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81.
82.
Square planar complexes of the type [2-(1-aminoethyl)phenyl-kappa(2)C(1),N]chloro(py-kappaN)palladium(II)(py = pyridine derivative) have been prepared by cyclopalladation of 1-phenylethylamine. When opposite enantiomers of the chiral amine and different pyridine ligands were coordinated to the metal, quasiracemic complexes were obtained. The racemisation speed of solutions containing equimolar amounts of such quasiracemic complexes was used to test the compounds for inertness: slow ligand exchange was found for methylated pyridines. Enantiomerically pure complexes of opposite chirality with the electron rich ligands 2,6-collidine and 2,4,6-lutidine were successfully cocrystallised: they form a well-ordered binary solid in which four independent molecules, two of each constituent, are related by pseudo symmetry operations. This quasiracemate as well as its components and the true racemates of the latter were characterised by single crystal X-ray diffraction. The heterochiral crystals, both the cocrystal as well as the racemates, show better space filling than the homochiral solids. 相似文献
83.
L. Bonora P. Cotta-Ramusino M. Rinaldi J. Stasheff 《Communications in Mathematical Physics》1987,112(2):237-282
The rôle of the evaluation map in anomaly calculations for field theory, sigma-models and strings is investigated. In this paper, anomalies in field theory (with and without a backgrounds connection), are obtained as pull-backs of suitable forms via evaluation maps. The cohomology of the group of gauge transformations is computed in terms of the cohomology of the base manifold and of the cohomology of the structure group. This allows us to clarify the different topological significance of gauge and gravitational anomalies. The relation between locality and universality is discussed and local cohomology is linked to the cohomology of classifying spaces. The problem of combining the locality requirement and the index theorem approach to anomalies is also examined. Anomaly cancellation in field theories derived from superstrings is analyzed and the relevant geometrical constraints are discussed.On leave of absence from Dipartimento di Fisica dell'Universitá di Padova and Istituto Nazionale di Fisica Nucleare, Sezione di PadovaWork supported in part by: Ministero Pubblica Istruzione (research project on Geometry and Physics)On leave of absence from Department of Mathematics, University of North Carolina, Chapel Hill, N.C. 27514. Work supported in part by N.S.F. 相似文献
84.
Spezia S Bocca B Forte G Gatti A Mincione G Ronchi A Bavazzano P Alimonti A Minoia C 《Rapid communications in mass spectrometry : RCM》2005,19(11):1551-1556
In recent years the increasing use of platinum (Pt) both in medical and in industrial applications has caused its growing anthropogenic emission and spread in the environment. Pt is released into the atmosphere by exhaust catalytic converters, and Pt compounds are often used in antitumour therapies. As a consequence, significant amounts of Pt can be detected in hospital wastewaters. This can lead to an increase in the exposure levels to Pt, especially in urban areas. It is therefore necessary to determine Pt reference values in the general population, by using suitable procedures able to achieve adequate analytical performances. Several measurements of Pt in biological fluids have been reported, but the analytical methods used for the determination of Pt often lack information about the uncertainty of the results, especially for low concentrations of urinary Pt in non-occupationally exposed subjects. The present paper considers the measurement of urinary Pt levels in a general population group from central Italy, by both quadrupole (Q) and sector field (SF) inductively coupled plasma mass spectrometry (ICP-MS). The two procedures were validated and their expanded uncertainties were evaluated. The limits of detection (LODs), calculated taking into account dilution factors, were 0.18 and 0.05 ng L(-1) of Pt for the Q and SF procedures, respectively. The median value observed was 4.13 ng L(-1) of Pt in urine, while the relative combined uncertainty at 5 ng L(-1) was below 20% with both ICP-MS techniques. These data are in good agreement with those reported in the literature for similar studies. 相似文献
85.
Lund A Olsson S Bonora M Lund E Gustafsson H 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(6):1301-1311
New materials for electron spin resonance (ESR) dosimetry have been investigated with the aim to find systems more sensitive than L-alanine accepted as a standard for high dose determinations. Among the investigated systems ammonium tartrate, 2-methylalanine, salts of formic acids and dithionates have been found to be more sensitive than alanine by a factor 2-10. The lower limit applies to tissue equivalent materials, while much higher sensitivities were obtained with formates and dithionates containing heavier atoms. The increased sensitivity was mainly attributed to suitable ESR properties of the room temperature stable radicals as regards spectral shape (narrow lines, little or no hyperfine structure) and microwave saturation properties (short relaxation times). The radical structures have when necessary been clarified by ENDOR spectroscopy, while the saturation properties have been screened by pulsed ESR measurements. 相似文献
86.
The coupling of two locally mass conservative methods is formulated and analyzed for the time‐dependent convection‐diffusion problem. Finite volume method is used in some subdomains and interior penalty discontinuous Galerkin method is used in other subdomains. Numerical examples show the advantages of the proposed hybrid method, namely an accurate approximation obtained at a reduced computational cost. © 2013 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 30: 133–157, 2014 相似文献
87.
88.
89.
Beatrice Nicolaï P. Espeau R. Céolin M. -A. Perrin L. Zaske J. Giovannini F. Leveiller 《Journal of Thermal Analysis and Calorimetry》2007,90(2):337-339
Spironolactone (C24H32O4S) usually crystallizes into an orthorhombic phase, named Form II. Another orthorhombic phase, named Form I, is also known
but seems difficult to obtain. Studies of the kinetics of desolvation of the ethanol solvate at room temperature showed that
these two forms can be obtained through different mechanisms of desolvation. 相似文献
90.
α-Well-posedness for Nash Equilibria and For Optimization Problems with Nash Equilibrium Constraints
We present the concepts of α-well-posedness for parametric noncooperative games and for optimization problems with constraints defined by parametric Nash equilibria. We investigate some classes of functions that ensure these types of well-posedness and the connections with α-well-posedness for variational inequalities and optimization problems with variational inequality constraints. 相似文献