of soil in the towing zone of an extended multielement array is investigated. In contrast to the well-known method of common depth point, in which the main estimated parameters are the transit times of waves reflected from deep layers of the sea bottom, two-dimensional spectral analysis is used to measure the longitudinal wavenumbers of the modes forming an infrasonic field in the water layer. The measured longitudinal wavenumbers of modes serve initial data for estimating the acoustic characteristics of the upper layers of bottom sediments directly in the towing zone of pulse emitter and extended multielement array. It is concluded that the use of data on the parameters of upper soil layers in seismic exploration should increase the accuracy of contouring oil and gas condensate fields. 相似文献
39.
Transalkylation of Higher Trifluoromethylated Fullerenes with C70: A Pathway to New Addition Patterns of C70(CF3)8
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Nikita M. Belov Marina G. Apenova Alexey V. Rybalchenko Eugenia V. Borkovskaya Dr. Natalia S. Lukonina Dr. Alexey A. Goryunkov Dr. Ilya N. Ioffe Prof. Dr. Sergey I. Troyanov Prof. Dr. Lev N. Sidorov 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(4):1126-1133
We report three new isomers of C70(CF3)8, structurally related to p7mp‐C70(CF3)10, that are inaccessible by direct trifluoromethylation, but can be easily identified among the products of the transalkylation of higher trifluoromethylfullerenes with C70. The reported compounds are characterized by UV/Vis, 1 D and 2 D COSY 19F NMR spectroscopy, and DFT calculations. A rather unusual addition pattern is observed in p6,i‐C70(CF3)8 in which one addend is attached remotely from the others; polarization of the adjacent unsaturated bonds by the addend makes the molecule readily oxidizable. 相似文献
40.
Polar Red‐Emitting Rhodamine Dyes with Reactive Groups: Synthesis,Photophysical Properties,and Two‐Color STED Nanoscopy Applications
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Dr. Kirill Kolmakov Dr. Christian A. Wurm M. Sc. Dirk N. H. Meineke Dipl.‐Biol. Fabian Göttfert Prof. Vadim P. Boyarskiy Dr. Vladimir N. Belov Prof. Stefan W. Hell 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(1):146-157
The synthesis, reactivity, and photophysical properties of new rhodamines with intense red fluorescence, two polar residues (hydroxyls, primary phosphates, or sulfonic acid groups), and improved hydrolytic stability of the amino‐reactive sites (NHS esters or mixed N‐succinimidyl carbonates) are reported. All fluorophores contain an N‐alkyl‐1,2‐dihydro‐2,2,4‐trimethylquinoline fragment, and most of them bear a fully substituted tetrafluoro phenyl ring with a secondary carboxamide group. The absorption and emission maxima in water are in the range of 635–639 and 655–659 nm, respectively. A vastly simplified approach to red‐emitting rhodamines with two phosphate groups that are compatible with diverse functional linkers was developed. As an example, a phosphorylated dye with an azide residue was prepared and was used in a click reaction with a strained alkyne bearing an N‐hydroxysuccinimid (NHS) ester group. This method bypasses the undesired activation of phosphate groups, and gives an amphiphilic amino‐reactive dye, the solubility and distribution of which between aqueous and organic phases can be controlled by varying the pH. The presence of two hydroxyl groups and a phenyl ring with two carboxyl residues in the dyes with another substitution pattern is sufficient for providing the hydrophilic properties. Selective formation of a mono‐N‐hydroxysuccinimidyl ester from 5‐carboxy isomer of this rhodamine is reported. The fluorescence quantum yields varied from 58 to 92 % for free fluorophores, and amounted to 18–64 % for antibody conjugates in aqueous buffers. The brightness and photostability of these fluorophores facilitated two‐color stimulated emission depletion (STED) fluorescence nanoscopy of biological samples with high contrast and minimal background. Selecting a pair of fluorophores with absorption/emission bands at 579/609 and 635/655 nm enabled two‐color channels with low cross‐talk and negligible background at approximately 40 nm resolution. 相似文献