Effect of matrix domination in PANI interpolymer complexes with polyamidosulfonic acids

Various polyaniline (PANI) interpolymer complexes with polyacids in the form of molecular solutions were synthesized by chemical oxidative polymerization of aniline in the presence of water-soluble poly-(2-acrylamido-2-methyl-1-propanesulfonic acid) (flexible backbone), poly-p,p′-(2,2′-disulfoacid)-diphenylene-terephthalamide (t-PASA, rigid backbone), and their mixtures in different ratios. The complexes were characterized by UV-Vis-near infrared spectroscopy in solutions; also, the films’ drop-casts from these solutions were investigated by cyclic voltammetry, spectroelectrochemical, direct current (DC) conductivity, and atomic force microscopy (AFM) measurements. It was shown that the nature of polyacid affects the shape of spectra and the dynamics of their changes. The character of spectral changes during the matrix synthesis of PANI in the presence of mixtures of the rigid-chain and flexible-chain matrixes and the study of spectral properties of the obtained PANI solutions demonstrates the existence of the rigid-matrix domination effect in the process of formation of PANI interpolymer complexes. Spectral properties of the obtained PANI complexes with the mixtures of flexible-chain and rigid-chain polyacids of different ratios (3:1, 1:1, 1:3, and 1:6) are very similar to those ones for the complex with rigid-chain t-PASA. At the same time, there is a correlation between the electrical conductivity and morphology of the films of PANI complexes and their composition, the conductivity passing through a minimum for the complexes with the polyacid mixtures (6:1, 3:1, and 1:1).     

Two new steroidal saponins, hylodoside A and novaeguinoside Y, from the starfish Leptasterias hylodes reticulata and Culcita novaeguineae (juvenile)

New steroid glycosides, hylodoside A (1) and novaeguinoside Y (2), along with previously known polyhydroxylated steroids (3-7) were isolated from the ethanolic extracts of the starfish Leptasterias hylodes reticulata and Culcita novaeguineae (juvenile). The structures have been elucidated using 1D and 2D NMR spectra (1H, 13C, DEPT, COSY-45, 1D-TOCSY, HSQCGP, ROESY, HSQC and HMBCGP) and mass spectrometry. Compound 3 was shown to inhibit the growth of Staphylococcus aureus up to 10% from the control at a concentration of 1 mg/mL. Steroids 1, 2 and 5 showed moderate hemolytic activity in the mouse erythrocytes assay. Compounds 3, 4 and 6 displayed pH-depended hemolytic properties.     

Low-loss multilayered metamaterial exhibiting a negative index of refraction at visible wavelengths

We experimentally demonstrate a low-loss multilayered metamaterial exhibiting a double-negative refractive index in the visible spectral range. To this end, we exploit a second-order magnetic resonance of the so-called fishnet structure. The low-loss nature of the employed magnetic resonance, together with the effect of the interacting adjacent layers, results in a figure of merit as high as 3.34. A wide spectral range of negative index is achieved, covering the wavelength region between 620 and 806 nm with only two different designs.     

Choice of targets for inertial confinement fusion

We propose a simple target in the form of a miniature torus, in which the heavy shell is used to confine the plasma spread, for a solution of the laser-fusion problem. We achieve a significant decrease of heat losses using an external magnetic field and/or as a result of a self-sustaining magnetic field that is generated in the plasma. We formulate the conditions and determine the energy of the laser pulse (or of a beam of fast charged particles) required to ignite a thermonuclear DD reaction and obtain a positive energy yield. We show that the stopping range of α-particles does not exceed the small radius of the torus within a broad range of the plasma and magnetic-field parameters.     

Guiding light at the nanoscale: numerical optimization of ultrasubwavelength metallic wire plasmonic waveguides

We present a comprehensive numerical analysis of the guiding of a photonic signal in the form of a strongly confined asymmetric surface plasmon polariton (SPP) mode along metallic nanowire waveguides. The proposed approach provides extremely high localization of the SPP mode, nanoscale integration density, and a feasible technological platform. The waveguide performance was studied over a broad range of subwavelength cross sections at a telecommunication wavelength. It was optimized using a conventional figure of merit for data transfer along a straight waveguide and an all-inclusive figure of merit has been introduced.     

Vortex structures with complex points singularities in two-dimensional Euler equations. New exact solutions

In this work we present a new class of exact stationary solutions for two-dimensional (2D) Euler equations. Unlike already known solutions, the new ones contain complex singularities. We consider point singularities which have a vector field index greater than 1 as complex. For example, the dipole singularity is complex because its index is equal to 2. We present in explicit form a large class of exact localized stationary solutions for 2D Euler equations with a singularity whose index is equal to 3. The solutions obtained are expressed in terms of elementary functions. These solutions represent a complex singularity point surrounded by a vortex satellite structure. We also discuss the motion equation of singularities and conditions for singularity point stationarity which provide the stationarity of the complex vortex configuration.     

Simultaneous establishing of stationary growth rate and composition of supercritical droplets at isothermal binary condensation in the diffusion-controlled regime

General integral relations expressing the droplet radius and time of the droplet nonstationary growth as nonlinear functions of solution concentration in the droplet have been derived. These relations are valid for a supercritical droplet (i.e., sufficiently large droplet, for which the Laplace pressure effect on the concentration at saturation of vapors is negligible) isothermally growing via stationary diffusion in the mixture of two condensing vapors and an incondensable carrier gas. The initial composition in the droplet may be arbitrary and partial molecular volumes of components are not fixed. Explicit analytical relations have been found for droplet composition and the droplet size as functions of time at small deviations from the stationary concentration in the growing droplet. These relations show that the assumption of the steady droplet growth rate is not valid for non-small deviations from the stationary concentration. Some illustrations of the general nonlinear theory have been done in situation when solution in the droplet can be considered ideal.