Violation of the additivity rule for the ion energy loss in hydrocarbons

Based on the experimental data, the rule of additivity of energy losses in hydrocarbon compounds is shown to be violated at low ion energies. This indicates the necessity of taking into account the chemical bonds in molecular targets. Deviation from the additivity rule increases with increasing nuclear charge of incident ions and decreases with increasing ion energy. The additivity rule is most strongly violated in the molecular targets with double and triple carbon-carbon bonds.     

Energy losses of beryllium ions penetrating through thin films before the attainment of charge equilibrium

The dependences between the energy losses of beryllium ions penetrating through thin organic (celluloid) films and the initial ion charge i ₀ and target thickness t are calculated. The proposed modified method is used to determine the charge fractions and average charge of an ion beam and the half-width and skewness of the charge distributions before the attainment of charge equilibrium. Calculations are performed for Be ⁱ⁺ ions with a velocity of 8 × 10⁸ cm/s (E = 0.33 MeV/nucleon).     

Intermolecular hydrogen bonding between neutral transition metal hydrides (eta(5)-C5H5)M(CO)3H (M = Mo, W) and bases

The interaction of CpM(CO)3H (M = Mo, W) hydrides as proton donors with different bases (B = pyridine, (n-Oc)3PO, ((CH3)2N)3PO, H3BNEt3) was studied by variable temperature IR spectroscopy and theoretically by DFT/B3LYP calculations. The data obtained show for the first time the formation of intermolecular hydrogen bonds between the neutral transition metal hydrides and bases in solutions of low polarity. These M-H...B hydrogen bonds are shown to precede the hydrides' deprotonation.