全文获取类型
收费全文 | 540篇 |
免费 | 34篇 |
国内免费 | 13篇 |
专业分类
化学 | 371篇 |
晶体学 | 2篇 |
力学 | 28篇 |
数学 | 93篇 |
物理学 | 93篇 |
出版年
2023年 | 4篇 |
2022年 | 7篇 |
2021年 | 24篇 |
2020年 | 25篇 |
2019年 | 23篇 |
2018年 | 33篇 |
2017年 | 17篇 |
2016年 | 39篇 |
2015年 | 28篇 |
2014年 | 38篇 |
2013年 | 60篇 |
2012年 | 54篇 |
2011年 | 60篇 |
2010年 | 39篇 |
2009年 | 35篇 |
2008年 | 27篇 |
2007年 | 25篇 |
2006年 | 12篇 |
2005年 | 12篇 |
2004年 | 7篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1978年 | 1篇 |
1932年 | 1篇 |
排序方式: 共有587条查询结果,搜索用时 234 毫秒
11.
12.
Zahra Taji Ali A. Ensafi Elahe Heydari-Soureshjani Behzad Rezaei 《Electroanalysis》2021,33(2):304-313
In this work, a modified 3D-rGO/MWCNT with nickel and copper oxide nanoparticles were synthesized. The structural properties of this nanocomposite were investigated by several techniques. The fabricated sensor at optimum condition potential of +0.60 V (vs. Ag/AgCl) and a rotational rate of 1800 rpm gave a detection limit of 0.04 μmol L−1 with two dynamic ranges of 0.10–300 and 300–900 μmol L−1 glucose with high stability. The good accuracy of the fabricated sensor was proved in the determination of glucose in a blood sample (with recoveries between 95 % to 105 % and RSDs of 1.2 to 2.5 %). 相似文献
13.
14.
15.
Preparation,characterization and heterogeneous catalytic applications of GO/Fe3O4/HPW nanocomposite in chemoselective and green oxidation of alcohols with aqueous H2O2 下载免费PDF全文
Graphene oxide ‐ Fe3O4 ‐ NH3+H2PW12O40 ‐ magnetic nanocomposite (GO/Fe3O4/HPW) was prepared by linking amino ‐ functionalized Fe3O4 nanoparticles (Fe3O4 ‐ NH2) on the graphene oxide (GO), and then grafting 12 ‐ tungstophosphoric acid (H3PW12O40) on the graphene oxide ‐ magnetite hybrid (GO ‐ Fe3O4 ‐ NH2). The obtained GO/Fe3O4/HPW nanocomposite was well characterized with different techniques such as FT ‐ IR, TEM, SEM, XRD, EDX, TGA ‐ DTA, AGFM, ICP and BET measurements. The used techniques showed that the graphene oxide layers were well prepared and the various stages of preparation of the GO/Fe3O4/HPW nanocomposites successfully completed. This new nanocomposite displayed excellent performance as a heterogeneous catalyst in the oxidation of alcohols with H2O2. The as ‐ prepared GO/Fe3O4/HPW catalyst was more stable and recyclable at least five times without significantly reducing its catalytic activity. 相似文献
16.
In this work, we study three-electron magnetic susceptibility in quantum dots under Rashba spin-orbit interaction (SOI) and magnetic field by an analytical methodology. The Hamiltonian of the system is separated to center of mass and relative terms using the Jacobi transformations and the hyperspherical coordinates. By solving Schrodinger equation, energy levels and thereby the susceptibility are calculated using canonical ensemble. At zero temperature, the magnetization reduces with increasing magnetic field with and without Rashba SOI in three-electron-quantum dot without electron-electron (e-e) interaction. Also, SOI slightly changes the magnetization for three-electron-quantum dot without e-e interaction. At nonzero temperature, the magnetization shows a paramagnetic peak when the magnetic field increases. This peak position changes under the SOI. In the presence of e-e interaction, the susceptibility enhances with raising magnetic field and it shows a maximum. The susceptibility at low magnetic field is negative and then it becomes positive. The susceptibility with e-e interaction and without SOI is always diamagnetic and its magnitude reduces with enhancing magnetic field. The susceptibility shows a transition between diamagnetic and paramagnetic with e-e interaction and SOI. 相似文献
17.
18.
Nanostructured γ-Al2O3 with high surface area and mesoporous structure was synthesized by sol-gel method and employed as catalyst support for nickel catalysts in methane reforming with carbon dioxide. The prepared samples were characterized by XRD, N2adsorption-desorption,TPR, TPO, TPH, NH3-TPD and SEM techniques. The BET analysis showed a high surface area of 204 m2 g-1and a narrow pore-size distribution centered at a diameter of 5.5 nm for catalyst support. The BET results revealed that addition of lanthanum oxide to aluminum oxide decreased the specific surface area. In addition, TPR results showed that addition of lanthanum oxide increased the reducibility of nickel catalyst. The catalytic evaluation results showed an increase in methane conversion with increasing lanthanum oxide to 3 mol% and further increase in lanthanum content decreased the catalytic activity. TPO analysis revealed that the coke deposition decreased with increasing lanthanum oxide to 3 mol%. SEM and TPH analyses confirmed the formation of whisker type carbon over the spent catalysts. Addition of steam and O2 to dry reforming feed increased the methane conversion and led to carbon free operation in combined processes. 相似文献
19.
Qamrul Hasan Ansari Mahboubeh Rezaei 《Journal of Optimization Theory and Applications》2012,153(3):587-601
In this paper, we introduce the notion of invariant pseudolinearity for nondifferentiable and nonconvex functions by means
of Dini directional derivatives. We present some characterizations of invariant pseudolinear functions. Some characterizations
of the solution set of a nonconvex and nondifferentiable, but invariant, pseudolinear program are obtained. The results of
this paper extend various results for pseudolinear functions, pseudoinvex functions, and η-pseudolinear functions, and also for pseudoinvex programs, pseudolinear programs, and η-pseudolinear programs. 相似文献
20.