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91.
A. Matos Beja J. A. Paixo M. Ramos Silva L. Alte da Veiga A. M. d'A. Rocha Gonsalves A. C. Serra 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(3):354-355
The molecules of the title compound, C7H5BrO2, form zigzag chains running along the b axis and are stacked in layers perpendicular to the a axis. Intermolecular bonding occurs through hydrogen bonds linking the hydroxyl and carbonyl groups, with an O?O distance of 2.804 (4) Å. The Br atom deviates significantly from the plane of the ring and the aldehyde group is twisted by 7.1 (5)° around the Csp2—Caryl bond. The geometry of the molecule in the crystal is compared to that given by ab initio quantum mechanical calculations for the isolated molecule, using a molecular orbital Hartree–Fock method and density functional theory. 相似文献
92.
V. H. Rodrigues J. A. Paixo M. M. R. R. Costa A. Matos Beja 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):1053-1055
The title compound, C3H8NO2+·C2F3O2?, crystallizes in space group C2/c. The main N—C—COOH skeleton of the protonated sarcosine molecule is almost perfectly planar. The trifluoroacetate anion has a staggered conformation and typical bond distances and angles. The CF3 group is probably slightly disordered. The structure is stabilized by an extensive network of strong O—H?O hydrogen bonds and weaker N—H?O bonds. 相似文献
93.
J. A. Paixo A. Matos Beja M. Ramos Silva J. Martin‐Gil 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):1132-1135
In the title compounds, C6H5NH3+·H2PO3? and C6H5NH3+·C2HO4?·0.5H2O, the NH3+ groups of the anilinium ion are ordered at room temperature. The rotation of these groups along the N—Caryl bond, which is often observed at room temperature in other anilinium compounds, is prevented by hydrogen bonds between the NH3+ group and the anions. In both compounds, the geometry of the cation is significantly distorted from D6h to a symmetry close to C2v. The angle ipso to the substituent is significantly larger than 120°, as expected from the σ‐electron‐withdrawing character of the NH3+ group. 相似文献
94.
95.
96.
A. Matos Beja V. H. Rodrigues J. A. Paixo M. M. R. R. Costa 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(2):o71-o72
The title compound, C2H6NO2+·C2Cl3O2−, crystallizes in the P41 space group with two glycinium cations and two trichloroacetate anions in the asymmetric unit. The glycinium cations have nearly Cs point‐group symmetry which is only broken by the H atoms of the amine group. The trichloroacetate anions show typical bond lengths and angles, one of the trichloromethyl groups being disordered. Chains of alternating anions and cations run along the c axis. Within these chains, consecutive anion–cation pairs are bound via strong hydrogen bonds involving the carboxylate anions and the carboxyl or amine groups of the cations. Weaker hydrogen bonds bind neighbouring chains together. 相似文献
97.
Manuela Ramos Silva Ana Matos Beja Jose Antonio Paixo Abilio J. F. N. Sobral Lucia M. L. Cabral A. M. d'A. Rocha Gonsalves 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(10):o562-o563
Molecules of the title 2,5‐dioxopiperazinedione derivative, C8H10N2O6, occupy centres of symmetry in the crystal structure. The six‐membered ring has an almost planar conformation, with the substituent on nitrogen nearly perpendicular to the ring. The ideal geometry of the isolated molecule, as determined by ab initio HF–LCAO quantum‐mechanical calculations, is slightly more puckered than that observed in the solid state. In the crystal structure, a strong hydrogen bond joins neighbouring molecules, thus forming a network of rectangular (30) rings. 相似文献
98.
99.
M. Ramos Silva A. Matos Beja J. A. Paixo L. Alte da Veiga J. Martin‐Gil 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(5):542-545
The title compound, [Fe3(C5H11NO2)6O(H2O)3](MnCl4)2Cl3·6H2O, contains a triiron core linked by a μ3‐bridging oxide ion. Each of the iron(III) ions has a distorted octahedral environment, being coordinated, in addition to the oxide ion, by four neutral betaine molecules and one water molecule. The N‐alkylated α‐amino acid betaine is present in the dipolar zwitterionic form and chelates pairs of Fe atoms at the vertices of the triangular [Fe3O]7+ ionic core. The Fe complex has a crystallographically imposed D3 symmetry. The water molecules fully exhaust their potential as hydrogen donors, forming a two‐dimensional hydrogen‐bond network in planes parallel to (001). 相似文献
100.
M. Ramos Silva A. J. F. N. Sobral J. A. Silva A. C. Santos S. M. Melo A. Matos Beja 《Journal of chemical crystallography》2007,37(10):695-698
Abstract A new substituted pyrrole, a precursor of meso-free-porphyrins, has been synthesised and characterised by single-crystal X-ray
diffraction: monoclinic, P21/c with a = 14.607(9) ?, b = 5.136(2) ?, c = 25.832(17) ?, β = 108.14(5)°, Mr = 349.41, V = 1841.6(18) ?3, Z = 4. The molecules are assembled in centrosymmetric dimers via strong N–H...O hydrogen bonds. The dimers are gathered
into chains via C–H...π intermolecular interactions.
Graphical abstract The molecules in 4-benzyl-5-methoxymethyl-3-methyl-1H-pyrrole-2-carboxylic acid benzyl ester are joined in dimmers by strong
hydrogen bonds. The dimmers are aggregated in chains running along the b axis through C-H...?€ intermoleculear interactions.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献