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31.
32.
Aneta Slodczyk Philippe Colomban Daniel Lamago Marie-Helene Limage François Romain Stephanie Willemin Beatrice Sala 《Ionics》2008,14(3):215-222
H+-containing lanthanide-doped perovskites A(Ba, Sr etc.)B(Zr, Ce, Ti etc.)O3 are potential ceramic membranes for fuel cell and medium temperature water electrolysis (300–800 °C). The comparison studies
of the hydrated and non-hydrated Yb-doped BaZrO3 and SrZrO3 were performed by thermal expansion, medium–high temperature neutron and room-temperature high-pressure Raman scattering.
Neutron diffraction and elastic/quasi-elastic studies carried out for BaZrO3 ceramic show the presence of the protons, their successive diffusion above ∼600 °C, and then their departure above 750 °C
(under vacuum). Phase transitions and their modification by proton insertion are discussed. A high-pressure Raman study of
SrZrO3 performed at room temperature in the diamond anvil cell reveals the presence of two pressure-induced phase transitions at
about 5 and 22 GPa and confirms that proton insertion modifies the phase transition sequences.
Paper presented at the 11th EuroConference on the Science and Technology of Ionics, Batz-sur-Mer, Sept. 9–15, 2007. 相似文献
33.
Villoresi P Bonora S Pascolini M Poletto L Tondello G Vozzi C Nisoli M Sansone G Stagira S De Silvestri S 《Optics letters》2004,29(2):207-209
We present a method for the optimization of high-order harmonic generation based on wave-front correction of the driving laser beam. The technique exploits wave-front adaptive control by means of a deformable mirror, governed by an optimization procedure. 相似文献
34.
Olga Bortolini Beatrice Russo Giovanni Sindona Amedeo Tocci 《Tetrahedron letters》2007,48(40):7125-7128
1,3-Dipolar cycloadditions of nitrones with alkenes afforded the corresponding isoxazolidines in ionic liquids in the presence of Er(OTf)3. The ionic liquid and the catalyst are recycled up to five times without any specific treatment or loss of activity. Extension of the procedure to the synthesis of isoxazolidinyl nucleosides has been investigated. 相似文献
35.
Zanchet A Bussery-Honvault B Honvault P 《The journal of physical chemistry. A》2006,110(43):12017-12025
The C((3)P) + OH(X (2)Pi) --> CO(X (1)Sigma(g)(+)) + H((2)S) reaction has been investigated by ab initio electronic structure calculations of the X(2)A' state based on the multireference (MR) internally contracted single and double configuration interaction (SDCI) method plus Davidson correction (+Q) using Dunning aug-cc-pVQZ basis sets. In particular, the multireference space is taken to be a complete active space (CAS). Improvement over previously proposed potential energy surfaces for HCO/COH is obtained in the sense that present surface describes also the potential part where the CO interatomic distance is large. A large number of geometries (around 2000) have been calculated and analytically fitted using the reproducing kernel Hilbert space (RKHS) method of Ho and Rabitz both for the two-body and three-body terms following the many-body decomposition of the total electronic energies. Results show that the global reaction is highly exothermic ( approximately 6.4 eV) and barrierless (relative to the reactant channel), while five potential barriers are located on this surface. The three minima and five saddle points observed are characterized and found to be in good agreement with previous work. The three minima correspond to the formation of HCO and COH complexes and to the CO + H products, with the COH complex being a metastable minimum relative to the product channel. The five saddle points correspond to potential barriers for both the dissociation/formation of HCO and COH into/from CO + H, to barriers for the isomerization of HCO into COH and to barriers for the inversion of HCO and COH through their respective linear configuration. 相似文献
36.
37.
The presumably "small molecule structure" of the organopalladium complex rac-PdCl(C(6)H(3)-4-OMe-CHMeNH(2))(py) crystallizes with 16 molecules in the asymmetric unit, a highly unusual situation according to the CSD database. The symmetrically independent residues differ with respect to soft conformational degrees of freedom. Packing in the acetonitrile solvate of the same compound is unexceptional. 相似文献
38.
Liliana Mititelu-Tartau Maria Bogdan Daniela Angelica Pricop Beatrice Rozalina Buca Ana-Maria Pauna Lorena Anda Dijmarescu Ana-Maria Pelin Liliana Lacramioara Pavel Gratiela Eliza Popa 《Molecules (Basel, Switzerland)》2021,26(13)
This paper is focused on the in vivo release and biocompatibility evaluation in rats of some novel systems entrapping zinc chloride in lipid vesicles. The particles were prepared by zinc chloride immobilization inside lipid vesicles made using phosphatidylcholine, stabilized with 0.5% chitosan solution, and dialyzed for 10 h to achieve a neutral pH. The submicrometric systems were physico-chemically characterized. White Wistar rats, assigned into four groups of six animals each, were treated orally with a single dose, as follows: Group I (control): deionized water 0.3 mL/100 g body weight; Group II (Zn): 2 mg/kg body weight (kbw) zinc chloride; Group III (LV-Zn): 2 mg/kbw zinc chloride in vesicles; Group IV (LVC-Zn): 2 mg/kbw zinc chloride in vesicles stabilized with chitosan. Haematological, biochemical, and immune parameters were assessed after 24 h and 7 days, and then liver fragments were collected for histopathological examination. The use of zinc submicrometric particles—especially those stabilized with chitosan—showed a delayed zinc release in rats. No substantial changes to blood parameters, plasma biochemical tests, serum complement activity, or peripheral neutrophils phagocytic capacity were noted; moreover, the tested substances did not induce liver architectural disturbances. The obtained systems provided a delayed release of zinc, and showed good biocompatibility in rats. 相似文献
39.
40.
We show that ghosts in gauge theories can be interpreted as Maurer-Cartan forms in the infinite dimensional group ? of gauge transformations. We examine the cohomology of the Lie algebra of ? and identify the coboundary operator with the BRS operator. We describe the anomalous terms encountered in the renormalization of gauge theories (triangle anomalies) as elements of these cohomology groups. 相似文献