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131.
HongBingJI DuGuiHE JunSONG YuQIAN 《中国化学快报》2004,15(10):1241-1244
Clean liquid oxidation of aldehydes can be accomplished using solid catalyst in the presence of molecular oxygen at room temperature, which is a valuable alternative to traditional counterparts. 相似文献
132.
Introduction Tremendous advances have been witnessed during the last decade in the syntheses and application of Group 4 metal complexes because of the motivity which comes from both academic and industrial field. Among them, studies have been dominated by the complexes supported by bis or mono cyclopentadienyl ligands, such as Cp2MX2 or half sandwich amide (CGC) com-plexes.1-6 At that time chemists paid a little attention to the non-cyclopentadienyl complexes, but in recent years, many chem… 相似文献
133.
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135.
Li Qiu WANG Xiao Jun PENG* Rong ZHANG Guo Quan XU Jing Nan CUI State Key Laboratory of Fine Chemicals Dalian University of Technology Dalian 《中国化学快报》2003,(1)
Indocyanine dyes as fluorescent labeling reagents have been used in bioanalysis1,2. Arylsulfonate indocyanine dyes 1d and 1e developed by Waggoner A. S. et al.3,4 have excellent fluorescent properties combined with good aqueous solubility, are a new generation of fluorescent label compounds for proteins, oligonucleotides and other compounds containing hydroxyl, mercaptol or primary amine groups5. However, photostability of these dyes has been a problem. Z. G. YAO et al.6 reported that p… 相似文献
136.
It is proved that the apparent transverse velocities β_(app) and the spectral powers at 10GHz P_(10) of the cores of known superluminal sources are correlated. An interpretation ofthis result within the framework of the relativistic jet model shows that the jet Lorentzfactor γ depends on the intrinsic luminosity of the sources. The probable existence of twosubpopulations of the superluminal sources is shown by a linear regression analysis. "Small"sources f i.e. the sources without extended emission or with a distance from the core tothe outer edge of the lobe<20 kpc, show lower β_(app) than the "large" objects; this can beinterpreted as an orientation effect. Since all BL Lac objects belong to the "small" class,this result sheds new light on such a question as why these sources have lower apparent ve-locities than the "classical" superluminal quasars. 相似文献
137.
SHEN Yehua WANG Haibo BAI Quan & GENG Xindu Institute of Modern Separation Science Shaanxi Key Laboratory of Modern Separation Science Northwest University Xi''''an China 《中国科学B辑(英文版)》2005,(Z1)
The renaturation of the denaturedα-chymotrypsin (α-Chy) with 1.7 mol·L-1 gua-nidine hydrochloride (GuHCI) by three kinds of stationary phase of high performance hydropho-bic interaction chromatography (STHIC) with a comparable hydrophobicity but different ligand structures was investigated. The obtained result indicates that the ligand structures of the three STHIC contribute to the renaturation efficiency ofα-Chy in the order of the end ligands PEG-600< phenyl group < tetrahydrofurfuryl alcohol (THFA). 相似文献
138.
HOU A-li MENG Qing-fan AN Jin-shuang ZHU Kai FENG Yun TENG Li-rong College of Life Science Jilin University Changchun P. R. China 《高等学校化学研究》2008,24(5):584-587
The crude polysaccharide was obtained by means of the decolorization of porphyrized Cordyceps minlitaris stroma with organic solvent, extraction with hot water, precipitation in 80% ethanol, and protein removal with the Sevag method. After purification with Sephadex G-75, two of its components, CMP-1 and CMP-2, were obtained. Through the assay of gel chromatography and polarimetry, CMP-1 was identified as pure polysaccharide. The results demonstrated that CMP-1 had favorable oxidation resistance activity, which could scavenge not only oxygen-free radicals in the self-oxidation system of pyrogallic acid, but also the hydroxide-free radicals in the Fenton system. The study focused on the effects of low, medium, and high dosages of CMP-1 in rat blood serum on the proliferation of glomerular mesangial cells in vitro. Through MTT Colorimetric analysis, the activities were compared among the blank control group and the Niaoduqing positive control group CMP-1 and CMP-2. The results shows that CMP-1 was able to inhibit the proliferation of rat glomerular mesangial cells effectively. Therefore, CMP-1, one component of polysaccharides of Cordyceps minlitaris, was certainly a potential remedy for hyperplastic glomerular nephritis, whose antioxidant activity could slow down the process of chronic renal failure(CRF) to some extent. 相似文献
139.
ZHAO Ying-xian WEI Feng YU Ying Ningbo Institute of Technology Zhejiang University Ningbo P.R.China 《高等学校化学研究》2008,24(5):620-627
Catalytic oxidation of NO by O2 over La0.8Sr0.2MnO3 was tested in a tubular reactor.The reaction temperature ranged from 373 to 473 K,space time from 0.090 to 0.720 s,inlet NO concentration from 300 to 2000μL/L, and O2 volume fraction from 3%to 9%.The steady-state conversion of NO was increased significantly with increasing reaction temperature and the space time,slightly with increasing the O2 concentration but decreased with increasing the inlet NO concentration at a lower temperature.Under the conditions of 0.720 s space time,500μL/L NO concentration, 5%O2 volume fraction and 473 K,NO conversion reached 90%.A kinetic model including a network of 12 elementary reactions with the desorption of NO2 as the rate-limiting step is established and fits the experimental data well.The activation energy of NO2 desorption from the catalyst surface is determined to be 101 kJ/mol. 相似文献
140.
CHEN Jie DONG Xin-shu GUO Xing-gang The Affiliated Tumor Hospital Harbin Medical University Harbin P. R. China 《高等学校化学研究》2008,24(6)
To explore the functional mechanism of Resveratrol against colon cancer cells Is174t and the growth of colon cancer tissue of tumor-bearing mice,MTT method was used to observe the functions of resveratrol for inhibition against cells ls174t in vitro.Transmission electron microscope was used to observe the cell apoptosis.FCM assay was performed to measure the change of the cell apoptosis rate and of cell cycle,RT-PCR method was used to detect the expressions of bc1-2 and bax mRNA.Western blot method was used to detect the expressions of bc1-2 and bax protein.Cells isi74t were transplanted subcutaneously to nude mice to observe the effect of resveratrol on the growth of subcutaneously transplanted tumor.RT-PCR method was used to detect the expressions of bc1-2 and bax mRNA in the tumor tissue.Western blot method was used to detect the expressions of bc1-2 and bax protein in the tumor tissue.Resveratrol has an effect of inhibiting proliferation of cells ls174t in vitro(P<0.01).It is able to induce the apoptosis of cells Is174t,causing the decrease in the expression of bc1-2 and the increase in the expression of bax.Resveratrol could inhibit the growth of subcutaneously transplanted tumor of nude mice(P<0.05),causing the decrease in the expression of bc1-2 and the increase in the expression of bax.Resveratrol can inhibit the growth of cells 174t and the growth of subcutaneously transplanted tumor.The mechanism is possibly related to the induction of the cell apoptosis and the regulation of bc1-2/bax expression. 相似文献