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81.
82.
FT-IR with partial least squares (PLS) was used to establish a full calibration model for tartaric acid, malic acid, lactic acid, succinic acid, citric acid and acetic acid in wines, vinegars and spirits. Sample pre-treatment was not required except for filtering.  相似文献   
83.
A biochemical gas-sensor (bio-sniffer) was constructed for convenient measurement of odourless hydrogen peroxide (H2O2) vapour, which is harmful to skin and mucous membranes. An enzyme-immobilized membrane was fabricated by spreading the mixture of catalase and photo-crosslinkable polymer on a dialysis membrane. An H2O2 biosensor was constructed by attaching this catalase-immobilized membrane to the sensitive top of a Clark-type oxygen electrode, and the oxygen generation from the decomposition of H2O2 catalysed by catalase was measured amperometrically. This biosensor was first applied to the measurement of H2O2 solution and was able to quantify the concentrations of H2O2 solution from 0.02 to 10.0?mmol?L?1. Then, this biosensor was applied to gaseous phase as a bio-sniffer and was able to detect the odourless H2O2 vapour with the calibration range from 0.5 to 30?ppm, where the threshold limit value assigned by the American Conference of Governmental Industrial Hygienists (1?ppm) is covered.  相似文献   
84.
Through delicate tuning of the electronic structure, we report herein a rational design of seventeen new putative global minimum energy structures containing a planar tetra- or pentacoordinate carbon atom embedded in an aromatic hydrocarbon. These structures are the result of replacing three consecutive hydrogen atoms of an aromatic hydrocarbon by less electronegative groups, forming a multicenter σ-bond with the planar hypercoordinate carbon atom and participating in the π-electron delocalization. This strategy that maximizes both mechanical and electronic effects through aromatic architectures can be extended to several molecular combinations to achieve new and diverse compounds containing planar hypercoordinate carbon centers.  相似文献   
85.
A fast, simple, and reliable analytical method for the determination of medium‐level volatile thiols in wines is presented. Stir bar sorptive extraction using ethylene glycol‐silicone coated stir bars has been used in combination with thermal desorption gas chromatography with mass spectrometry for the analysis of 4‐mercapto‐4‐methylpentan‐2‐one, 2‐furanmethanethiol, 3‐mercaptohexyl acetate, and 3‐mercaptohexanol in wine. Optimization of the extraction technique was performed using a two‐level fractional factorial design. For the extraction step, the optimum conditions were: Ethylene glycol and silicone coated stir bars, pH at 3.5, sample volume of 25 mL, extraction time of 90 min, NaCl content 4.0 g, and stirring speed at 500 rpm. The optimized method achieved good linearity for all studied compounds (r2 > 0.995) and it provided detection limits of 21.52, 0.36, 0.73, and 2.55 μg/L for 4‐mercapto‐4‐methylpentan‐2‐one, 2‐furanmethanethiol, 3‐mercaptohexyl acetate, and 3‐mercaptohexanol, respectively. It was repeatable, with precisions lower than 18% relative standard deviation for both intraday and interday repeatability. The developed procedure is suitable for the determination of these kinds of compounds when they are present at medium concentration levels. It was finally applied to real wine samples with negative aroma derived from the high concentration levels of these compounds.  相似文献   
86.
87.
Levels of organotin body burden (expressed as tin), imposex and steroid hormones (testosterone, 17β‐oestradiol, testosterone glucuronide and sulfate conjugates) were investigated in natural populations of Nassarius reticulatus in the Ria de Aveiro (northwest Portugal) between 1997 and 1999. The tributyltin (TBT) whole body burden (b.b.) of females presented increasing gradients from the adjacent open coast (16–26 ng g?1 dry weight (d.w.)) towards the ports inside the Ria de Aveiro (195–272 ng g?1 d.w.). Triphenyltin b.b. was only detected at the most polluted port (22 ng g?1 d.w.). Imposex also presented increasing values from the adjacent coast (vas deferens sequence index (VDSI): 0.0–0.5; relative penis length index (RPLI): 0.0–2.4; penis length index (PLI): 0.0–0.3 mm; percentage of affected females (%I): 0–30) towards the ports (VDSI: 3.8–4.8; RPLI: 51–80; PLI: 6.7–10.8 mm; %I: 100). The testosterone levels in females without imposex were always lower than in females with imposex, and the ratio of testosterone/17β‐oestradiol in females tended to increase with increasing imposex and organotin contamination. In spite of the large difference in the female testosterone and 17β‐oestradiol levels between summer and winter, related to the reproductive cycle, the spatial trend of the testosterone/17β‐oestradiol ratio was remarkably similar in shape and values in the two seasons. Imposex was significantly correlated with the TBT b.b. and the testosterone/17β‐oestradiol ratio in females. The testosterone conjugate levels did not show any clear pattern with the increasing values of imposex and TBT contamination. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
88.
The conceptual design of a 35 GHz gyrotron has been developed consistently with the complex formulation of the electric field longitudinal distribution in the resonant cavity. Some models of magnetron injection guns able to produce laminar beams have been investigated leading to the design of an electron gun capable of generating a current of 5 A with a perpendicular velocity dispersion of 0.5%. The device includes three magnetic systems producting flat axial magnetic induction profiles of 1.05 kG, 13.2 kG and 0.65 kG in the cathode, cavity and collector regions, respectively. The gyrotron has been designed for pulsed operation in the TE021 mode. Under the soft self-excitation condition, the maximum attainable efficiency is 40% with an output power of 100 kW. An analysis of the collector thermal behaviour has been carried out as well as a study of the thermophysical properties of the alumina window to be used.  相似文献   
89.
Moringa oleifera seeds contain a water-soluble lectin [water-soluble M. oleifera lectin (WSMoL)] that has shown coagulant activity. Magnesium ions are able to interfere with the ability of this lectin to bind carbohydrates. In this study, we performed structural characterization of WSMoL and analyzed its effect on the electrical resistance of a kaolin clay suspension in both presence and absence of monosaccharides (N-acetylglucosamine, glucose, or fructose) and magnesium ions. The coagulant activity of WSMoL was monitored by measuring optical density and electrical resistance over a period of 60 min. Native WSMoL had a molecular mass of 60 kDa and exhibited anionic nature (pI 5.5). In sodium dodecyl sulfate–polyacrylamide gel electrophoresis (SDS-PAGE), it appeared as three polypeptide bands of 30, 20, and 10 kDa. WSMoL reduced the optical density and electrical resistance of the kaolin suspension, which suggests that suspended particles are destabilized and that this is followed by formation of complexes. The coagulant activity of lectin decreased in the presence of Mg2+ ions and carbohydrates at concentrations that also inhibited hemagglutinating activity. This was most likely due to conformational changes in lectin structure. Our findings suggest that the coagulant activity of WSMoL is enhanced by lowering of electrical resistance of the medium and is impaired by lectin–carbohydrate and lectin–Mg2+ interactions.  相似文献   
90.
A fast method using high-performance liquid chromatography based on two monolithic columns has been developed for the simultaneous determination of isoflavones extracted from soybeans and derived foods. The 12 main isoflavones were resolved in 10 min in two coupled monolithic columns working at 35 °C using a elution gradient of acidified water (0.1% acetic acid) and methanol (0.1% acetic acid) at a flow rate of 5 mL min−1. Retention time and relative area standard deviations were below 1% for all isoflavones. The method developed was successfully applied to several soy food samples and spiked samples. Total isoflavone concentration in sampled soy foods ranged from 34.28 mg L−1 to 4.29 mg g−1.  相似文献   
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