全文获取类型
收费全文 | 567篇 |
免费 | 23篇 |
国内免费 | 5篇 |
专业分类
化学 | 406篇 |
晶体学 | 7篇 |
力学 | 14篇 |
数学 | 45篇 |
物理学 | 123篇 |
出版年
2023年 | 1篇 |
2022年 | 7篇 |
2021年 | 4篇 |
2020年 | 13篇 |
2019年 | 10篇 |
2018年 | 13篇 |
2017年 | 14篇 |
2016年 | 26篇 |
2015年 | 15篇 |
2014年 | 23篇 |
2013年 | 31篇 |
2012年 | 48篇 |
2011年 | 46篇 |
2010年 | 33篇 |
2009年 | 28篇 |
2008年 | 45篇 |
2007年 | 38篇 |
2006年 | 46篇 |
2005年 | 40篇 |
2004年 | 22篇 |
2003年 | 12篇 |
2002年 | 15篇 |
2001年 | 7篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1998年 | 7篇 |
1997年 | 3篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1975年 | 1篇 |
1971年 | 1篇 |
1963年 | 1篇 |
1931年 | 1篇 |
1930年 | 1篇 |
1926年 | 1篇 |
1900年 | 1篇 |
排序方式: 共有595条查询结果,搜索用时 31 毫秒
21.
22.
A. A. Bel’mesov A. V. Levchenko T. A. Palankoev L. S. Leonova A. E. Ukshe A. I. Chikin N. G. Bukun 《Russian Journal of Electrochemistry》2013,49(8):831-835
Electrocatalysts based on platinized titania modified with ruthenia (0–9 mol %) were studied. The synthesized materials were investigated as working electrodes in potentiometric sensors sensitive to hydrogen and carbon monoxide. All electrocatalysts showed reproducible behavior at pure gas concentrations from 400 to 4000 ppm. In CO-H2 mixtures with comparable concentrations of both gases, the sensors were selective toward hydrogen at ≥0.05 mol % Ru, but not selective to hydrogen or CO at less than 0.05 mol % Ru in the substrate. 相似文献
23.
Successive action of α-bromoesters and organometallics on hydroximates constitute a good way to obtain - 5,6 dihydro-1,4,2 dioxazines. 相似文献
24.
Víctor García-Vázquez Alba Carretero Cerdán Dr. Amparo Sanz-Marco Prof. Enrique Gómez-Bengoa Prof. Belén Martín-Matute 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(44):e202201000
In this paper, we present an unprecedented and general umpolung protocol that allows the functionalization of silyl enol ethers and of 1,3-dicarbonyl compounds with a large range of heteroatom nucleophiles, including carboxylic acids, alcohols, primary and secondary amines, azide, thiols, and also anionic carbamates derived from CO2. The scope of the reaction also extends to carbon-based nucleophiles. The reaction relies on the use of 1-bromo-3,3-dimethyl-1,3-dihydro-1λ3[d][1,2]iodaoxole, which provides a key α-brominated carbonyl intermediate. The reaction mechanism has been studied experimentally and by DFT, and we propose formation of an unusual enolonium intermediate with a halogen-bonded bromide. 相似文献
25.
Accurate control of a liquid-crystal display to produce a homogenized Fourier transform for holographic memories 总被引:1,自引:0,他引:1
Márquez A Gallego S Méndez D Alvarez ML Fernández E Ortuño M Neipp C Beléndez A Pascual I 《Optics letters》2007,32(17):2511-2513
We show an accurate procedure to obtain a Fourier transform (FT) with no dc term using a commercial twisted-nematic liquid-crystal display. We focus on the application to holographic storage of binary data pages, where a drastic decrease of the dc term in the FT is highly desirable. Two different codification schemes are considered: binary pi radians phase modulation and hybrid ternary modulation. Any deviation in the values of the amplitude and phase shift generates the appearance of a strong dc term. Experimental results confirm that the calculated configurations provide a FT with no dc term, thus showing the effectiveness of the proposal. 相似文献
26.
V. I. Lad’yanov S. G. Men’shikova A. L. Bel’tyukov B. B. Maslov 《Bulletin of the Russian Academy of Sciences: Physics》2010,74(8):1176-1178
We investigate the temperature and time dependences of viscosity of Al99Y1, Al97Y3, Al95Y5 melts in the range from liquidus to 1200°C. By metallographic, XRD, and differential thermal analyses, we study how the time
of isothermal holding of melts influences the structure of ingots during hardening. 相似文献
27.
L. L. Tolstikova A. V. Bel’skikh B. A. Shainyan 《Russian Journal of General Chemistry》2010,80(6):1189-1192
The reaction of N-sulfinyltrifluoromethanesulfonamide with triphenylphosphine and triphenylphosphine oxide or of trifluoromethanesulfonamide
with dichloro(triphenyl)phosphorane leads to trifluoro-N-(triphenyl-λ5-phosphanylidene)methanesulfonamide, which is hydrolyzed to trifluoromethanesulfonamide and triphenylphosphine oxide via the
intermediate trifluoro-N-[hydroxy(triphenyl)phosphoranyl]methanesulfonamide. 相似文献
28.
N. Bel Baraka 《International Journal of Theoretical Physics》2002,41(4):737-752
Comparing the star product defined by Takhtajan on the Poisson–Lie group GL(2) and any star product calculated from the Kontsevich's graphs (any K-star product) on the same group, we show, by direct computation, that the Takhtajan star product on GL(2) can't be written as a K-star product. 相似文献
29.
30.
This article reviews the most relevant chemical and structural aspects that influence the spin-crossover phenomenon (SCO). Special attention is focussed on the recent development of SCO coordination polymers. The different approaches currently being explored in order to achieve multifunctionality in SCO materials are discussed. 相似文献