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71.
One form of contract bridge tournament comprises several rounds of matches in which players compete as pairs for ‘masterpoints’ awarded for each match won or drawn and for being highly placed at the end of the tournament. In the second and subsequent rounds, pairs are matched against other pairs that have been approximately equally successful so far. There has been vague discussion among bridge players of the possible advantages of ‘throwing’, that is, deliberately losing a match in round r so as to obtain a lower ranking and face an easier opponent in round r+1. This paper uses dynamic programming and data from one tournament to identify an optimal strategy (either ‘throw’ or ‘play to win’). The optimal strategy is a function of a pair's ability, its placing after each round, the relative rewards for winning a match and finishing high, the opponent's skill, and the round. For example, we find that a very weak pair should ‘throw’ and ‘play to win’ in alternate rounds.  相似文献   
72.
Abstract— The yield of singlet oxygen (1Δg) from some furocoumarins in the presence of DNA has been measured using time resolved techniques. For both psoralen and 4'-aminomethyl-4,5',8-trimethylpsoralen, increasing DNA concentration leads to a decrease in the yield of singlet oxygen. In addition, there is a linear dependence between the yield of singlet oxygen and the observed triplet yield determined by laser flash photolysis. In view of this observation it seems unlikely that singlet oxygen production occurs from these two furocoumarins when they are complexed with DNA. Preliminary, albeit inconclusive, results for 8-methoxypsoralen are also presented.  相似文献   
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We demonstrate new principles of microfluidic pumping and mixing by electronic components integrated into a microfluidic chip. The miniature diodes embedded into the microchannel walls rectify the voltage induced between their electrodes from an external alternating electric field. The resulting electroosmotic flows, developed in the vicinity of the diode surfaces, were utilized for pumping or mixing of the fluid in the microfluidic channel. The flow velocity of liquid pumped by the diodes facing in the same direction linearly increased with the magnitude of the applied voltage and the pumping direction could be controlled by the pH of the solutions. The transverse flow driven by the localized electroosmotic flux between diodes oriented oppositely on the microchannel was used in microfluidic mixers. The experimental results were interpreted by numerical simulations of the electrohydrodynamic flows. The techniques may be used in novel actively controlled microfluidic-electronic chips.  相似文献   
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In the last two decades, surface-science experiments and techniques have been developed to focus on obtaining molecular information under reaction conditions at high pressures (near or above 1 bar) and liquid interfaces. This Minireview describes the results of these studies obtained by surface-sensitive laser spectroscopies, scanning tunneling microscopy, and X-ray spectroscopies usually practiced at a synchrotron light source. The use of model surfaces, single crystals, and monodisperse nanoparticles with variable size (1-10 nm) and shape facilitates meaningful interpretation of the experimental data. These methods allow evaluation of the molecular structures of intermediates, oxidation states of metals, and mobility of adsorbants. New techniques that are likely to make major contributions to the investigation of surfaces under reaction conditions are also discussed.  相似文献   
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Free energy and capture cross section of the E2 trap in n‐type GaN are investigated by deep level transient spectroscopy with the help of an experimental method, relying on space charge depth modulation [D. Pons, J. Appl. Phys. 55 , 3644 (1984)]. This technique is applied with a large range of filling pulse durations (up to 6 orders of magnitude) and for temperature varying between 260 K and 330 K. Entropy and capture barrier are found to be negligible. Analysis of our results makes N in Ga site (NGa antisite) as the best candidate for this trap. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
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Gallium nitride doped with oxygen (unintentionally), silicon and magnesium was grown by metalorganic chemical vapor deposition on the conductive single crystals of GaN grown at high hydrostatic pressure. The layers were examined using X-ray diffraction, photoluminescence and far-infrared reflectivity. It was found that the incorporation of silicon depends on the side used for deposition. For the two Si-doped layers grown in the same run, the one grown on the (00.1) side (gallium-terminated) had always smaller free electron concentration with respect to the (00._1) side (nitrogen-terminated). This conclusion could be drawn from the lattice expansion by free electrons, the photoluminescence peak shift by Burstein-Moss effect and the position of plasma edge in far-infrared reflectivity.  相似文献   
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The misfit between GaN and 6H-SiC is 3.5% instead of 16% on growth over sapphire, whereas that between AlN and 6H-SiC is only 1%. Therefore, ELOG GaN on AlN/6H-SiC could be a route to further improve the quality of ELOG GaN. We analyzed ELOG GaN grown on AlN at an early stage of coalescence in order to identify which dislocations bend and try to understand why. The ELOG islands were always limited by {101-0} facets. From the center of these islands, more than 99% dislocations bend to the basal plane. The a -type dislocations were found to fold many times from basal to the prismatic plane, whereas when a + c dislocations bend to the basal plane, they were not seen to come back to a prismatic one.  相似文献   
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